Skip to main content
SpringerLink
Log in

PVC-based Cu (II)-Schiff base complex membrane coated graphite electrode for the determination of the triiodide ion

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A triiodide-selective electrode based on copper (II)-Schiff base complex as a membrane carrier is proposed. The electrode was prepared by incorporating the carrier into a plasticized polyvinylchloride (PVC) membrane and was directly coated on the surface of a graphite electrode. The obtained electrode showed a near Nernstian slope of 57.0 ± 0.4 mV/decade to I −3 ions over an activity range of 1.0 × 10−5−1.0 × 10−1 M with a limit of detection of 4.8 × 10−6 M. The response time of the electrode was fast (5 s) and the electrode could be used for about 2 months without considerable divergence in response. The potentiometric selectivity coefficients were evaluated and displayed anti-Hofmeister behavior. The electrode was used as an indicator electrode in the potentiometric titration of the triiodide ion and in the determination of ascorbic acid in vitamin C tablets.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Schulthess, P., Ammann, D., Kraeutler, B., Caderas, Ch., Stepanek, R., and Simon, W., Anal. Chem., 1985, vol. 57, no. 7, p. 1397.

    Article  CAS  Google Scholar 

  2. Buhlmann, P., Pretsch, E., and Bakker, E., Chem. Rev., 1998, vol. 98, no. 8, p. 1593.

    Article  Google Scholar 

  3. Li, J., Janata, J., and Josowicz, M., Eletroanalysis, 1996, vol. 8, no. 8, p. 778.

    Article  CAS  Google Scholar 

  4. Chang, Q. and Meyerhoff, M.E., Anal. Chim. Acta, 1986, vol. 186, p. 81.

    Article  CAS  Google Scholar 

  5. Suzuki, H., Nakagawa, H., Mifune, M., and Saito, Y., Anal. Sci., 1993, vol. 9, no. 7, p. 351.

    CAS  Google Scholar 

  6. Yuan, R. and Chai, Y.-Q., Liu, D., Gao, D., Li, J.-Z., and Yu, R.-Q., Anal. Chem., 1993, vol. 65, no. 19, p. 2572.

    Article  CAS  Google Scholar 

  7. Yuan, R. and Song, Y.-Q., Chai, Y.-Q., Xia, Sh.-X., Zhong, Q.-Y., Yi, B., Ying, M., Shen, G.-L., and Yu, R.-Q., Talanta, 1999, vol. 48, no. 3, p. 649.

    Article  CAS  Google Scholar 

  8. Daunert, S., Wallace, S., Florido, A., and Bachas, L.G., Anal. Chem., 1991, vol. 63, no. 17, p. 1676.

    Article  CAS  Google Scholar 

  9. Liu, D., Chen, W.-C., Shen, G.L., and Yu, R.-Q., Analyst, 1996, vol. 121, no. 10, p. 1495.

    Article  CAS  Google Scholar 

  10. Day, R.A. and Underwood, A.L., in Quantitative Chemical Analysis, 6th ed., Englewood Cliffs, NJ: Prentice Hall, 1991, p. 639.

    Google Scholar 

  11. Nacapricha, D., Muangkaew, S., Ratanawimarnwong, N., Shiowatana, J., and Grudpan, K., Analyst, 2001, vol. 126, no. 1, p. 121.

    Article  CAS  Google Scholar 

  12. Sadeghi, S., Shamsipur, M., and Elahi, M., Pol. J. Chem., 1997, vol. 71, p. 1594.

    CAS  Google Scholar 

  13. Farhadi, Kh. and Maleki, R., Anal. Sci., 2002, vol. 18, no. 2, p. 133.

    Article  CAS  Google Scholar 

  14. Valsami, G.N., Macheras, P.E., and Koupparis, M.A., Analyst, 1989, vol. 144, no. 3, p. 387.

    Article  Google Scholar 

  15. Rouhollahi, A. and Shamsipur, M., Anal. Chem., 1999, vol. 71, no. 7, p. 135.

    Article  Google Scholar 

  16. Sadeghi, S. and Dashti, Gh.R., Anal. Chem., 2002, vol. 74, no. 11, p. 2591.

    Article  CAS  Google Scholar 

  17. Shamsipur, M., Sadeghi, S., Naeimi, H., and Sharghi, H., Pol. J. Chem., 2000, vol. 74, p. 231.

    CAS  Google Scholar 

  18. Sadeghi, S., Gafarzadeh, A., Naseri, M.A., and Sharghi, H., Sens. Actuators, B, 2004, vol. 98, nos. 2–3, p. 174.

    Article  CAS  Google Scholar 

  19. Sadeghi, S., Eslahi, M., Naseri, M.A., Naeimi, H., Sharghi, H., and Shameli, A., Electroanalaysis, 2003, vol. 15, no. 7, p. 1327.

    Article  CAS  Google Scholar 

  20. Sharghi, H. and Naeimi, H., Bull. Chem. Soc. Jpn., 1999, vol. 72, nos. 15–16, p. 1525.

    Article  CAS  Google Scholar 

  21. Naeimi, H., Sci. (Chem.) Ph. D. Dissertation, Shiraz: Shiraz University, 1998.

    Google Scholar 

  22. Kamata, S., Bhale, A., Fukunaga, Y., and Murata, H., Anal. Chem., 1988, vol. 60, no. 22, p. 2464.

    Article  CAS  Google Scholar 

  23. Malon, A., Radu, A., Qin, W., Qin, Yu., Ceresa, A., Maj-Zurawska, M., Bakker, E., and Pretsch, E., Anal. Chem., 2003, vol. 75, no. 15, p. 3865.

    Article  CAS  Google Scholar 

  24. Hariss, D.C., in Quantitative Chemical Analysis, 4th ed., New York: Freeman, 1995, p. 439.

    Google Scholar 

  25. Umezawa, Y., Umezawa, K., and Saito, H., Pure Appl. Chem., 1995, vol. 68, no. 2, p. 507.

    Google Scholar 

  26. Li, Z.-Q., Yuan, R., Ying, H., Song, Y.-Q., Shen, G.L., and Yu, R.-Q., Anal. Lett., 1997, vol. 30, no. 9, p. 1455.

    CAS  Google Scholar 

  27. Shamsipur, M., Solymanpour, A., Akhond, M., Sharghi, H., and Naser, M.A., Anal. Chim. Acta, 2001, vol. 450, nos. 1–2, p. 37.

    Article  CAS  Google Scholar 

  28. Ying, M., Yuan, R., Zhang, X.-M., Song, Y.-Q., Li, Z.-Q., Shen, G.L., and Yu, R.Q., Analyst, 1997, vol. 122, no. 10, p. 1143.

    Article  CAS  Google Scholar 

  29. Farhadi, Kh., Shaikhlouei, H., Maleki, R., Sharghi, H., and Shamsipur, M., Bull. Korean Chem. Soc., 2002, vol. 23, no. 11, p. 1635.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Birjand University, Faculty of Science, P.O. Box 97175-615, Birjand, Iran

    S. Sadeghi & A. Gafarzadeh

  2. Department of Chemistry, Kashan University, Faculty of Science, Kashan, Iran

    H. Naeimi

Authors
  1. S. Sadeghi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Gafarzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Naeimi
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sadeghi, S., Gafarzadeh, A. & Naeimi, H. PVC-based Cu (II)-Schiff base complex membrane coated graphite electrode for the determination of the triiodide ion. J Anal Chem 61, 677–682 (2006). https://doi.org/10.1134/S1061934806070136

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934806070136

Keywords

Search

Navigation