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Non-isothermal crystallization kinetics of Fe2O3–CaO–SiO2 glass containing nucleation agent P2O5/TiO2

  • Nanomaterials, Ceramics
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An Erratum to this article was published on 01 May 2017

Abstract

Fe2O3–CaO–SiO2 glass ceramics containing nucleation agent P2O5/TiO2 were prepared by sol-gel method. The samples were characterized by X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The activation energy and kinetic parameters for crystallization of the samples were calculated by the Johnson-Mehi-Avrami (JMA) model and Augis-Bennett method according to the results of DSC. The results showed that the crystallization mechanism of Fe2O3–CaO–SiO2 glass, whose non-isothermal kinetic parameter n = 2.3, was consistent with surface crystallization of the JMA model. The kinetics model function of Fe2O3–CaO–SiO2 glass, f(α) = 2.3(1–α)[–ln(1–α)]0.57, was also obtained. The addition of nucleation agent P2O5/TiO2 could reduce the activation energy, which made the crystal growth modes change from onedimensional to three-dimensional.

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Authors and Affiliations

  1. Department of Material Chemistry, Huzhou University, Huzhou, 313000, China

    Bin Li, Yongya Wang, Wenqin Luo & Jingfen Li

  2. Orthopedic Department, Huzhou Central Hospital, Huzhou, 313000, China

    Jianyou Li

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  1. Bin Li
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  2. Yongya Wang
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  3. Wenqin Luo
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  4. Jingfen Li
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  5. Jianyou Li
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Correspondence to Bin Li.

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The article is published in the original.

An erratum to this article is available at http://dx.doi.org/10.1134/S106377451733001X.

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Li, B., Wang, Y., Luo, W. et al. Non-isothermal crystallization kinetics of Fe2O3–CaO–SiO2 glass containing nucleation agent P2O5/TiO2 . Crystallogr. Rep. 62, 260–264 (2017). https://doi.org/10.1134/S1063774517020080

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  • DOI: https://doi.org/10.1134/S1063774517020080

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