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Synthesis and crystal structure of a copper complex with (E)-2-(4-(1H-1,2,4-triazol-1-yl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one ligand

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Abstract

The title compound, C35H23CuF6N3O5S2 (1), was synthesized by the reaction of Cu(tta)2 and L 1, (L 1 = (E)-2-(4-(1H-1,2,4-triazol-1-yl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one) in the dichloromethane solution. It crystallizes in the monoclinic, space group P21/c with a = 33.8388(5), b = 9.3874(2), c = 21.8194(4) Å, β = 95.522(2), V = 6898.9(2) Å3, Z = 8, D x = 1.554 Mg/m3, F(000) = 3272, µ = 0.834 mm–1, R 1 = 0.0639, wR 2 = 0.1637. The copper(II) ion of 1 is in a distorted square-pyramidal environment with four O atoms of the two tta ligands and one N atom of triazole ligand L 1. Single-crystal X-ray diffraction data revealed that the hydrogen bonds, weak C–H···π and π···π interactions in the crystals link the coordination units to form 3D supramolecular structures.

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References

  1. M. E. Katsarou, E. K. Efthimiadou, G. Psomas, et al., J. Med. Chem., 51, 470 (2008).

    Article  Google Scholar 

  2. M. M. Ibrahim, J. Mol. Struct. 990, 227 (2011).

    Article  ADS  Google Scholar 

  3. S. Patitungkho, S. Adsule, P. Dandawate, et al., Bioorg. Med. Chem. Lett. 21, 1802 (2011).

    Article  Google Scholar 

  4. R. S. Hoonur, B. R. Patil, D. S. Badiger, et al., Eur. J. Med. Chem. 45, 227 (2011).

    Google Scholar 

  5. F. J. Muñoz-Lara, A. B. Gaspar. M. C. Muñoz, et al., Inorg. Chem. 51, 13078 (2012).

    Article  Google Scholar 

  6. B.-Y. Liu, F. Liu, L.-H. Lv, et al., CrystEngCommun 15, 447 (2013).

    Article  ADS  Google Scholar 

  7. D. Sarma, V. Srivastava, and S. Natarajan, Dalton Trans. 41, 4135 (2012).

    Article  Google Scholar 

  8. J.-P. Zhang, Y.-B. Zhang, and J.-B. Lin, Chem. Rev. 112, 1001 (2012).

    Article  Google Scholar 

  9. I. M. Lagoja, C. Pannecouque, L. Musumeci, et al., Helv. Chem. Acta 85, 1883 (2002).

    Article  Google Scholar 

  10. S. Papakostantinou-Garoufalias, N. Pouli, P. Marakos, et al., Farmaco 57, 973 (2002).

    Article  Google Scholar 

  11. Y. A. Al-Soud, Heteroat. Chem. 18, 443 (2007).

    Article  Google Scholar 

  12. A. Almasirad, S. A. Tabatabai, M. Faizi, et al., Bioorg. Med. Chem. Lett. 14, 6057 (2004).

    Article  Google Scholar 

  13. G.-F. Wang, S.-W. Sun, Q.-P. Han, et al., Crystallogr. Rep. 58, 994 (2014).

    Google Scholar 

  14. G.-F. Wang, Z. Naturforsch. 70B, 165 (2015).

    Google Scholar 

  15. E. Fursova, G. Romanenko, V. Ikorskii, et al., Polyhedron 22, 1957 (2003).

    Article  Google Scholar 

  16. E. Colacio, J. M. Dominguez-Vera, M. Ghazi, et al., Eur. J. Inorg. Chem. 1999, 441, (1999).

    Article  Google Scholar 

  17. E. Colacio, M. Ghazi, R. Kivekas, et al., Inorg. Chem. 39, 2770 (2000).

    Article  Google Scholar 

  18. N. Matsumoto, T. Akui, H. Murakami, et al., J. Chem. Soc., Dalton Trans. 1021 (1988).

    Google Scholar 

  19. S. Delgado, A. Muñoz, M. E. Medina, et al., Inorg. Chim. Acta, 359, 109 (2006).

    Article  Google Scholar 

  20. E. Colacio, J.-M. Dominguez-Vera, M. Ghazi, et al., Inorg. Chem. 37, 3040 (1998).

    Article  Google Scholar 

  21. F. Zhu, H. W. Schmalle, B. Fischer, et al., Inorg. Chem. 37, 1161 (1998).

    Article  Google Scholar 

  22. D. Pogozhev, S. A. Baudron, and M. W. Hosseini, Inorg. Chem. 49, 331 (2010).

    Article  Google Scholar 

  23. R.-N. Liu, L.-C. Li, X.-Y. Xing, et al., Inorg. Chim. Acta. 362, 2253 (2009).

    Article  Google Scholar 

  24. J. B. Gilroy, B. D. Koivisto, R. McDonald, et al., J. Mater. Chem. 16, 2618 (2006).

    Article  Google Scholar 

  25. L. M. Field and P. M. Lahti, Inorg. Chem. 42, 7447 (2003).

    Article  Google Scholar 

  26. B. Li, J. Zou, C. Duan, et al., Acta. Crystallogr. C 55, 165 (1999).

    Article  Google Scholar 

  27. Z.-D. Li, X.-Z. You, Y.-G. Yao, et al., Acta. Chem. Sin. 45, 260 (1987).

    Google Scholar 

  28. W.-Q. Geng, H.-P. Zhou, L.-H. Cheng, et al., Polyhedron 31, 738 (2012).

    Article  Google Scholar 

  29. CrysAlisPro Version 1.171.35.19 (Agilent Technologies, Santa Clara, CA, USA, 2011).

  30. G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, Beijing, 044000, P. R. China

    Shu-Wen Sun & Gao-Feng Wang

  2. Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Heilongjiang, 150080, P. R. China

    Xiao Zhang

Authors
  1. Shu-Wen Sun
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  2. Xiao Zhang
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  3. Gao-Feng Wang
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Correspondence to Shu-Wen Sun.

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Sun, SW., Zhang, X. & Wang, GF. Synthesis and crystal structure of a copper complex with (E)-2-(4-(1H-1,2,4-triazol-1-yl)benzylidene)-3,4-dihydronaphthalen-1(2H)-one ligand. Crystallogr. Rep. 60, 1044–1048 (2015). https://doi.org/10.1134/S1063774515070275

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  • DOI: https://doi.org/10.1134/S1063774515070275

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