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Stacking faults in lizardites 1T from electron diffraction data and modeling of diffraction effects

  • Structure of Inorganic Compounds
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Abstract

Stacking faults in lizardites 1T (polytype group A) have been studied by analyzing the oblique-texture electron diffraction patterns in combination with a numerical simulation of diffraction patterns. The simulation of diffraction profiles was performed for finite (10-layer) sequences using the statistical Markov model in the quasi-homogeneous approximation. Diffraction criteria are revealed, which indicate the presence of defects in lizardite 1T; these defects are related to the change in the layer orientation by 180° and displacements of adjacent layers by a/3. It is shown that in the case of the statistical distribution of defects, along with pairs of adjacent layers with layer packing features typical of polytype groups D and B, there are also sequences of layers 1T(A), correspondingly rotated by 180° or displaced by a/3 and 2a/3 with respect to the layers in the 1T matrix. The data obtained give deeper insight into the variations in layer packing in lizardites 1T.

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Correspondence to A. P. Zhukhlistov.

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Original Russian Text © A.P. Zhukhlistov, 2011, published in Kristallografiya, 2011, Vol. 56, No. 1, pp. 123–127.

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Zhukhlistov, A.P. Stacking faults in lizardites 1T from electron diffraction data and modeling of diffraction effects. Crystallogr. Rep. 56, 117–121 (2011). https://doi.org/10.1134/S1063774511010275

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  • DOI: https://doi.org/10.1134/S1063774511010275

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