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Diffusion of implanted sodium in oxygen-containing silicon

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Abstract

The effect of oxygen on diffusion of sodium implanted into silicon is studied for the first time in the temperature range from 500 to 850°C. A high-resistivity p-Si (ρ > 1 kΩ cm) grown by the Czochralski method in a magnetic field (mCz) with the oxygen concentration ∼3 × 1017 cm−3 was used. For comparison, we used silicon grown by the crucibleless floating zone method (fz). Temperature dependences of the effective diffusion coefficient of sodium in the mCz-Si and fz-Si crystals were determined and written as D mCz[cm2/s] = 1.12exp(−1.64 eV/kT) cm2/s and D fz[cm2/s] = 0.024exp(−1.29 eV/kT) cm2/s, respectively. It is assumed that larger values of diffusion parameters in oxygen-containing silicon are caused by formation of complex aggregates that contain sodium and oxygen atoms.

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Correspondence to V. M. Korol’.

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Original Russian Text © V.M. Korol’, S.A. Vedenyapin, A.V. Zastavnoĭ, V. Ovchinnikov, 2008, published in Fizika i Tekhnika Poluprovodnikov, 2008, Vol. 42, No. 9, pp. 1140–1144.

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Korol’, V.M., Vedenyapin, S.A., Zastavnoĭ, A.V. et al. Diffusion of implanted sodium in oxygen-containing silicon. Semiconductors 42, 1122–1126 (2008). https://doi.org/10.1134/S1063782608090212

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  • DOI: https://doi.org/10.1134/S1063782608090212

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