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Identification and quantitative determination of some inorganic lanthanide compounds by diffuse reflectance spectroscopy

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Abstract

Diffuse reflectance spectroscopy in the UV, visible, and near-IR regions is found to allow the detection and identification of lanthanide oxides, fluorides, sulfides, and sulfofluorides without decomposing and dissolving samples. A nondestructive method for the detection and quantitative determination of more than 1 wt % of Eu(II) in the corresponding fluorides is proposed.

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Authors and Affiliations

  1. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lyustdorfskaya doroga 86, Odessa, 65080, Ukraine

    V. P. Antonovich, I. V. Stoyanova, N. A. Chivireva, E. V. Timukhin, V. F. Zinchenko & N. P. Efryushina

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  1. V. P. Antonovich
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  2. I. V. Stoyanova
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  3. N. A. Chivireva
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  4. E. V. Timukhin
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  5. V. F. Zinchenko
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  6. N. P. Efryushina
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Original Russian Text © V.P. Antonovich, I.V. Stoyanova, N.A. Chivireva, E.V. Timukhin, V.F. Zinchenko, N.P. Efryushina, 2007, published in Zhurnal Analiticheskoi Khimii, 2007, Vol. 62, No. 3, pp. 263–269.

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Antonovich, V.P., Stoyanova, I.V., Chivireva, N.A. et al. Identification and quantitative determination of some inorganic lanthanide compounds by diffuse reflectance spectroscopy. J Anal Chem 62, 238–244 (2007). https://doi.org/10.1134/S1061934807030070

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  • DOI: https://doi.org/10.1134/S1061934807030070

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