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Synthesis and Structural Characterization of a Zinc Cooridination Polymer with bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone and 4-Nitrophthalate

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Abstract

A zinc coordination polymer with the formula {[Zn(npa)(L1)]·2H2O}n (1) (L1 = bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2npa = 4-nitrophthalic acid) is synthesized and characterized by IR, elemental analysis, and single crystal X-ray diffraction. The Zn2+ ion has a distorted tetrahedral environment with two O atoms from two npa ligands and two N atoms from two L1 ligands. Each L1 acts as a bridging ligand to link the neighboring [Zn(npa)]2 dimers to form a 1D ladder.

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Correspondence to G.-F. Wang.

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Original Russian Text © 2018 X. Yang, G.-F. Wang, L. Yang.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 7, pp. 1742–1745, September-October, 2018.

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Yang, X., Wang, GF. & Yang, L. Synthesis and Structural Characterization of a Zinc Cooridination Polymer with bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone and 4-Nitrophthalate. J Struct Chem 59, 1684–1687 (2018). https://doi.org/10.1134/S0022476618070235

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  • DOI: https://doi.org/10.1134/S0022476618070235

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