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Synchrotron Study of the Effect of Tantalum Variation on the Piezoelectric Modulus d11 in Langatate Crystal

  • DIFFRACTION AND SCATTERING OF IONIZING RADIATIONS
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Abstract

The nonuniform distribution of chemical element ratios in a crystal of nominal composition La3(Ga0.5Ta0.5)Ga5O14 has been determined using X-ray diffraction and X-ray fluorescence mapping on beamline 6.2 of the Kurchatov synchrotron radiation source “KISI-Kurchatov.” The Ga/Ta and La/Ta ratios are shown to increase from the center to the periphery of the crystal growth boule, which is accompanied by an increase in the number of oxygen vacancies leading to a decrease in piezoelectric modulus d11. The study is of practical importance for the creation of materials with desired properties.

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REFERENCES

  1. A. G. Kulikov, A. E. Blagov, A. S. Ilin, et al., J. Appl. Phys. 127, 065106 (2020). https://doi.org/10.1063/1.5131369

  2. M. V. Koval’chuk, A. E. Blagov, A. G. Kulikov, et al., Crystallogr. Rep. 59 (6), 862 (2014). https://doi.org/10.1134/S1063774514060145

    Article  ADS  Google Scholar 

  3. A. G. Kulikov, A. E. Blagov, N. V. Marchenkov, et al., JETP Lett. 107 (10), 646 (2018). https://doi.org/10.1134/S0021364018100120

    Article  ADS  Google Scholar 

  4. A. G. Kulikov, Yu. V. Pisarevskii, A. E. Blagov, et al., Phys. Solid State 61 (4), 548 (2019). https://doi.org/10.1134/S1063783419040188

    Article  ADS  Google Scholar 

  5. J. Stade, L. Bohaty, M. Hengst, and R. B. Heimann, Cryst. Res. Technol. 37 (10), 1113 (2002). https://doi.org/10.1002/1521-4079(200210)37:10<1113::AID-CRAT1113>3.0.CO;2-E

    Article  Google Scholar 

  6. A. E. Blagov, N. V. Marchenkov, Yu. V. Pisarevskii, et al., Crystallogr. Rep. 58 (1), 49 (2013). https://doi.org/10.1134/S1063774513010057

    Article  ADS  Google Scholar 

  7. T. Fukuda, H. Takeda, K. Shimamura, et al., Proc. 11th IEEE Int. Symp. on Applications of Ferroelectrics, Montreux, Switzerland, August 24–27, 1998, p. 315. https://doi.org/10.1109/ISAF.1998.786697

  8. V. Mill, IEEE–EIA Int. Frequency Control Symp. and Exhibition, 2000, p. 133. https://doi.org/10.1109/FREQ.2000.887343

  9. J. Bohm, E. Chilla, C. Flannery, et al., J. Cryst. Growth 216, 293 (2000). https://doi.org/10.1016/S0022-0248(00)00440-1

    Article  ADS  Google Scholar 

  10. D. Irzhak and D. Roshchupkin, J. Appl. Crystallogr. 51, 1174 (2018). https://doi.org/10.1107/S1600576718009184

    Article  Google Scholar 

  11. I. A. Kaurova, G. M. Kuz’micheva, V. B. Rybakov, et al., Inorg. Mater. 46 (9), 988 (2010). https://doi.org/10.1134/S0020168510090128

    Article  Google Scholar 

  12. I. A. Kaurova, G. M. Kuz’micheva, and A. B. Dubovskii, Inorg. Mater. 46 (10), 1131 (2010). https://doi.org/10.1134/S0020168510100195

    Article  Google Scholar 

  13. G. M. Kuz’micheva, I. A. Kaurova, V. B. Rybakov, et al., Cryst. Res. Technol. 47 (2), 131 (2012). https://doi.org/10.1002/crat.201100356

    Article  Google Scholar 

  14. I. A. Kaurova, Candidate’s Dissertation in Chemistry (MITKhT, Moscow, 2010).

  15. G. M. Kuz’micheva, O. Zakharko, E. A. Tyunina, et al., Crystallogr. Rep. 54 (2), 279 (2009).

    Article  ADS  Google Scholar 

  16. I. A. Kaurova, G. M. Kuz’micheva, and A. Kusson, Crystallogr. Rep. 54 (2), 279 (2009). https://doi.org/10.1134/S1063774509020163

    Article  ADS  Google Scholar 

  17. W. L. Bond, Acta Crystallogr. 13, 814 (1960). https://doi.org/10.1107/S0365110X60001941

    Article  Google Scholar 

  18. P. A. Filatov, Extended Abstract of Cand. Sci. Dissertation in Physics and Mathematics (MISiS, Moscow, 2008).

  19. P. V. Gureva, N. V. Marchenkov, A. N. Artemev, et al., J. Appl. Crystallogr. 53, 734 (2020). https://doi.org/10.1107/S1600576720005154

    Article  Google Scholar 

  20. https://newpiezo.com/

  21. http://kcsni.nrcki.ru/pages/en/source/index.shtml

  22. P. V. Gur’eva, N. V. Marchenkov, A. N. Artem’ev, et al., Instrum. Exp. Tech. 64 (2), 308 (2021). https://doi.org/10.1134/S0020441221010243

    Article  Google Scholar 

  23. E. E. Vainshtein and M. M. Kakhana, Reference Tables on X-Ray Spectroscopy (Izd-vo AN SSSR, Moscow, 1953) [in Russian].

    Google Scholar 

  24. https://en.wikipedia.org/wiki/Chi-square_distribution

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Funding

This study was supported by the Russian Foundation for Basic Research, project no. 19-32-90136.

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Authors and Affiliations

  1. National Research Centre “Kurchatov Institute”, 123182, Moscow, Russia

    P. V. Gureva, N. V. Marchenkov, A. N. Artemev & A. A. Demkiv

  2. Federal Scientific and Research Center “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

    N. V. Marchenkov

  3. Moscow State University of Fine Chemical Technologies, 119435, Moscow, Russia

    G. M. Kuz’micheva

Authors
  1. P. V. Gureva
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  2. N. V. Marchenkov
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  3. G. M. Kuz’micheva
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  4. A. N. Artemev
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  5. A. A. Demkiv
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Correspondence to P. V. Gureva.

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Translated by E. Bondareva

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Gureva, P.V., Marchenkov, N.V., Kuz’micheva, G.M. et al. Synchrotron Study of the Effect of Tantalum Variation on the Piezoelectric Modulus d11 in Langatate Crystal. Crystallogr. Rep. 67, 845–850 (2022). https://doi.org/10.1134/S1063774522060098

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  • DOI: https://doi.org/10.1134/S1063774522060098

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