Abstract
A new approach is proposed for constructing the phenomenological theory of phase transitions. The approach is based on the classical Landau theory with allowance made for the order parameter that corresponds to changes in the charge distribution probability density of a crystal and does not affect the symmetry of the high-symmetry phase. It is demonstrated that this approach makes it possible to describe phase transitions in terms of a nonequilibrium polynomial Landau potential of degree four in the components of the order parameters. The capabilities of the proposed approach are illustrated with three systems that undergo ferroelastic phase transitions.
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Original Russian Text © A.Yu. Gufan, 2007, published in Zhurnal Éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2007, Vol. 132, No. 1, pp. 138–149.
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Gufan, A.Y. Totally symmetric order parameter in the framework of the phenomenological theory of phase transitions: Ferroelastics. J. Exp. Theor. Phys. 105, 120–131 (2007). https://doi.org/10.1134/S1063776107070266
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DOI: https://doi.org/10.1134/S1063776107070266