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Synthesis, thermal analysis, and crystal structure of manganese(II) 9-molybdocobaltate(III)

  • Structure of Inorganic Compounds
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Abstract

Manganese(II) 9-molybdocobaltate(III) of the composition [Mn(H2O)4] · [CoMo9O27(OH)5] · 7H2O (I) has been synthesized for the first time and investigated using X-ray diffraction and thermal gravimetric analyses. Compound I crystallizes in the trigonal system with the following unit cell parameters: a = 15.926(1) Å, c = 12.363(1) Å, V = 2715.6(4) Å3, M = 1692.55, Z = 3, ρ(calcd) = 3.105 g/cm3, space group R32.

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Authors and Affiliations

  1. Moscow State Pedagogical University, ul. Malaya Pirogovskaya 1, Moscow, 119991, Russia

    A. V. Oreshkina & G. Z. Kaziev

  2. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskiĭ pr. 59, Moscow, 119333, Russia

    M. Kh. Rabadanov & A. G. Ivanova

Authors
  1. A. V. Oreshkina
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  2. M. Kh. Rabadanov
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  3. A. G. Ivanova
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  4. G. Z. Kaziev
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Correspondence to A. V. Oreshkina.

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Original Russian Text © A.V. Oreshkina, M.Kh. Rabadanov, A.G. Ivanova, G.Z. Kaziev, 2007, published in Kristallografiya, 2007, Vol. 52, No. 6, pp. 1096–1099.

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Oreshkina, A.V., Rabadanov, M.K., Ivanova, A.G. et al. Synthesis, thermal analysis, and crystal structure of manganese(II) 9-molybdocobaltate(III). Crystallogr. Rep. 52, 1061–1065 (2007). https://doi.org/10.1134/S1063774507060211

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  • DOI: https://doi.org/10.1134/S1063774507060211

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