Abstract
The results of model experiments on the effect of transition elements (iron, manganese) and sulfide ions on the values of chemical (COD) and biochemical oxygen demand (BOD) are presented. It is shown that, in the presence of transition elements in water, BOD is overestimated. In the presence of 100 mg/L of iron(II) and >0.05 mg/L of sulfides in water, the BOD values exceed those of COD.
Similar content being viewed by others
REFERENCES
PND (Environmental Regulatory Document) F 14.1:2:3:4.123-97: Method for Performing Biochemical Oxygen Demand (BOD) Measurements after n Days of Incubation in Surface Fresh, Underground (Ground), Drinking, Waste, and Treated Waters, Moscow, 2015.
Baena, J.R., Gallego, M., and Valcarel, M., TrAC, Trends Anal. Chem., 2003, no. 22, p. 641.
PND (Environmental Regulatory Document) Titrimetric Method for Measuring Chemical Oxygen Demand in Samples of Natural and Waste Waters, Moscow, 2016.
NOMITECH. https://nomitech.ru/articles-and-blog/sootnoshenie_khpk_i_bpk_dlya_stochnyh_vod_razlichnogo_proiskhozhdeniya. Accessed February 15, 2017.
Dedkov, Yu.M., Ross. Khim. Zh., 2002, vol. 46, no. 4, p. 11.
Abdrakhmanov, I.A., Shaidulina, G.F., Vdovina, I.V., Smirnova, T.P., and Kostitsyn, V.G., Ekol. Sist. Pribory, 2009, no. 9, p. 36.
PND (Environmental Regulatory Document) F 14.1:2.101-97: Method for Performing Measurements of the Weight Concentration of Dissolved Oxygen in Samples of Natural and Treated Wastewaters by the Iodometric Method, Moscow, 2004.
PND (Environmental Regulatory Document) F 14.1:2:4.50-96: Method for Measuring the Weight Concentration of Total Iron in Drinking, Surface and Waste Waters by Photometric Method with Sulfosalicylic Acid, Moscow, 2011.
PND (Environmental Regulatory Document) F 14.1:2:4.178-02: Method for Measuring the Wight Concentrations of Hydrogen Sulfide, Sulfides, and Hydrosulfides in Drinking, Natural, and Waste Waters by Photometric Method, Moscow, 2010.
PND (Environmental Regulatory Document) F 14.1:2:214-06: Method for Measuring the Weight Concentrations of Fe, Co, Mn, Cu, Ni, Cd, Pb, Cr, and Zn in Natural and Waste Waters by Flame Atomic Absorption Spectrometry, Moscow, 2006.
Nekrasov, B.V., Osnovy obshchei khimii (Fundamentals of General Chemistry), Moscow: Khimiya, 1973, vol. 2.
Ivchatov, A.L. and Malov, V.I., Khimiya vody i mikrobiologiya (TRANSLATION), Moscow: INFRA-M, 2009.
Nikiforova, L.O. and Belopol’skii, L.M., Vliyanie tyazhelykh metallov na protsessy biokhimicheskogo okisleniya organicheskikh veshchestv (Effect of Heavy Metals on the Processes of Biochemical Oxidation of Organic Substances), Moscow: BINOM. Laboratoriya znanii, 2012.
Moiseenko, T.I., Dinu, M.I., Gashkina, N.A., and Kremleva, T.A., Water Resour., 2013, vol. 40, no. 4, p. 407.
Martynova, M.V., Russ. J. Gen. Chem., 2012, vol. 82, no. 13, p. 2194.
Nekrasov, B.V., Osnovy obshchei khimii (Fundamentals of General Chemistry), Moscow: Khimiya, 1973, vol. 1.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Zhukova
Rights and permissions
About this article
Cite this article
Safarov, A.M., Khatmullina, R.M., Safarova, V.I. et al. Effect of Transition Elements on Biochemical Oxygen Demand. J Anal Chem 73, 771–776 (2018). https://doi.org/10.1134/S1061934818080087
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061934818080087