Abstract
This paper reports on the results of precision X-ray structural investigations of a RbTi0.98Zr0.02OPO4 single crystal at temperatures of 293 and 105 K. It is established that the observed decrease in the temperature of the ferroelectric phase transition in RbTiOPO4 crystals doped with zirconium is associated with the increase in the Rb-O bond lengths. The structural factors responsible for the decrease in the electrical conductivity in these crystals are revealed. An analysis is made of the structure of the helical channels which in crystals of this family are considered to be a decisive factor for the manifestation of superionic conduction. It is shown that, in structures of the KTiOPO4 (KTP) type, the migration of ions in channels is most hindered inside the cavities.
Similar content being viewed by others
References
V. I. Voronkova, I. N. Leont’eva, N. I. Sorokina, et al., Kristallografiya 51(6), 1043 (2006) [Crystallogr. Rep. 51 (6), 977 (2006)].
I. Tordjman, R. Masse, and J.-C. Guitel, Z. Kristallogr., Kristallgeom., Kristallphys., Kristallchem. 139, 103 (1974).
F. C. Zumsteg, J. D. Bierlein, and T. E. Gier, J. Appl. Phys. 47(11), 4980 (1976).
M. L. F. Phillips, W. T. A. Harrison, G. D. Stucky, et al., Chem. Mater. 4, 222 (1992).
D. Xue and S. J. Zhang, J. Solid State Chem. 108, 4324 (1999).
P. A. Thomas, A. Baldwin, R. Dupree, et al., J. Phys. Chem. B 108, 4324 (2004).
O. A. Alekseeva, A. P. Dudka, N. I. Sorokina, et al., Kristallografiya 52(4), 628 (2007) [Crystallogr. Rep. 52 (4), 659 (2007)].
E. I. Agapova, V. I. Voronkova, E. P. Kharitonova, et al., Kristallografiya 53(2), 311 (2008) [Crystallogr. Rep. 53 (2), 285 (2008)].
V. A. Kalesinskas, N. I. Pavlova, I. S. Rez, and Ĭ. P. Grigas, Liet. Fiz. Rinkinys (Lithuanian Phys. Papers) 22(5), 87 (1982).
V. K. Yanovskii and V. I. Voronkova, Phys. Status Solidi A 93, 665 (1986).
E. L. Belokoneva, O. V. Yakubovich, V. G. Tsirel’son, and V. S. Urusov, Dokl. Akad. Nauk SSSR 310(5), 1129 (1990) [Sov. Phys. Dokl. 35 (2), 106 (1990)].
N. K. Hansen, J. Protas, and G. Marnier, Acta Crystallogr., Sect. B: Struct. Sci. 47, 660 (1991).
F. K. Larsen, Acta Crystallogr., Sect. B: Struct. Sci. 51, 468 (1995).
P. Delarue, C. Lecomte, M. Jannin, et al., Phys. Rev. B: Condens. Matter 58(9), 5287 (1998).
V. A. Streltsov, J. Nordborg, and J. Albertsson, Acta Crystallogr., Sect. B: Struct. Sci. 56, 785 (2000).
S. T. Norberg, A. N. Sobolev, and V. A. Streltsov, Acta Crystallogr., Sect. B: Struct. Sci. 59, 353 (2003).
S. T. Norberg, J. Gustafsson, and B.-E. Mellander, Acta Crystallogr., Sect. B: Struct. Sci. 59, 588 (2003).
S. T. Norberg and N. Ishizawa, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 61, 99 (2005).
V. I. Voronkova, V. K. Yanovskii, I. N. Leont’eva, et al., Neorg. Mater. 40(12), 1505 (2004) [Inorg. Mater. 40 (12), 1321 (2004)].
A. P. Dudka, Kristallografiya 47(1), 163 (2002) [Crystallogr. Rep. 47 (1), 152 (2002)].
A. P. Dudka, J. Appl. Crystallogr. 40, 602 (2007).
Xcalibur CCD System and CrysAlis Software System: Version 1.170 (Oxford Diffraction, Abingdon, Oxfordshire, United Kingdom, 2003).
V. Petricek and M. Dusek, Jana2000: The Crystallographic Computing System (Institute of Physics, Prague, Czech Republic, 2000).
P. J. Becker and P. Coppens, Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr. 30, 129 (1974).
F. L. Hirshfeld, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 32, 239 (1976).
A. P. Dudka, Kristallografiya 53(2), 377 (2008) [Crystallogr. Rep. 53 (2), 351 (2008)].
H. Takazawa, S. Ohba, and Y. Saito, Acta Crystallogr., Sect. B: Struct. Sci. 44, 580 (1988).
H. D. Flack, Acta Crystallogr., Sect. A: Found. Crystallogr. 39, 876 (1983).
N. I. Sorokina, V. I. Voronkova, V. K. Yanovskii, et al., Kristallografiya 41(3), 457 (1996) [Crystallogr. Rep. 41 (3), 432 (1996)].
O. D. Krotova, N. I. Sorokina, I. A. Verin, et al., Kristallografiya 48(6), 992 (2003) [Crystallogr. Rep. 48 (6), 925 (2003)].
L. A. Muradyan, S. F. Radaev, and V. I. Simonov, Methods of Structural Analysis (Nauka, Moscow, 1989), p. 5 [in Russian].
A. P. Dudka, I. A. Verin, V. N. Molchanov, et al., Kristallografiya 50(1), 43 (2005) [Crystallogr. Rep. 50 (1), 36 (2005)].
J. Almgren, V. A. Streltsov, A. N. Sobolev, et al., Acta Crystallogr., Sect. B: Struct. Sci. 55, 712 (1999).
L. Ven’, “Growth, Structure, and Properties of Single Crystals of Solid Solutions in the Family of Potassium Titanyl Phosphate KTiOPO4,” Candidate’s Dissertation in Mathematical Physics (Moscow State University, Moscow, 2000).
E. L. Belokoneva and B. V. Mill’, Zh. Neorg. Khim. 39(3), 355 (1994) [Russ. J. Inorg. Chem. 39 (3), 341 (1994)].
B. V. Andreev, V. A. Dyakov, N. I. Sorokina, and V. I. Simonov, Solid State Commun. 80, 777 (1991).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.A. Alekseeva, A.P. Dudka, N.E. Novikova, N.I. Sorokina, E.I. Agapova, V.I. Voronkova, 2008, published in Kristallografiya, 2008, Vol. 53, No. 4, pp. 597–604.
Rights and permissions
About this article
Cite this article
Alekseeva, O.A., Dudka, A.P., Novikova, N.E. et al. Structure of the RbTi0.98Zr0.02OPO4 single crystal at temperatures of 293 and 105 K. Crystallogr. Rep. 53, 557–564 (2008). https://doi.org/10.1134/S1063774508040056
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063774508040056