Skip to main content
Log in

Mechanical modification of β-AgI nanocrystals

  • Nanomaterials
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

A nanostructured AgI powder has been synthesized. The structure, sizes, and shapes of nanoparticles of the initial powder and a powder modified in a VIBRATOR GM-945B vibration ball mill have been investigated by SEM, X-ray diffraction, and differential thermal analysis. A hypothesis of the structure and microscopic mechanism of structural transformations in the materials under study is proposed. Particular attention is paid to the ac ionic conduction of silver iodide particles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E. G. Avakumov, Mechanical Methods for Activating Chemical Processes (Nauka, Novosibirsk, 1986) [in Russian].

    Google Scholar 

  2. P. Yu. Butyagin, Usp. Khim. 63(12), 1031 (1994).

    Article  Google Scholar 

  3. V. V. Boldyrev, Usp. Khim. 75(3), 203 (2006).

    Article  Google Scholar 

  4. R. S. Saifullin, Physical Chemistry of Inorganic Polymers and Composites (Khimiya, Moscow, 1990) [in Russian].

    Google Scholar 

  5. N. S. Enikolopov, Usp. Khim. 60(3), 586 (1991).

    Article  Google Scholar 

  6. G. Heinicke, Tribochemistry (Carl Hanser, Munich, 1985).

    Google Scholar 

  7. J.-S. Lee, St. Adams, and J. Maier, Solid State Ionics 136–137, 1261 (2000).

    Article  Google Scholar 

  8. N. F. Uvarov, Zh. Prikl. Khim. 73(6), 307 (2000).

    MathSciNet  Google Scholar 

  9. Y.-G. Guo, J.-S. Lee, and J. Maier, Solid State Ionics 177, 2467 (2006).

    Article  Google Scholar 

  10. N. Sata, N. Y. Jin-Phillipp, K. Eberl, and J. Majer, Solid State Ionics 154–155, 497 (2002).

    Article  Google Scholar 

  11. C. C. Liang, J. Electrochem. Soc. 120, 1289 (1973).

    Article  Google Scholar 

  12. N. F. Uvarov and V. V. Boldyrev, Usp. Khim. 70(4), 970 (2001).

    Article  Google Scholar 

  13. Yu. S. Tver’yanovich, M. D. Bal’makov, V. V. Tomaev, et al., Fiz. Khim. Stekla 34(2), 196 (2008).

    Google Scholar 

  14. V. V. Tomaev, Yu. S. Tver’yanovich, M. D. Bal’makov, et al., Fiz. Khim. Stekla 35(6), 881 (2009).

    Google Scholar 

  15. V. V. Tomaev, A. T. Nakusov, and E. G. Zemtsova, Fiz. Khim. Stekla 36(1), 118 (2009).

    Google Scholar 

  16. V. V. Tomaev, Yu. S. Tver’yanovich, M. D. Bal’makov, et al., Fiz. Khim. Stekla 36(4), 565 (2009).

    Google Scholar 

  17. A. K. Ivanov-Shits and I. V. Murin, Ionics of Solids (Izd-vo SPbGU, 2000), Vol. 1 [in Russian].

  18. A. K. Ivanov-Shits and I. V. Murin, Ionics of Solids (Izd-vo SPbGU, 2010), Vol. 2 [in Russian].

  19. E. A. Ukshe and N. G. Bukun, Solid Electrolytes (Nauka, Moscow, 1977) [in Russian].

    Google Scholar 

  20. Yu. Ya. Gurevich and Yu. I. Kharkats, Superionic Conductors (Nauka, Moscow, 1992) [in Russian].

    Google Scholar 

  21. G. Burley, American Mineralogist 48(6), 1266 (1963).

    Google Scholar 

  22. Electronic Base of Powder X-Ray Diffraction Data PDF-2.

  23. A. R. West, Solid State Chemistry and Its Applications (Wiley, New York, 1984; Mir, Moscow, 1988, Part 1).

    Google Scholar 

  24. P. A. Thiessen, K. Meyer, and G. Heinicke, Grundlagen der Tribochemie (Akad. Verlag, Berlin, 1996), Part 1, p. 194.

    Google Scholar 

  25. K. Meyer, Physikalisch-chemische Kristallographie (VEB Deutscher Verlag für Grundstoffindustrie, Leipzig, 1968; Metallurgiya, Moscow, 1972).

    Google Scholar 

  26. J. Gibbs, Thermodynamics and Statistical Mechanics (Nauka, Moscow, 1982) [in Russian].

    Google Scholar 

  27. M. Volmer, Kinetik der Phasenbildung (Theodor Steinkopff, Dresden, 1939.

    Google Scholar 

  28. R. A. Laudise and R. Parker, The Growth of Single Crystals (Academic, New York, 1970; Mir, Moscow, 1974).

    Google Scholar 

  29. C. E. Mees and T. H. James, Theory of the Photographic Process (Macmillan, London, 1971; Khimiya, Leningrad, 1980).

    Google Scholar 

  30. I. Kh. Akopyan, B. V. Novikov, and S. A. Soboleva, Phys. Solid State 40(5), 784 (1998).

    Article  ADS  Google Scholar 

  31. S. Schlag and H. F. Eicke, Solid State Commun. 91(11), 883 (1994).

    Article  ADS  Google Scholar 

  32. G. Ya. Akimov, V. M. Timchenko, and I. V. Gorelik, Phys. Solid State 36(12), 1906 (1994).

    ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. V. Tomaev.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tomaev, V.V., Tver’yanovich, Y.S. & Bal’makov, M.D. Mechanical modification of β-AgI nanocrystals. Crystallogr. Rep. 57, 948–954 (2012). https://doi.org/10.1134/S106377451207022X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106377451207022X

Keywords

Navigation