Abstract
Stacking fault energy is one of key parameters for understanding the mechanical properties of face-centered cubic materials. It is well known that the plastic deformation mechanism is closely related to the size of stacking fault energy. Although alloying is a conventional method to modify the physical parameter, the underlying microscopic mechanisms are not yet clearly established. Here, we propose a simple model for determining the effect of interstitial alloying on the stacking fault energy. We derive a volumetric behaviour of stacking fault energy from the harmonic approximation to the energy-lattice curve and relate it to the contents of interstitials. The stacking fault energy is found to change linearly with the interstitial content in the usual low concentration domain. This is in good agreement with previously reported experimental and theoretical data.
Similar content being viewed by others
Introduction
Face-centered cubic (fcc) and hexagonal close-packed (hcp) structures can be characterized by an ordered stacking of 2D honeycomb-type layers. As a consequence, the stacking fault in an fcc structure refers to the locally irregular stacking sequence along the [111] direction, which is generated by the splitting of a perfect dislocation into two Shockley partial dislocations during plastic deformation. The excess stuctural energy induced in a material by the process defines the so-called stacking fault energy (SFE, \({\gamma }_{{\rm{sf}}}\)). Because a stacking fault locally resembles an hcp structure embedded in the fcc structure, the SFE can be found in relation to the energy difference between the two structures. The SFE is regarded as one of the most important parameters for understanding the mechanical properties of fcc materials.
It is an empirical rule that as the SFE value increases, the deformation mechanism of the fcc materials varies from γ/ε phase transformation to twin formation, and slip. For example, the plastic deformation behaviour of Co-Ni-Cr-Mo alloys changes from phase transformation to twinning for \({\gamma }_{{\rm{sf}}} \sim 18\,m{\rm{J}}/{{\rm{m}}}^{2}\) and to slip for \( \sim 30\mbox{--}47\,m{\rm{J}}/{{\rm{m}}}^{2}\). These boundaries become \({\gamma }_{{\rm{sf}}} \sim 12\,m{\rm{J}}/{{\rm{m}}}^{2}\) and \( \sim 18\mbox{--}42\,m{\rm{J}}/{{\rm{m}}}^{2}\), respectively, for Fe-Mn-Cr-C alloys1, 2. Similarly, transformation-induced plasticity and twinning-induced plasticity steels are classified3 by the critical value of \({\gamma }_{{\rm{sf}}} \sim 16\,m{\rm{J}}/{{\rm{m}}}^{2}\).
Although a considerable number of works have measured and predicted SFEs for fcc materials, the effect of alloying on the behaviour of SFE is not yet clearly understood from basic physical parameters. Specifically, the influence of interstitial elements on the SFE of fcc materials such as austenitic steels is usually quite significant, but it remains vague for some cases. From the Hume-Rothery rules4, a solid solution will not be substitutional when the difference in the atomic radii of the solute and solvent atoms is more than 15%. Therefore, we can generally regard carbon and nitrogen as the interstitial elements because their atomic sizes are significantly smaller than those of the metallic elements which form the crystalline lattice, and are comparable to the size of interstices.
The stacking fault energy values measured for Fe-18Cr-10Mn-0.2Si-0.06C-N5 and Fe-15Mn-2Cr-0.6C-N6 alloys using neutron diffraction (ND) and X-ray diffraction (XRD) methods, respectively, increased linearly with interstitial content. These overall increasing trends were also demonstrated with transmission-electron microscopy (TEM) measurements for Fe-12Mn-C, Fe-18Mn-10Ni-C and Fe-18Cr-16Ni-10Mn-N alloys, while a decreasing SFE behaviour was locally observed for Fe-22Mn-C and Fe-15Cr-17Mn-N in the low carbon and nitrogen regions7, 8.
In addition, recent ab-initio calculations also exhibit the linear tendency of SFE with interstitials. Non-magnetic γ-Fe shows enhanced SFE values with the homogeneous alloying of carbon and nitrogen, and the effect of nitrogen is also similar in the Fe-12Mn-N system9, 10. Moreover, magnetic and chemical disorders in austenitic Fe-Cr-Ni stainless steels retain linear SFE behaviour with the addition of interstitial carbon11. Hence, interstitial elements might be regarded as inducing the linear trend in SFE. In this work, we provide the origin of the physical properties and its implications.
Results and Discussion
Using the structural characteristic of a stacking fault, Olson and Cohen12 suggested a formulation for SFE, as
where \({\rm{\Delta }}{G}^{\mathrm{hcp}-\mathrm{fcc}}\) is the free energy difference between the hcp and fcc structures, \(\rho \) is the surface atomic number density of the (111) layer, and \(\sigma \) is the fcc/hcp interfacial free energy. The factor of 2 reflects the two interfaces between the fcc structure and stacking fault. The variation in \(\sigma \) with composition, temperature, and volume is often neglected for the same kind of materials13.
It is a first principle in physics that the response of a material in equilibrium to external perturbation appears to be the second order of the variation of the physical parameter. By employing this fact, we expand the total energy of a given material near equilibrium as a function of volume \(V\). It is straightforward to obtain the energy difference of the hcp and fcc structures
where \({V}_{0}\) and \({V}_{1}\) are the fcc and hcp volumes in each equilibrium, \({E}_{f}\) and \({E}_{h}\) are the fcc and hcp total energy, respectively. The hcp bulk modulus is given by \({B}_{h}={{V}_{1}{\partial }^{2}{E}_{h}/\partial {V}^{2}|}_{{V}_{1}}\). We divide the left and right sides of equation (2) by the surface area in order to find the stacking fault energy as a function of the lattice parameter
where \({\gamma }_{{\rm{sf}}}\,(a)\) and \({\gamma }_{{\rm{sf}}}\,({a}_{0})\) are the SFEs of a material at the fcc volumes of \(a=\sqrt[3]{V}\) and \({a}_{0}=\sqrt[3]{{V}_{0}}\), respectively, and the linear coefficient is obtained to be \(\alpha =2\sqrt{3}{B}_{h}\{({V}_{0}-{V}_{1})/{V}_{1}\}\). It is clear that the SFE varies linearly in proportion to the lattice deviation from that of equilibrium \({\rm{\Delta }}a=a-{a}_{0}\). Note that the SFE and lattice parameter relationship proposed by equation (3) is consistent with equation (1) because the interfacial energy term is nearly constant and implicitly included in both sides of equation (3).
Next, we consider the effect of interstitial alloying on material volume. As far as the interstitial distribution is homogeneous and its content is low, it is sound to assume that each interstitial atom contributes an equal amount of additional volume to the host material. Thus, we write the volume change induced by a single interstitial atom as \({v}_{i}=V(N,1)-V(N,0)\), where V(N, n) is the volume of the material, consisting of N host atoms and n interstitial atoms. Because the number of interstitial atoms is usually small compared with that of host atoms, n ≪ N, the lattice parameter a(n) can be written as
where is defined as the initial material volume per atom. After noticing that n/N is related to the interstitial concentration \(c=n/(N+n)\), the above equation can also be expressed as
with the constant \(\beta =({a}_{0}/3)({v}_{i}/{v}_{0})\)
Hence, the internal pressure effect of interstitials on SFE can be obtained by combining equations (3) and (5),
where \(k=\alpha \beta \) is understood to be the characteristic constant of a given material, to represent the change in SFE produced by interstitial alloying. Interstitial content in a material usually does not exceed a few percent. Thus we may set \(c \sim {\mathscr{O}}\,({10}^{-2})\) and derive \({\gamma }_{{\rm{sf}}}\,(c)={\gamma }_{{\rm{sf}}}\,(0)+kc\). It is remarkable that the stacking fault energy linearly depends upon the interstitial concentration in the low c regime.
To examine the reliability of the proposed relationships, in Fig. 1 we plot the lattice parameter versus interstitial concentration with the known data for the Fe-C and Fe-N binary alloys. The lattice parameters were adjusted to zero for \(a(0)\) and scaled by the proportional coefficient \(\beta \) in equation (5). Clearly, both the carbon (Fig. 1(a)) and nitrogen (Fig. 1(b)) linearly increase the lattice constant as their contents increase.
Like the cases of the Fe-C and Fe-N alloys, in Fig. 2 we compare the lattice parameter versus interstitial concentration relationship with previously reported experimental data for austenitic steels. It is evident that all the experimental data in the considered multi-component alloys follow the current theoretical linear line well.
The behaviour of lattice parameter with interstitial concentration in multi-component alloys. The experimental data are for austenitic steels from the literature. All data consitently fit to the theoretical linear line at low interstitial concentrations. As shown in the inset with the Fe-19Cr-13Ni-2Mn-1Mo-1Si-N alloy, the non-linear behaviour of lattice parameter at high interstitial concentration is also well-captured by the present results.
The present result demonstrated in Figs 1 and 2 can be regarded in a mathematical sense as a simple linear expansion of the lattice parameter near a small alloy concentration. However, we provided a physical meaning to the expansion coefficient \(\beta =({a}_{0}/3)({v}_{i}/{v}_{0})\) in equation (5) behind the abstract mathematical treatment. We can estimate \({v}_{i}/{v}_{0} \sim 1/2\) for carbon in austenitic steels, which is large and not at all obvious by intuition. In addition, the lattice-interstitial concentration relationship of equation (5) can be applied to the extended range of interstitial concentration. For example, the inset in Fig. 2 shows the lattice parameter behaviour for high interstitial concentration with the experimental data of Fe-19Cr-13Ni-2Mn-1Mo-1Si-N14. When one tries a linear fit to the displayed data, it suffers from substantial deviation when extrapolated to the low concentration region. In contrast, the curve from equation (5) shown in the inset behaves properly through the whole considering range of interstitial concentration. Therefore, the empirical assumption of a linear relationship between the lattice parameter and interstitial alloying at low concentration15,16,17 is clearly resolved, and can be extended to the higher concentration region.
Figure 3 shows the change in SFE as a function of interstitial concentration with experimental and theoretical data for austenitic steels found in the literature. The SFEs are scaled using equation (6) in a process similar to the lattice parameter in Figs 1 and 2. It is very interesting that the SFE increases as the interstitial concentration increases. Both the experimental (Fig. 3(a)) and theoretical (Fig. 3(b)) data consistently support the linear behaviour of SFE variation in relation to interstitial content at low concentration.
The behaviour of stacking fault energy with interstitial concentration. Data shown are for some austenitic steels from experiments (a) and theoretical calculations (b), respectively, in the literature. Clearly, all data well follow a linear line within the range of conventional interstitial concentrations. The weak deviations from the linear line observed in some experiments come from extrinsic factors, as discussed in the main text.
Although a weak anomaly is locally observed in the TEM-measured SFE of Fe-12Mn-C18 and Fe-30Ni-C19 alloys in very low concentrations, this does not appear in another TEM measurement with one of the same Fe-12Mn-C alloys7. As suggested by Hickel et al., these phenomena might arise as an effect due to local heating of the specimen during TEM measurement20. Their ab-initio calculations indicated that interstitial carbons in the central layer of a stacking fault sharply increase SFE, and thus enhanced carbon diffusivity near the heated zone may alter the SFE of specimen. Therefore, it is likely that the local deviations from the linearity in some of the TEM-measured SFE data are extrinsic effects that depend specifically on the specimen temperature during measurement. The SFE trends in the TEM measurements of the Fe-22Mn-C and Fe-15Cr-17Mn-N alloys8 can also be understood in a similar way. Note that the SFE values obtained by other diffraction methods are highly consistent with our observation of linearity.
Theoretical calculations in Fig. 3(b) provide additional support to the current model of the effect of interstitial alloying on SFE. All data sets in Fig. 3(b) are closely bound to the ideal curve from equation (6). The small deviation in the Fe-C binary alloy21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47 is attributed to errors in the experimental data that was used to build the thermodynamic model. It is an important fact that the trend in SFE with respect to interstitials does not rely on the details of the substitutional alloy composition. This observation might imply weak chemical interactions between the interstitial and constituent metallic atoms inside the materials. It was previously reported that the formation of a stacking fault tends to deplete interstitial atoms at the structure, which reduces the SFE by about one-third20. Another ab-initio study showed that for the paramagnetic γ-Fe and the Fe-20Cr-8.4Ni alloy, at least 70% of the change in SFE produced by interstitial carbons relies on the volumetric effect11. Therefore, the leading term in the variation of SFE with interstitial alloying can be considered to have a mechanical origin rather than reflecting a chemical effect.
Once again, we would like to emphasize that equation (6) is an accurate description of the SFE response to interstitial contents. It implicitly incorporates the interfacial energy term, which is higher order and less variant. When a chemical effect needs to be considered, within the weak interaction regime, one can formally adopt the same form of the relationship with a slightly modified coefficient constant \(k\) in equation (6). It is also expected that a similar idea can be applied to the cases of substitutional alloys within the low concentration domain, where the concentration dependency will be given by \(c/(1-c)\to c\). The non-linear form of the SFE with respect to interstitials in equation (6) naturally guarantees extended validity to the higher concentration regime. Furthermore, the newly introduced physical parameters \(\alpha \) and \(\beta \) are expressed in terms of well-defined material properties like bulk modulus and lattice constant/volume and no other arbitrary parameters are used. Thus, the present discussions are also proper from the viewpoint of theoretical development.
In conclusion, we established a physical model of the SFE change induced by interstitial alloying and showed that the volumetric effect gives rise to the dominant behaviour of the SFE. The derived relationship is mostly suitable for a low concentration of interstitials, but encompasses the usual range of alloy concentrations in materials. We are convinced that the present model will find an application in alloy deign for engineering materials.
References
Rémy, L. & Pineau, A. Twinning and strain-induced F.C.C.→H.C.P. transformation on the mechanical properties of Co-Ni-Cr-Mo alloys. Mater. Sci. Eng. 26, 123–132 (1976).
Rémy, L. & Pineau, A. Twinning and strain-induced F.C.C.→H.C.P. transformation in the Fe-Mn-Cr-C system. Mater. Sci. Eng. 28, 99–107 (1977).
Frommeyer, G., Brüx, U. & Neumann, P. Supra-ductile and high-strength manganese-TRIP/TWIP steels for high energy absorption purposes. ISIJ Int. 43, 438–446 (2003).
Gottstein, G. Physical foundations of materials science (Springer-Verlag, Berlin, 2004).
Lee, T. H., Shin, E., Oh, C. S., Ha, H. Y. & Kim, S. J. Correlation between stacking fault energy and deformation microstructure in high-interstitial-alloyed austenitic steels. Acta Mater. 58, 3173–3186 (2010).
Lee, S.-J., Han, J., Lee, C.-Y., Park, I.-J. & Lee, Y.-K. Elastic strain energy induced by epsilon martensitic transformation and its contribution to the stacking-fault energy of austenite in Fe–15Mn–xC alloys. J. Alloys. Compd. 617, 588–596 (2014).
Volosevich, P. Y., Gridnev, V. N. & Petrov, Y. N. Carbon effect on austenite stacking faults energy in manganese steels. Fiz. Metal. Metalloved. 40, 554–559 (1975).
Petrov, Y. N. Effect of carbon and nitrogen on the stacking fault energy of high-alloyed iron-based austenite. Z. Metallkd. 94, 1012–1016 (2003).
Abbasi, A., Dick, A., Hickel, T. & Neugebauer, J. First-principles investigation of the effect of carbon on the stacking fault energy of Fe–C alloys. Acta Mater. 59, 3041–3048 (2011).
Kibey, S., Liu, J. B., Curtis, M. J., Johnson, D. D. & Sehitoglu, H. Effect of nitrogen on generalized stacking fault energy and stacking fault widths in high nitrogen steels. Acta. Mater. 54, 2991–3001 (2006).
Lu, S. et al. Stacking fault energy of C-alloyed steels: The effect of magnetism. Acta Mater. 122, 72–81 (2017).
Olson, G. B. & Cohen, M. A general mechanism of martensitic nucleation: Part I. General concepts and the FCC→HCP transformation. Metall. Trans. A 7, 1897–1904 (1976).
Saeed-Akbari, A., Imlau, J., Prahl, U. & Bleck, W. Derivation and variation in composition-dependent stacking fault energy maps based on subregular solution model in high-manganese steels. Metall. Mater. Trans. A 40, 3076–3090 (2009).
Christiansen, T. & Somers, M. A. J. Controlled dissolution of colossal quantities of nitrogen in stainless steel. Metall. Mater. Trans. A. 37, 675–682 (2006).
Dyson, D. J. & Holmes, B. Effect of alloying additions on the lattice parameter of austenite. JISI 208, 469–474 (1970).
Cheng, L., Böttger, A., de Keijser, T. H. & Mittemeijer, E. J. Lattice parameters of iron-carbon and iron-nitrogen martensites and austenites. Scr. Metal. Mater. 24, 509–514 (1990).
Mittemeijer, E. J. Fundamentals of Materials Science: The Microstructure–Property Relationship Using Metals as Model Systems 159–160 (Springer-Verlag, Berlin, 2010).
Gavriljuk, V. G. & Berns, H. High Nitrogen Steels: Structure, Properties, Manufacture, Applications (Springer-Verlag, Berlin, 1999).
Petrov, Y. N. On the electron structure of Mn–, Ni–and Cr–Ni–Mn austenite with different stacking fault energy. Scr. Mater. 53, 1201–1206 (2005).
Hickel, T. et al. Impact of nanodiffusion on the stacking fault energy in high-strength steels. Acta Mater. 75, 147–155 (2014).
Charnock, W. & Nutting, J. The effect of carbon and nickel upon the stacking-fault energy of iron. Met. Sci. J. 1, 123–127 (1967).
Wever, F. Zur konstitution des technischen eisens. Z. Elktrochem. Angew. P. 30, 376–382 (1924).
Öhman, E. X-ray Investigations on the Crystal Structure of Hardened Steel. JISI 123, 445–463 (1931).
Westgren, A. Martensite—Recent Structural Studies. Met. Prog. 20, 49–53 (1931).
Honda, K. & Nishiyama, Z. On the nature of the tetragonal and cubic martensites. Sci. Rep. Tohoku Univ. 21, 299–331 (1932).
Hägg, G. The Decomposition of Martensite. JISI 130, 439–451 (1934).
Roberts, C. S. Effect of carbon on the volume fractions and lattice parameters of retained austenite and martensite. J. Met. 197, 203–204 (1953).
Wrazej, W. J. Lattice spacing of retained austenite in iron-carbon alloys. Nature 163, 212–213 (1949).
Mazur, J. Lattice parameters of martensite and of austenite. Nature 166, 828 (1950).
Krainer, H. Untersuchungen über angelassenen Martensit. Steel Res. Int. 22, 53–62 (1951).
Falkanhagen, G. & Hofmann, W. Beobachtungen an schroff abgeschreckten Eisen-Kohlenstoff-Schmelzen. Arch. Eisenhütt. 25, 73–74 (1952).
Ruhl, R. & Cohen, M. Splat quenching of iron-carbon alloys. Trans. Metall. Soc. AIME 245, 241–251 (1969).
Ridley, N. & Stuart, H. Partial molar volumes from high-temperature lattice parameters of iron–carbon austenites. Met. Sci. J. 4, 219–222 (1970).
Eisenhut, O. & Kaupp, E. The system iron-nitrogen from x-ray diffraction investigations”. Z. Elektrochem. 36, 392–404 (1930).
Paranjpe, V. G., Cohen, M., Bever, M. B. & Floe, C. F. The Iron Nitrogen System. J. Met. 188, 261–267 (1950).
Jack, K. H. The Iron-Nitrogen System: The Preparation and the Crystal Structures of Nitrogen-Austenite (γ) and Nitrogen-Martensite (α’). Proc. Roy. Soc. A. 208, 200–215 (1951).
Bell, T. & Owen, W. S. Martensite in iron-nitrogen alloys. JISI 205, 428–434 (1967).
Gavriljuk, V. G. et al. Effect of carbon and nitrogen on chemical homogeneity of fcc iron-based alloys. Metall. Mater. Trans. A. 28, 2195–2199 (1997).
Sun, Y., Li, X. & Bell, T. Structural characteristics of low temperature plasma carburised austenitic stainless steel. Mater. Sci. Tech. 15, 1171–1178 (1999).
Kahn, H., Michal, G. M., Ernst, F. & Heuer, A. H. Poisson effects on X-ray diffraction patterns in low-temperature-carburized austenitic stainless steel. Metall. Mater. Trans. A. 40, 1799–1804 (2009).
Hummelshøj, T. S., Christiansen, T. L. & Somers, M. A. J. Lattice expansion of carbon-stabilized expanded austenite. Scr. Mater. 63, 761–763 (2010).
Lee, S.–J. et al. The effect of nitrogen on the stacking fault energy in Fe–15Mn–2Cr–0.6C–xN twinning-induced plasticity steels. Scr. Mater. 92, 23–26 (2014).
Gavriljuk, V., Petrov, Y. N. & Shanina, B. Effect of nitrogen on the electron structure and stacking fault energy in austenitic steels. Scr. Mater. 55, 537–540 (2006).
Mazancová, E. & Mazanec, K. Stacking fault energy in high manganese alloys. Mater. Eng. 16, 26–31 (2009).
Bouaziz, O. et al. Effect of chemical composition on work hardening of Fe—Mn—C TWIP steels. Mater. Sci. Tech. 27, 707–709 (2011).
Peng, X. et al. Effect of Carbon Content on Stacking Fault Energy of Fe-20Mn-3Cu TWIP Steel. JISI 21, 116–120 (2014).
Ghasri-Khouzani, M. & McDermid, J. R. Effect of carbon content on the mechanical properties and microstructural evolution of Fe–22Mn–C steels. Mater. Sci. Eng. A 621, 118–127 (2015).
Acknowledgements
This work was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (NRF-2014R1A2A1A12067579), the Swedish Research Council, the Swedish Foundation for Strategic Research, Sweden’s Innovation Agency (VINNOVA Grant No. 2014-03374), the Swedish Foundation for International Cooperation in Research and Higher Education, the Carl Tryggers Foundation, and the Hungarian Scientific Research Fund (OTKA 109570).
Author information
Authors and Affiliations
Contributions
J.–Y.L., L.V. and S.K.K. initiated the research; J.-Y.L. and S.K.K. performed the calculations; All authors analyzed the results and contributed to preparing the manuscript.
Corresponding authors
Ethics declarations
Competing Interests
The authors declare that they have no competing interests.
Additional information
Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Lee, JY., Koo, Y.M., Lu, S. et al. The behaviour of stacking fault energy upon interstitial alloying. Sci Rep 7, 11074 (2017). https://doi.org/10.1038/s41598-017-11328-4
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-017-11328-4
- Springer Nature Limited
This article is cited by
-
Thermomechanical Behavior of Biocompatible Austenitic Stainless Steels during Simulated Torsion Tests
Journal of Materials Engineering and Performance (2019)