Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]2

  • STRUCTURE OF INORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

Crystals of a new triclinic iodate with the formula (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 (sp. gr. P\(\bar {1}\)) were prepared by hydrothermal synthesis. These crystals are isostructural with the previously characterized iodate Sr[IO3]2. Reliable structural data were obtained by applying corrections for absorption and twinning. The structure contains isolated umbrella-like [IO3]– groups typical of iodates, which are located at the same levels in layers parallel to the bc plane. The sites between these layers are isomorphously occupied by large Pb and Ba cations in a nearly 1 : 1 ratio, thereby allowing the retention of the structure type of Sr-containing compounds despite the incorporation of a larger Ba atom into the Pb site. This fact can be used in the synthesis of new iodates.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. C.-F. Sun, B.-P. Yang, and J.-G. Mao, Sci. China: Chem. 54, 911 (2011).

    Article  Google Scholar 

  2. C.-L. Hu and J.-G. Mao, Coord. Chem. 288, 1 (2015).

    Article  Google Scholar 

  3. Z. Cao, Y. Yue, J. Yao, et al., Inorg. Chem. 50, 12818 (2011).

    Article  Google Scholar 

  4. X. Xu, B-P. Yang, C. Huang, and J.-G. Mao, Inorg. Chem. 53, 1756 (2014).

    Article  Google Scholar 

  5. D. Phanon and I. Gautier-Luneau, Angew. Chem. Int. Ed. 46, 8488 (2007).

    Article  Google Scholar 

  6. K. M. Ok and P. S. Halasyamani, Angew. Chem. Int. Ed. 43, 5489 (2004).

    Article  Google Scholar 

  7. E. L. Belokoneva, S. Yu. Stefanovich, O. V. Dimitrova, et al., Inorg. Chem. 56, 1186 (2017).

    Article  Google Scholar 

  8. T. Hu, L. Qin, F. Kong, et al., Inorg. Chem. 48, 2193 (2009).

    Article  Google Scholar 

  9. F.-F. Mao, C.-L. Hu, B.-X. Li, and J.-G. Mao, Inorg. Chem. 56, 14357 (2017).

    Article  Google Scholar 

  10. M. Zhang, C. Hu, T. Abudouwufu, el. al., Chem. Mater. 30, 1136 (2018).

    Article  Google Scholar 

  11. H. Liu, Q. Wu, X. Jiang, et al., Angew. Chem. Int. Ed. 56, 9492 (2017).

    Article  Google Scholar 

  12. X. Chen, W. Xiao, X. Chang, and H. Zang, J. Alloys Compd. 381, 229 (2004).

    Article  Google Scholar 

  13. V. Petricek, K. Maly, B. Kratochvil, et al., Acta Crystallogr. B 24, 1968 (1982).

    Google Scholar 

  14. T. Kellersohn, E. Alici, D. Esser, and H. D. Lutz, Z. Kristallogr. 203, 225 (1993).

    Google Scholar 

  15. E. L. Belokoneva and O. V. Dimitrova, Crystallogr. Rep. 59 (2), 174 (2014).

    Article  ADS  Google Scholar 

  16. A. M. M. Lanfredi, M. A. Pellinghelli, and A. Tiripicchio, Acta Crystallogr. B 24, 1968 (1982).

    Google Scholar 

  17. H. D. Lutz, E. Alici, and W. Buchmeier, Z. Anorg. Allg. Chem. 535, 31 (1986).

    Article  Google Scholar 

  18. Inorganic Crystal Structure Data Base: ICSD (Fachinformationzentrum (FIZ), Karlsruhe, 2011), I version.

  19. Agilent Technologies, CrysAlisPro Software System, Version 1.171.37.35 (Agilent Technologies, Oxford, UK, 2014).

  20. G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

Download references

ACKNOWLEDGMENTS

We are grateful to N.V. Zubkova for help in obtaining experimental data and applying necessary correction and researchers of the Laboratory of Local Methods of Substance Investigation of the Moscow State University for determining the composition of the crystals.

Funding

The study was supported by the Russian Foundation for Basic Research (project no. 17-03-000886a).

Author information

Authors and Affiliations

  1. Moscow State University, 119992, Moscow, Russia

    E. L. Belokoneva, O. V. Reutova, O. V. Dimitrova & A. S. Volkov

Authors
  1. E. L. Belokoneva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. V. Reutova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Dimitrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. L. Belokoneva.

Additional information

Translated by T. Safonova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Belokoneva, E.L., Reutova, O.V., Dimitrova, O.V. et al. Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]2. Crystallogr. Rep. 64, 590–593 (2019). https://doi.org/10.1134/S1063774519040047

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774519040047

Search

Navigation