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Main Processes Facilitating the Formation of Composite Silica-Based Nanocolloids Doped with Complexes of d- and f-Metals and Inorganic Nanoparticles

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Abstract

This review is devoted to the analysis of various supramolecular interactions that facilitate the incorporation of water-soluble complexes of d- and f-metals and inorganic nanoparticles into silica-based nanomaterials formed within the framework of two main methods (the water-in-oil microemulsion and Stöber methods). The interest in such nanomaterials is due to the possibility of their use in different fields of chemistry and medicine. The driving forces and regularities of the incorporation of transition metal ions and complexes and nanoparticles of metal oxides and sulfides (dopants) into silica nanoparticles are discussed. The presented regularities, correlations, and possible mechanisms of incorporating diverse dopants into polymer matrices have shown the multifactor character of this process and provided the prerequisites for the control over it via the selection of an incorporation method or a preliminary treatment of the used ions, complexes, and nanoparticles.

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Funding

The work was supported by the Russian Foundation for Basic Research, project no. Ital_t 20-53-7802.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, FRC, Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    S. V. Fedorenko, A. S. Stepanov, O. D. Bochkova & A. R. Mustafina

  2. Kazan (Volga region) Federal University, 420008, Kazan, Russia

    O. D. Bochkova

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  1. S. V. Fedorenko
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  2. A. S. Stepanov
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  3. O. D. Bochkova
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Fedorenko, S.V., Stepanov, A.S., Bochkova, O.D. et al. Main Processes Facilitating the Formation of Composite Silica-Based Nanocolloids Doped with Complexes of d- and f-Metals and Inorganic Nanoparticles. Colloid J 84, 611–620 (2022). https://doi.org/10.1134/S1061933X22700077

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