Abstract
Thin GaN films were grown on GaAs(111) substrates by radical-beam gettering epitaxy. The structural quality of the films was studied by high-resolution x-ray diffraction. The chemical composition of the GaAs surface and GaN film was studied by x-ray photoelectron spectroscopy. It is shown that Ga-N and As-N bonds are formed on the GaAs surface at initial growth stages at low temperatures. The state of the film-substrate interface was studied. It was found that prolonged annealing of GaN films in nitrogen radicals shifts the composition to nitrogen excess.
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S. J. Pearton, J. C. Zolper, R. J. Shul, and F. Ren, J. Appl. Phys. 86, 1 (1999).
M. Asif Khan, M. Shatalov, H. P. Maruska, et al., Jpn. J. Appl. Phys., Part 1 44, 7191 (2005).
O. Ambacher, J. Phys. D 31, 2653 (1998).
M. Boćkowski, Physica B (Amsterdam) 265, 1 (1999).
A. Kikuchi, H. Hoshi, and K. Kishino, Jpn. J. Appl. Phys., Part B 33, 688 (1994).
A. N. Georgobiani, M. B. Kotlyarevsky, and I. V. Rogozin, Inorg. Mater. 40(Suppl. 1), S1 (2004).
T. Ito, M. Sumiya, Y. Takano, et al., Jpn. J. Appl. Phys., Part A 38, 649 (1999).
Z. Li, H. Chen, H. Liu, et al., Jpn. J. Appl. Phys., Part 1 39, 4704 (2000).
S. Strite, J. Ruan, Z. Li, et al., J. Vac. Sci. Technol. B 10, 1924 (1992).
H. Sugiyma, M. Shinohara, and K. Wada, Appl. Surf. Sci. 117–118, 546 (1997).
Q.-K. Xue, Q.-Zh. Xue, Y. Hasegawa, et al., Jpn. J. Appl. Phys., Part B 36, L1486 (1997).
A. N. Georgobiani and M. B. Kotlyarevsky, Nucl. Phys. B (Proc. Suppl.) 61, 341 (1998).
T. V. Butkhuzi, A. N. Georgobiani, E. Zada-Uly, et al., Tr. Fiz. Inst. im. P. N. Lebedeva, Akad. Nauk SSSR 182, 140 (1987).
P. Hill, D. I. Westwood, L. Haworth, et al., J. Vac. Sci. Technol. B 15, 1133 (1997).
J. F. Moulder, W. F. Stickle, P. E. Sobol, and K. D. Bomben, Handbook of X-Ray Photoelectron Spectroscopy (Perkin-Elmer, Eden Pairie, MN, 1992).
K. M. Tracy, W. J. Mecouch, R. F. Davis, and R. J. Nemanich, J. Appl. Phys. 94, 3163 (2003).
X.-Y. Zhu, M. Wolf, T. Huett, and J. M. White, J. Chem. Phys. 97, 5856 (1992).
I. Aksenov, Y. Nakada, and H. Okumura, Jpn. J. Appl. Phys., Part B 37, L972 (1998).
Y. Zang, G. Du, X. Wang, et al., J. Cryst. Growth 252, 180 (2003).
I. V. Rogozin and A. V. Marakhovskiĭ, Zh. Prikl. Spektrosk. 72, 760 (2005).
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Original Russian Text © I.V. Rogozin, M.B. Kotlyarevsky, 2007, published in Fizika i Tekhnika Poluprovodnikov, 2007, Vol. 41, No. 5, pp. 575–579.
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Rogozin, I.V., Kotlyarevsky, M.B. X-ray photoelectron spectroscopy of gallium nitride films grown by radical-beam gettering epitaxy. Semiconductors 41, 555–559 (2007). https://doi.org/10.1134/S1063782607050156
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DOI: https://doi.org/10.1134/S1063782607050156