Skip to main content
SpringerLink
Log in

Crystal chemistry of silicates with three-layer TOT and HOH modules of layered, chainlike, and mixed types

  • Reviews
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

In view of new data on the chemical composition and structure of a series of natural layered silicates containing three-layer blocks and their corresponding microporous minerals with related fragments, their structural features; the structural conditionality of their properties; their transformation in the presence of isomorphism, decationation, and hydration; and the problems related to typomorphism and some other questions urgent for modern mineralogy have been considered. The structures are described in terms of threelayer modules of different forms and dimensions that are present in these structures. The composition and design of the general structural base of related series—three-layer modules forming layered or linear radicals—are also discussed. The minerals of these families differ in chemical composition, symmetry, and unit-cell parameters, as well as in the topological features associated with the type of condensation of the Si tetrahedra into layers or ribbons and the degree of condensation of M polyhedra in the central part of blocks: from layers and octahedral ribbons of different widths to chains and isolated polyhedra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. V. Belov, Essays on Structural Mineralogy (Nedra, Moscow, 1976) [in Russian].

    Google Scholar 

  2. G. Ferraris, EMU Notes in Mineralogy (1997), Vol. 1, p. 275.

    Google Scholar 

  3. G. Ferraris and A. Gula, Rev. Mineral. Geochem. 57, 69 (2005).

    Article  Google Scholar 

  4. G. Ferraris, Z. Kristallogr. 223, 76 (2008).

    Article  Google Scholar 

  5. Handbook of Minerals (Nauka, Moscow, 1992), Vol. IV, Iss. 1 [in Russian].

  6. Handbook of Minerals (Nauka, Moscow, 1992), Vol. IV, Iss. 2 [in Russian].

  7. G. Ferraris and G. Ivaldi, Rev. Mineral. Geochem. 46(1), 117 (2002).

    Article  Google Scholar 

  8. M. Rieder, G. Cavazzini, Yu. S. D’yakonov, et al., Can. Mineral. 36, 905 (1998).

    Google Scholar 

  9. H. N. Nickel and J. D. Grice, Can. Mineral. 36, 913 (1998).

    Google Scholar 

  10. V. G. Evsyunin, A. A. Kashaev, and R. K. Rastsvetaeva, Crystallogr. Rep. 42(4), 571 (1997).

    ADS  Google Scholar 

  11. M. F. Brigatti, E. Galli, and L. Poppi, Am. Mineral. 76, 1174 (1991).

    Google Scholar 

  12. M. F. Brigatti and L. Poppi, Eur. J. Mineral. 5, 856 (1993).

    Google Scholar 

  13. F. Scordari, G. Ventruti, A. Sabato, et al., Eur. J. Mineral. 18, 379 (2006).

    Article  Google Scholar 

  14. G. Cruciani and P. F. Zanazzi, Am. Mineral. 79, 289 (1994).

    Google Scholar 

  15. J. C. Greenwood, Mineral. Mag. 62, 687 (1998).

    Article  Google Scholar 

  16. L. N. Kogarko, Y. A. Uvarova, E. Sokolova, et al., Can. Mineral. 43, 1501 (2005).

    Article  Google Scholar 

  17. N. V. Chukanov, K. A. Rozenberg, R. K. Rastsvetaeva, and Sch. Mökkel, New Data În Minerals (OOO Al’tum, Moscow, 2009), Iss. 43, p. 72 [in Russian].

    Google Scholar 

  18. N. V. Chukanov, A. A. Mukhanova, R. K. Rastsvetaeva, et al., Zap. Vseross. Mineral. O-va 139(3), 31 (2010).

    Google Scholar 

  19. R. H. Mitchell and P. C. Burns, Can. Mineral. 31, 769 (2001).

    Article  Google Scholar 

  20. S. Merlino, Mineral. Mag. 52, 247 (1988).

    Article  Google Scholar 

  21. E. E. Lachowski, L. W. Murray, and H. F. W. Taylor, Mineral. Mag. 43, 333 (1979).

    Article  Google Scholar 

  22. S. Merlino, Mineral. Mag. 52, 377 (1988).

    Article  Google Scholar 

  23. V. I. Kudryashova, Dokl. Akad. Nauk SSSR, 171(5), 1167 (1966).

    Google Scholar 

  24. R. K. Rastsvetaeva, S. M. Aksenov, and N. V. Chukanov, Dokl. Ross. Akad. Nauk, 437(4), 499 (2011).

    Google Scholar 

  25. R. K. Rastsvetaeva and V. I. Andrianov, Sov. Phys. Crystallogr. 31(1), 44 (1986).

    Google Scholar 

  26. Ya.-S. Guan’, V. I. Simonov, and N. V. Belov, Dokl. Akad. Nauk SSSR, 149(6), 1416 (1963).

    Google Scholar 

  27. R. K. Rastsvetaeva, R. A. Tamazyan, E. V. Sokolova, and D. I. Belakovskii, Sov. Phys. Crystallogr. 36(2), 186 (1991).

    Google Scholar 

  28. P. Nemeth, G. Ferraris, G. Radnoczi, and O. A. Ageeva, Can. Mineral. 43, 973 (2005).

    Article  Google Scholar 

  29. R. K. Rastsvetaeva, S. M. Aksenov, I. A. Verin, and I. S. Lykova, Crystallogr. Rep. 56(3), 407 (2011).

    Article  ADS  Google Scholar 

  30. T. S. Ercit, M. A. Cooper, and F. C. Hawtorne, Can. Mineral. 36, 1311 (1998).

    Google Scholar 

  31. R. K. Rastsvetaeva, M. I. Sirota, and N. V. Belov, Sov. Phys. Crystallogr. 20(2), 158 (1975).

    Google Scholar 

  32. R. K. Rastsvetaeva, Sov. Phys. Crystallogr. 31(6), 633 (1986).

    Google Scholar 

  33. R. K. Rastsvetaeva, Zap. Vseross. Mineral. O-va 117(6), 696 (1988).

    Google Scholar 

  34. R. K. Rastsvetaeva, Sov. Phys. Crystallogr. 34(4), 528 (1989).

    Google Scholar 

  35. A. M. McDonald, J. D. Chao, and G. Y. Grice, Can. Mineral. 38, 649 (2000).

    Article  Google Scholar 

  36. A. N. Chernov, V. V. Ilyukhin, B. A. Maksimov, and N. V. Belov, Sov. Phys. Crystallogr. 16(1), 65 (1971).

    Google Scholar 

  37. I. V. Pekov, N. V. Chukanov, I. M. Kulikova, and D. L. Belakovskii, Zap. Vseross. Mineral. O-va 135, 52 (2006).

    Google Scholar 

  38. R. K. Rastsvetaeva, Sov. Phys. Dokl. 16(1), 182 (1971).

    ADS  Google Scholar 

  39. Kh. Zhu, R. K. Rastsvetaeva, A. P. Khomyakov, et al., Crystallogr. Rep. 47(1), 43 (2002).

    Article  ADS  Google Scholar 

  40. R. K. Rastsvetaeva, E. V. Sokolova, and A. I. Gusev, Mineral. Zh. 12(5), 25 (1990).

    Google Scholar 

  41. R. K. Rastsvetaeva and N. V. Chukanov, Dokl. Phys. 44(4), 492 (1999).

    Google Scholar 

  42. N. V. Chukanov, M. M. Moiseev, I. V. Pekov, et al., Zap. Vseross. Mineral. O-va, No. 1, 59 (2004).

  43. R. K. Rastsvetaeva and M. D. Dorfman, Crystallogr. Rep. 40(6), 951 (1995).

    ADS  Google Scholar 

  44. Z. Z. Peng, J. Zhang, and J. Shu, Kexue Tongbao 29, 237 (1984).

    Google Scholar 

  45. R. K. Rastsvetaeva, V. G. Evsyunin, and A. A. Konev, Crystallogr. Rep. 40(3), 472 (1995).

    ADS  Google Scholar 

  46. S. Matsubara, Mineral. J. 10, 107 (1980).

    Article  Google Scholar 

  47. E. Sokolova and F. C. Hawthorne, Can. Mineral. 39, 1275 (2001).

    Article  Google Scholar 

  48. P. B. Moore, Lithos. 4, 137 (1971).

    Article  ADS  Google Scholar 

  49. E. Sokolova, F. Camara, F. C. Hawthorn, and Y. Abdu, Eur. J. Mineral. 21, 871 (2009).

    Article  Google Scholar 

  50. R. K. Rastsvetaeva, E. M. Eskova, V. D. Dusmatov, et al., Eur. J. Mineral. 20, 289 (2008).

    Article  Google Scholar 

  51. N. A. Yamnova, Yu. K. Egorov-Tismenko, and I. V. Pekov, Crystallogr. Rep. 43(3), 401 (1998).

    ADS  Google Scholar 

  52. R. K. Rastsvetaeva, N. V. Chukanov, and K. A. Rozenberg, Crystallogr. Rep. 53(4), 553 (2008).

    Article  ADS  Google Scholar 

  53. F. Camara, E. Sokolova, and F. Nieto, Mineral. Mag. 73, 855 (2009).

    Article  Google Scholar 

  54. G. Ferraris, G. Ivaldi, D. Yu. Puscharovsky, et al., Can. Mineral. 39, 1307 (2001).

    Article  Google Scholar 

  55. A. P. Khomyakov, Mineralogy of Ultraagpaite Alkaline Rocks (Nauka, Moscow, 1990) [in Russian].

    Google Scholar 

  56. P. Nemeth, G. Ferraris, I. Dodony, et al., Acta Crystallogr. A 60, 196 (2004).

    Article  Google Scholar 

  57. S. V. Krivovichev and T. Armbruster, Am. Mineral. 89, 314 (2004).

    Google Scholar 

  58. E. V. Sokolova and F. C. Hawthorne, Can. Mineral. 43, 1527 (2005).

    Article  Google Scholar 

  59. Yu. P. Men’shikov, A. P. Khomyakov, L. I. Polezhaeva, and R. K. Rastsvetaeva, Zap. Vseross. Mineral. O-va 125(1), 120 (1996).

    Google Scholar 

  60. E. V. Sokolova, Yu. K. Egorov-Tismenko, and A. P. Khomyakov, Sov. Phys. Dokl. 33(5), 711 (1988).

    ADS  Google Scholar 

  61. G. Ferraris, E. Belluso, A. Gula, et al., Can. Mineral. 39, 1665 (2001).

    Article  Google Scholar 

  62. F. Camara and E. Sokolova, Mineral. Mag. 73, 753 (2009).

    Article  Google Scholar 

  63. E. V. Sokolova, Yu. K. Egorov-Tismenko, L. A. Pautov, and D. I. Belakovskii, Zap. Vses. Mineral. O-va 118(4), 81 (1989).

    Google Scholar 

  64. N. V. Chukanov and I. V. Pekov, Rev. Mineral. Geochem. 57, 105 (2005).

    Article  Google Scholar 

  65. S. Vrana, M. Rieder, and M. Gunter, Eur. J. Mineral. 4, 35 (1992).

    Google Scholar 

  66. T. Peng and C. Chang, Sci. Sinica 14(12), 1827 (1965).

    Google Scholar 

  67. I. V. Pekov and N. V. Chukanov, Rev. Mineral. Geochem. 57, 145 (2005).

    Article  Google Scholar 

  68. I. V. Bussen, A. P. Denisov, N. I. Zabavnikova, et al., Zap. Vses. Mineral. O-va 102(4), 423 (1973).

    Google Scholar 

  69. A. P. Khomyakov, Constitution and Properties of Minerals (Naukova Dumka, Kiev, 1976), Iss. 10, p. 96 [in Russian].

    Google Scholar 

  70. Yu. N. Drozdov, N. G. Batalieva, A. A. Voronkov, and E. A. Kuz’min, Sov. Phys. Dokl. 19(1), 258 (1974).

    ADS  Google Scholar 

  71. J. G. Ronsbo, E. S. Leonardsen, O. V. Petersen, and O. Johnsen, Neues Jahrb. Mineral. 451 (1983).

  72. W. Hong and P. Fu, Geochemistry (China) 1, 458 (1982).

    Google Scholar 

  73. G. Y. Chao, Can. Mineral. 29, 235 (1991).

    Google Scholar 

  74. E. M. Es’kova, V. D. Dusmatov, R. K. Rastsvetaeva, et al., Zap. Vseross. Mineral. O-va, No. 2, 60 (2003).

  75. K. A. Rozenberg, R. K. Rastsvetaeva, and I. A. Verin, Crystallogr. Rep. 48(3), 384 (2003).

    Article  ADS  Google Scholar 

  76. D. Holtstam, GFF 120(4), 373 (1998).

    Article  Google Scholar 

  77. R. K. Rastsvetaeva, Priroda, No. 9, 41 (2007).

  78. C. C. Shristiansen, O. Johnsen, and E. Makovicky, Can. Mineral. 41, 1203 (2003).

    Article  Google Scholar 

  79. D. Atencio, J. M. V. Coutinho, M. N. C. Ulbrich, et al., Can. Mineral. 37(1), 91 (1999).

    Google Scholar 

  80. C. C. Shristiansen, R. A. Gault, J. D. Grice, and O. Johnsen, Eur. J. Mineral. 15, 551 (2003).

    Article  Google Scholar 

  81. V. I. Simonov and N. V. Belov, Sov. Phys. Crystallogr. 4(2), 146 (1959).

    Google Scholar 

  82. M. Belezza, M. Franzini, A. O. Larsen, et al., Eur. J. Mineral. 16, 971 (2004).

    Article  Google Scholar 

  83. M. Bellezza, S. Merlino, and N. Perchiazzi, Can. Mineral. 47, 897 (2009).

    Article  Google Scholar 

  84. R. K. Rastsvetaeva, B. E. Borutskii, and Z. V. Shlyukova, Sov. Phys. Crystallogr. 36(3), 349 (1991).

    Google Scholar 

  85. M. Kadiyski, T. Armbruster, E. V. Galuskin, et al., Am. Mineral. 93, 456 (2008).

    Article  Google Scholar 

  86. O. V. Petersen, J. G. Ronsbo, and E. S. Leonardsen, Neues Jahrb. Mineral. 2, 84 (1989).

    Google Scholar 

  87. R. K. Rastsvetaeva, D. Yu. Pushcharovsky, and D. Attensio, Crystallogr. Rep. 40(4), 574 (1995).

    ADS  Google Scholar 

  88. P. C. Piilonen, A. E. Lalonde, A. M. McDonald, and R. A. Gault, Can. Mineral. 38, 627 (2000).

    Article  Google Scholar 

  89. P. C. Piilonen, A. M. McDonald, and A. E. Lalonde, Eur. J. Mineral. 13, 973 (2001).

    Article  Google Scholar 

  90. F. Camara, E. Sokolova, Y. Abdu, and F. C. Hawthorne, Can. Mineral. 48, 1 (2010).

    Article  Google Scholar 

  91. P. C. Piilonen, A. M. McDonald, and A. E. Lalonde, Can. Mineral. 41, 27 (2003).

    Article  Google Scholar 

  92. N. Shi, Z. Ma, G. Li, et al., Acta Crystallogr. B 54, 109 (1998).

    Article  Google Scholar 

  93. Yu. L. Kapustin, Zap. Vseross. Mineral. O-va 101, 459 (1972).

    Google Scholar 

  94. Y. A. Uvarova, E. Sokolova, F. C. Hawthorne, et al., Can. Mineral. 46, 651 (2008).

    Article  Google Scholar 

  95. P. A. Williams, F. Hatert, M. Pasero, and S. J. Mills, Mineral. Mag. 74, 899 (2010).

    Article  Google Scholar 

  96. P. C. Piilonen, A. E. Lalonde, and A. M. McDonald, Can. Mineral. 41, 1 (2003).

    Article  Google Scholar 

  97. G. Ferraris, G. Ivaldi, A. P. Khomyakov, et al., Eur. J. Mineral. 8, 241 (1996).

    Google Scholar 

  98. P. M. Kartashov, G. Ferraris, D. V. Soboleva, and N. V. Chukanov, Can. Mineral. 44, 1331 (2006).

    Article  Google Scholar 

  99. F. C. Hawthorne and R. Oberti, Can. Mineral. 44, 1 (2006).

    Article  Google Scholar 

  100. N. V. Belov, Dokl. Akad. Nauk SSSR, 71, 61 (1950).

    Google Scholar 

  101. R. K. Rastsvetaeva, D. Yu. Pushcharovsky, R. A. Vinogradova, and I. V. Pekov, Crystallogr. Rep. 41(1), 58 (1996).

    ADS  Google Scholar 

  102. I. V. Pekov, N. V. Chukanov, M. E. Nefedova, et al., Zap. Vseross. Mineral. O-va 134(6), 31 (2005).

    Google Scholar 

  103. R. K. Rastsvetaeva, D. Yu. Pushcharovsky, and B. E. Borutskii, Crystallogr. Rep. 40(1), 27 (1995).

    ADS  Google Scholar 

  104. D. Yu. Pushcharovsky, R. K. Rastsvetaeva, and B. Borutskii, Mineral. Zh. 17(1), 48 (1995).

    Google Scholar 

  105. R. K. Rastsvetaeva and S. M. Aksenov, Abstr. XVII Jnt. Conf. “Crystal Chemistry, X-ray Diffraction and Spectroscopy of Minerals”. St. Petersburg, Russia, 2011, Jine 20–24. P. 58.

  106. F. C. Hawthorne and H. D. Grundy, Mineral. Mag. 39, 390 (1973).

    Article  Google Scholar 

  107. N. Morimoto, J. Fabries, A. K. Ferguson, et al., Am. Mineral. 73, 1123 (1988).

    Google Scholar 

  108. J. B. Thompson, Am. Mineral. 63, 239 (1978).

    Google Scholar 

  109. D. R. Veblen and Ch. W. Burnham, Am. Mineral. 63, 1053 (1978).

    Google Scholar 

  110. G. Artioli and E. Galli, Mater. Sci. Forum. 166, 647 (1994).

    Article  Google Scholar 

  111. K. Brauner and A. Preisinger, Tscherm. Mineral. Petrogr. Mitt. 6, 120 (1956).

    Article  ADS  Google Scholar 

  112. G. Ferraris, A. P. Khomyakov, E. Belluso, and S. V. Soboleva, Eur. J. Mineral. 10, 865 (1998).

    Google Scholar 

  113. D. Yu. Pushcharovsky, I. V. Pekov, J. J. Plac, et al., Crystallogr. Rep. 44(4), 610 (1999).

    Google Scholar 

  114. S. Karup-Möller and O. V. Peterson, Neues Jahrb. Mineral. 11, 501 (1984).

    Google Scholar 

  115. F. Camara, L. A. J. Garvie, B. Devouard, et al., Am. Mineral. 87, 1458 (2002).

    Google Scholar 

  116. R. K. Rastsvetaeva, S. M. Aksenov, and I. Verin, Kristallografiya 56(4), 657 (2011).

    Google Scholar 

  117. A. R. Kampf, G. R. Rossman, and R. M. Housley, Am. Mineral. 94, 1198 (2009).

    Article  Google Scholar 

  118. G. Perrault, Y. Harvey, and R. Pertsowsky, Can. Mineral. 13, 68 (1975).

    Google Scholar 

  119. A. Biedl and A. Preisinger, Fortschr. Mineral. 40, 50 (1962).

    Google Scholar 

  120. G. Springer, Can. Mineral. 14, 407 (1976).

    Google Scholar 

  121. N. A. Yamnova, Yu. K. Egorov-Tismenko, and A. P. Khomyakov, Crystallogr. Rep. 41(2), 239 (1996).

    ADS  Google Scholar 

  122. R. K. Rastsvetaeva, O. Yu. Rekhlova, and A. P. Khomyakov, Sov. Phys. Crystallogr. 36(4), 500 (1991).

    Google Scholar 

  123. A. P. Khomyakov, Yu. P. Men’shikov, R. K. Rastsvetaeva, and G. N. Nechelyustov, Zap. Vseross. Mineral. O-va, No. 1, 116 (1993).

  124. A. P. Khomyakov, F. Camara, E. Sokolova, et al., Can. Mineral. 48, 279 (2010).

    Article  Google Scholar 

  125. Cr. Biagoni, E. Bonaccorso, N. Perchiazzi, and S. Merlino, Period. Mineral. 79(3), 1 (2010).

    Google Scholar 

  126. S. Merlino, N. Perchiazzi, A. P. Khomyakhov, et al., Eur. J. Mineral. 2, 177 (1990).

    Google Scholar 

  127. A. Piotrowski, V. Kahlenber, and R. X. Fisher, Am. Mineral. 85, 1534 (2000).

    Google Scholar 

  128. H. Annehed, L. Faelth, and G. Raade, Neues Jahrb. Mineral., p. 7 (1985).

  129. M. Mellini, Tscherm. Min. Petrogr. Mitt. 28, 99 (1981).

    Article  Google Scholar 

  130. M. Mellini, Tscherm. Min. Petrogr. Mitt. 30, 249 (1982).

    Article  Google Scholar 

  131. N. Perchiazzi, A. M. McDonald, R. A. Gault, et al., Can. Mineral. 38, 641 (2000).

    Article  Google Scholar 

  132. M. Mellini and S. Merlino, Tscherm. Min. Petrogr. Mitt. 26, 109 (1979).

    Article  Google Scholar 

  133. S. Merlino and N. Perchiazzi, Mineral. Petrol. 37, 25 (1987).

    Article  ADS  Google Scholar 

  134. A. R. Chakhmouradian, R. H. Mitchell, and P. C. Burns, Can. Mineral. 46, 1023 (2008).

    Article  Google Scholar 

  135. N. V. Zubkova, I. V. Pekov, D. Yu. Pushcharovsky, and N. V. Chukanov, Z. Kristallogr. 224, 389 (2009).

    Article  Google Scholar 

  136. P. A. Williams, F. Hatert, M. Pasero, and S. J. Mills, Mineral. Mag. 75, 27 (2010).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 119333, Russia

    R. K. Rastsvetaeva & S. M. Aksenov

Authors
  1. R. K. Rastsvetaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. M. Aksenov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to R. K. Rastsvetaeva.

Additional information

Dedicated to the memory of N.V. Belov

Original Russian Text © R.K. Rastsvetaeva, S.M. Aksenov, 2011, published in Kristallografiya, 2011, Vol. 56, No. 6, pp. 975–1000.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rastsvetaeva, R.K., Aksenov, S.M. Crystal chemistry of silicates with three-layer TOT and HOH modules of layered, chainlike, and mixed types. Crystallogr. Rep. 56, 910–934 (2011). https://doi.org/10.1134/S1063774511060216

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774511060216

Keywords

Search

Navigation