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Synthesis and crystal structure of the zinc(II) coordination polymer with 1,1-(1,4-butanediyl)bis(imidazole)

  • Structure of Organic Compounds
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Abstract

The self-assembly of 1,1-(1,4-butanediyl)bis(imidazole) (L) with [ZnL(NO3)2] gives the new coordination polymer C10H14N6O6Zn (1). The crystal structure of 1 was determined by X-ray diffraction. It crystallizes in space group \(P\bar 1\) with a = 7.9975(11), b = 8.4392(11), c = 13.8326(19) Å; α = 76.876(2)°, β = 85.892(2)°, γ = 71.0440(10)° and Z = 2. In the complex, Zn atom is coordinated to two nitrogen atoms from two molecules of L and to two oxygen atoms from two nitrate groups. Each L molecule is coordinated to two Zn atom, acting as a bridging ligand. The Zn-N bond lengths are 1.995(3) and 2.014(2) Å, and Zn-O bond lengths are 1.944(2) and 1.958(3) Å.

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Authors and Affiliations

  1. Key Laboratory of Nuclear Medicine, Ministry of Health, Jiangsu Key Laboratory of Molecular Nuclear Medicine, Jiangsu Institute of Nuclear Medicine, Wuxi, Jiangsu, 214063, China

    F. Chen, D. -H. Pan, Y. -P. Xu, R. -L. Yang, L. -Z. Wang, M. Yang & S. -N. Luo

  2. Nanjing Medical University, Nanjing, Jiangsu, 210029, China

    F. Chen & S. -N. Luo

Authors
  1. F. Chen
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  2. D. -H. Pan
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  3. Y. -P. Xu
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  4. R. -L. Yang
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  5. L. -Z. Wang
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  6. M. Yang
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  7. S. -N. Luo
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Correspondence to M. Yang.

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Chen, F., Pan, D.H., Xu, Y.P. et al. Synthesis and crystal structure of the zinc(II) coordination polymer with 1,1-(1,4-butanediyl)bis(imidazole). Crystallogr. Rep. 59, 1010–1012 (2014). https://doi.org/10.1134/S1063774514070074

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  • DOI: https://doi.org/10.1134/S1063774514070074

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