Skip to main content
Log in

Effect of a Mixture’s Composition on the Electrophysical Parameters and Emission Spectra of Hydrogen Chloride Plasma with Chlorine and Helium

  • Published:
Russian Microelectronics Aims and scope Submit manuscript

Abstract

The effect of a mixture’s composition on the electrophysical parameters and emission spectra of HCl/Cl2 and HCl/He plasmas under the conditions of a DC glow discharge is analyzed. The data on the gas temperature and reduced electric field strength are obtained. It is established that the reduced electric field strength in HCl/Cl2 plasma rises linearly with the rising fraction of the second gas in the mixture, while the same value in the HCl/He plasma decreases. It is shown that, in the HCl/Cl2 plasma with a variable composition, the atomic chlorine concentration remains practically unchanged, whereas, in the HCl/He plasma, it decreases monotonically.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Murin, D.B., Efremov, A.M., Svettsov, V.I., Pivovarenok, S.A., and Godnev, E.M., Radiation intensity and concentration of neutral particles in the plasma of a dc glow discharge in mixtures of HCl–H2 and HCl–O2, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2013, vol. 56, no. 8, pp. 41–44.

    Google Scholar 

  2. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.

  3. Rokhlin, G.N., Razryadnye istochniki sveta (Discharge Light Sources), 2nd ed., Moscow: Energoatomizdat, 1991.

  4. Lebedev, Yu.A., Ivanov, Yu.A., and Polak, L.S., Metody kontaktnoi diagnostiki v neravnovesnoi plazmokhimii (Contact Diagnostic Methods in Nonequilibrium Plasma Chemistry), Moscow: Nauka, 1981.

  5. Pearse, R.W.B. and Gaydon, A.G., The Identification of Molecular Spectra, 4th ed., New York: Wiley, 1976.

    Book  Google Scholar 

  6. Striganov, A.R. and Sventitskii, N.S., Tablitsy spektral’nykh linii neitral’nykh i ionizirovannykh atomov (Tables of Spectral Lines of Neutral and Ionized Atoms), Moscow: Atomizdat, 1966.

  7. Efremov, A.M., Pivovarenok, S.A., and Svettsov, V.I., Plasma parameters and etching mechanisms of metals and semiconductors in hydrogen chloride, Russ. Microelectron., 2009, vol. 38, no. 3, pp. 147–159.

    Article  Google Scholar 

  8. Pivovarenok, S.A., Dunaev, A.V., Efremov, A.M., and Svettsov, V.I., Plasma nanoscale etching of GaAs in chlorine and hydrogen chloride, Nanotekhnika, 2011, no. 25, pp. 69–71.

  9. Pivovarenok, S.A., Dunaev, A.V., Murin, D.B., Efremov, A.M., and Svettsov, V.I., Electrophysical parameters and emission spectra of a glow discharge plasma in hydrogen chloride, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2011, vol. 54, no. 9, pp. 48–52.

    Google Scholar 

  10. Dunaev, A.V., Pivovarenok, S.A., Kapinos, S.P., Efremov, A.M., and Svettsov, V.I., Spectral study of HCl plasma etching of gallium arsenide, Russ. Microelectron., 2011, vol. 40, no. 6, pp. 379–382.

    Article  Google Scholar 

  11. Sitanov, D.V., Svettsov, V.I., and Efremov, A.M., Mechanism of formation of atoms in chlorine–oxygen plasmas, High Energy Chem., 1999, vol. 32, no. 2, pp. 110–113.

    Google Scholar 

  12. Pivovarenok, S.A., Effect of the mixture composition on the electrophysical parameters and emission spectra of CF2Cl2/Ar and CF2Cl2/He plasma, Russ. Microelectron., 2017, vol. 46, no. 4, pp. 267–271.

    Article  Google Scholar 

Download references

Funding

The work was carried out as part of a state assignment on scientific research (project no. FZZW-2020-0007).

Author information

Authors and Affiliations

Authors

Corresponding authors

Correspondence to S. A. Pivovarenok or D. B. Murin.

Additional information

Translated by Z. Smirnova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pivovarenok, S.A., Murin, D.B. & Sitanov, D.V. Effect of a Mixture’s Composition on the Electrophysical Parameters and Emission Spectra of Hydrogen Chloride Plasma with Chlorine and Helium. Russ Microelectron 50, 39–44 (2021). https://doi.org/10.1134/S1063739720060098

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063739720060098

Keywords:

Navigation