Abstract
The application of sulfur and nitrogen co-doped carbon quantum dot−potassium permanganate chemiluminescence (CL) system for the determination of trace amounts of deltamethrin insecticide was investigated. The results showed that traces of deltamethrin significantly increased the CL of this system in the optimized conditions. This increase was proportional to the concentration of deltamethrin and was used for its determination. We prepared sulfur and nitrogen co-doped carbon quantum dots by hydrothermal method and characterized by fluorescence, X-ray and infrared spectra and transmission electron microscopy. In the optimum analytical conditions, the calibration graph was linear in the range of 1.8 to 20.0 µg/L with a detection limit of 0.3 µg/L. The new tested method has simple set up, high sensitivity and has been successfully applied to the determination of deltamethrin in water samples.
Similar content being viewed by others
REFERENCES
Yan, X., Li, H., and Su, X., TrAC, Trends. Anal. Chem., 2018, vol. 103, p. 1.
Fereja, T.H., Hymete, A., and Gunasekaran, T., ISRN Spectrosc., 2013, vol. 2013, p. 1.
Nsibande, S.A. and Forbes, P.B.C., Anal. Chim. Acta, 2016, vol. 945, p. 9.
Isacsson, U. and Wettermark, G., Anal. Chim. Acta, 1974, vol. 68, no. 2, p. 339.
Amjadi, M., Manzoori, J.L., Hallaj, T., and Sorouraddin, M.H., Microchim. Acta, 2014, vol. 181, nos. 5–6, p. 671.
Zhang, H.Y., Wang, Y., Xiao, S., Wang, H., Wang, J.H., and Feng, L., Biosens. Bioelectron., 2017, vol. 87, p. 46.
Amjadi, M., Manzoori, J.L., and Hallaj, T., J. Lumin., 2015, vol. 158, p. 160.
Li, H., Shao, F.Q., Zou, S.Y., Yang, Q.J., Huang, H., Feng, J.J., and Wang, A.J., Microchim. Acta, 2016, vol. 183, no. 2, p. 821.
Liu, B. and Han, S., Microchim. Acta, 2016, vol. 183, no. 11, p. 3087.
Cui, X., Wang, Y., Liu, J., Yang, Q., Zhang, B., Gao, Y., Wang, Y., and Lu, G., Sens. Actuators, B, 2017, vol. 242, p. 1272.
Zou, S., Hou, C., Fa, H., Zhang, L., Ma, Y., Dong, L., Li, Dan., Huo, D., and Yang, M., Sens. Actuators, B, 2017, vol. 239, p. 1033.
Zhang, Y., Wang, Y., Feng, X., Zhang, F., Yang, Y., and Liu, X., Appl. Surf. Sci., 2016, vol. 387, p. 1236.
Lin, Y., Yao, B., Huang, T., Zhang, S., Cao, X., and Weng, W., Microchim. Acta, 2016, vol. 183, no. 7, p. 2221.
Hallaj, T., Amjadi, M., Manzoori, J.L., and Azizi, N., Luminescence, 2017, vol. 32, no. 7, p. 1174.
Lau, C., Lu, J., and Kai, M., Anal. Chim. Acta, 2004, vol. 503, no. 2, p. 235.
Lu, J., Lau, C., Lee, M.K., and Kai, M., Anal. Chim. Acta, 2002, vol. 455, no. 2, p. 193.
Amjadi, M., Manzoori, J.L., Hallaj, T., and Sorouraddin, M.H., Spectrochim. Acta, Part A, 2014, vol. 122, p. 715.
Algar, W.R., Kim, H., Medintz, I.L., and Hildebrandt, N., Coord. Chem. Rev., 2014, vol. 263, p. 65.
Gu, D., Shang, S., Yu, Q., and Shen, J., Appl. Surf. Sci., 2016, vol. 390, p. 38.
Amjadi, M., Manzoori, J.L., Hallaj, T., and Azizi, N., J. Lumin., 2017, vol. 182, p. 246.
Ge, S., Lu, J., Ge, L., Yan, M., and Yu, J., Spectrochim. Acta, Part A, 2011, vol. 79, no. 5, p. 1704.
Shan, X., Chai, L., Ma, J., Qian, Z., Chen, J., and Feng, H., Analyst, 2014, vol. 139, no. 10, p. 2322.
Liu, T., Cui, Z., Zhou, J., Wang, Y., and Zou, Z., Nanoscale Res. Lett., 2017, vol. 12, no. 1, p. 375.
Lu, Q., Sun, Y., Ares, I., Anadón, A., Martínez, M., Martínez-Larrañaga, MR., Yuan, Z., Wang, X., and Martínez, MA., Environ. Res., 2019, vol. 170, p. 260.
Kulikov, A.U., Chromatographia, 2007, vol. 66, no. 5, p. 303.
Galera, M.M., García, M.D.G., and Valverde, R.S., J. Chromatogr. A, 2006, vol. 1113, no. 1, p. 191.
Amin, A.S., Moalla, S.M.N., Salama, M.S.S., Ali, A., and Gouda, A.A., Int. J. Adv. Res. Chem. Sci., 2015, vol. 2, no. 10, p. 72.
Ge, S., Zhang, C., Yu, F., Yan, M., and Yu, J., Sens. Actuators. B: Chem., 2011, vol. 156, no. 1, p. 222.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Azimi, M., Manzoori, J.L., Amjadi, M. et al. Determination of Deltamethrin in Water Samples Using Sulfur and Nitrogen Co-Doped Carbon Quantum Dots as a Chemiluminescence Probe. J Anal Chem 76, 1217–1224 (2021). https://doi.org/10.1134/S1061934821100026
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934821100026