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Phase formation and phase transformations in Bi-Te films with nanoscale thickness

  • Atomic Structure and Nonelectronic Properties of Semiconductors
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Abstract

The processes of phase formation are studied in a binary Bi-Te system using the kinematic electron diffraction technique. It is established that, in the case of both simultaneous and layer-by-layer deposition of bismuth and tellurium and irrespective of the order of their deposition, phases with compositions Bi2Te3 and BiTe are formed at the condensation plane in the amorphous and crystalline state, respectively. The amorphous Bi2Te3 phase is stable at room temperature and crystallizes at a temperature of 423 K. It is shown that ordering of the phase BiTe is not a consequence of atomic order of the structure; rather, it is caused by the real structure of the object (by blocks).

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References

  1. N. Kh. Abrikosov and V. F. Bankina, Zh. Neorg. Khim. 3, 659 (1958).

    Google Scholar 

  2. A. Broun and B. Lewis, J. Phys. Chem. Sol. 32, 1597 (1962).

    Article  ADS  Google Scholar 

  3. M. Khazhen and K. Anderko, Structure of Binary Alloy (Metallurgizdat, Moscow, 1962), Vol. 2 [in Russian].

    Google Scholar 

  4. V. T. Kuznetsov and K. K. Palkina, Zh. Neorg. Khim. 8, 1204 (1963).

    Google Scholar 

  5. A. Glatz, J. Electrochem. Soc. 112, 1201 (1965).

    Article  Google Scholar 

  6. C. Champness and L. Klipling, Can. J. Phys. 44, 769 (1966).

    ADS  Google Scholar 

  7. B. M. Gol’tsman, V. A. Kudinov, and I. A. Smirnov, Semiconducting Thermoelectric Materials Based on Bi 2 Te 3 (Nauka, Moscow, 1972).

    Google Scholar 

  8. D. M. Gel’fgat, Z. M. Dashevskiĭ, and N. V. Kolomiets, in Thermoelectric Materials and Films (Leningrad, 1976), p. 240 [in Russian].

  9. T. Harman, J. Phys. Chem. Sol. 2, 181 (1957).

    Article  ADS  Google Scholar 

  10. H. Tamura. Jpn. J. Appl. Phys. 5, 593 (1966).

    Article  ADS  Google Scholar 

  11. Yu. A. Bonosvskiĭ, A. G. Dudoladov, and V. P. Kozlenkov, Pis’ma Zh. Éksp. Teor. Fiz. 20, 304 (1974) [JETP Lett. 20, 135 (1974)].

    Google Scholar 

  12. D. I. Ismailov, G. M. Akhmedov, and R. B. Shafizade, DokL. Akad. Nauk AzSSR 45(4), 6 (1989).

    Google Scholar 

  13. G.A. Éfendiev and R. B. Shafizade, Prib. Tekh. Éksp., No. 1, 142 (1963).

  14. Physical and Chemical Properties of Semiconductor Materials. A Handbook, Ed. by A. V. Novoselova and V. B. Lazareva (Nauka, Moscow, 1979) [in Russian].

    Google Scholar 

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Correspondence to K. M. Akhmedov.

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Original Russian Text © K.M. Akhmedov, 2008, published in Fizika i Tekhnika Poluprovodnikov, 2008, Vol. 42, No. 9, pp. 1025–1027.

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Akhmedov, K.M. Phase formation and phase transformations in Bi-Te films with nanoscale thickness. Semiconductors 42, 1009–1011 (2008). https://doi.org/10.1134/S1063782608090017

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  • DOI: https://doi.org/10.1134/S1063782608090017

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