Abstract
Based on the properties of the corrected retention volume and, primarily, its independence from the carrier gas pressure, we concluded that the corrected retention volume cannot be a gas volume. We demonstrated that this parameter is identical to the volume of an ideal fluid required for the elution of a sorbate in an ideal chromatographic system. The corrected retention volume does not obey gas laws; because of this, numerous relationships obtained in gas chromatography without taking into account this property of the corrected retention volume should be revised. We considered publications of various authors in order to illustrate inconsistencies and contradictions that follow from the nonrecognition (or rejection) of this fact.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
De Vault, D., J. Am. Chem. Soc., 1943, vol. 65, p. 532.
Wilson, J.N., J. Am. Chem. Soc., 1940, vol. 62, p. 1583.
Synge, R.L.M., Biochem. J., 1941, vol. 35, p. 1358.
James, A.T. and Martin, A.J.P., Biochem. J., 1952, vol. 50, p. 679.
Davankov, V.A., Chromatographia, 1996, vol. 42, p. 111.
Ettre, L.S. and Hinshaw, J.V., Chromatographia, 1996, vol. 43, nos. 3–4, p. 159.
Davankov, V.A., Onuchak, L.A., Kudryashov, S.Yu., and Arutunov, Yu.I., Chromatographia, 1999, vol. 49, p. 449.
Davankov, V.A. and Part, B., Pure Appl. Chem., 2001, vol. 73, no. 6, p. 982.
Littlewood, A.B.G., Phillips, C.S., and Price, D.T., J. Chem. Soc., 1955, no. 5, p. 1480.
Pierotti, G.J., Deal, C.H., Derr, E.L., and Porter, P.E., J. Am. Chem. Soc., 1956, vol. 78, p. 2989.
Porter, P.E., Deal, H., and Stross, F.H., J. Am. Chem. Soc., 1956, vol. 78, p. 2999.
Kurganov, A.A., J. Chromatogr. A, 2007, vol. 1150, p. 100.
Everett, D.H. and Stoddart, C.T.H., Trans. Faraday Soc., 1961, vol. 57, p. 746.
Everett, D.H., Trans. Faraday Soc., 1965, vol. 61, p. 1637.
Young, C.L., Chromatogr. Rev., 1968, vol. 10, p. 129.
Conder, J.R. and Young, C.L., Physicochemical Measurements by Gas Chromatography, Chichester: Wiley, 1979.
Kwantes, A. and Rijjnders, G.W.A., Gas Chromatography, London: Butterworths, 1958.
Cruickshank, A.J.B., Windsor, M.L., and Young, C.L., Proc. R. Soc. London, Ser. A, 1966, vol. 295.
Windsor, M.L. and Young, C.L., J. Chromatogr. A, 1967, vol. 27, p. 355.
Cruickshank, A.J.B., Gainey, W., and Young, C.L., Trans. Faraday Soc., 1968, vol. 64, p. 337.
Nogare, S.D. and Juvet, R.S., Gas-Liquid Chromatography, New York: Interscience, 1962.
Atkins, P.W., Physical Chemistry, Oxford: Oxford Univ. Press, 1999.
Kiselev, A.V., Iogansen, A.V., Sakodynskii, K.I., Sakharov, V.M., Yashin, Ya.I., Karnaukhov, A.P., Buyanova, N.E., and Kurkin, G.A., Fiziko-khimicheskoe primenenie gazovoi khromatografii (Physicochemical Applications of Gas Chromatography), Moscow: Khimiya,1973.
de Gennes, P.-G., Scaling Concepts in Polymer Physics. Ithaca, N.Y.: Cornell University Press, 1979.
Patterson, D., Tewari, Y.B., Schreiber, H.P., and Guillet, J.E., Macromolecules, 1971, vol. 4, p. 356.
Yampolskii, Y. and Belov, N., Macromolecules, 2015, vol. 48, p. 6751.
Mohammadi-Jam, S. and Waters, K.E., Adv. Colloid Interface Sci., 2014, vol. 212, p. 21.
Cruickshank, A.J.B., Gainey, W., Hicks, C.P., Letcher, T.M., Moody, R.W., and Young, C.L., Trans. Faraday Soc., 1969, vol. 65, p. 1014.
Grajek, H., J. Chromatogr. A, 2003, vol. 986, p. 89.
Funding
This work was carried out within the framework of a state contract at the Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by V. Makhlyarchuk
Rights and permissions
About this article
Cite this article
Kanat’eva, A.Y., Korolev, A.A. & Kurganov, A.A. Independence of Corrected Retention Volume from Carrier Gas Pressure and Its Value for Gas Chromatography. J Anal Chem 77, 126–130 (2022). https://doi.org/10.1134/S1061934822010063
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934822010063