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A Model Description of Diffusion Permeability of Bilayer Ion-Exchange Membranes

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Abstract

A model approach is developed, which enables one, using the concentration dependences of the diffusion permeability for individual layers, to estimate the density of a diffusion flux through a bilayer membrane, determine the concentration of a virtual solution at the interface between the membrane layers, and find the thickness of each layer that has constant diffusion characteristics. The approach is verified by the example of a perfluorinated MF-4SC membrane, with its surface being modified with polyaniline under different conditions. The adequacy of the approach is confirmed by a satisfactory coincidence of the modified layer thicknesses calculated in terms of the model and found by the optical examination of membrane sections.

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REFERENCES

  1. Loza, S.A., Zabolotsky, V.I., Loza, N.V., and Fomenko, M.A., Pet. Chem., 2016, vol. 56, p. 1027.

    Article  CAS  Google Scholar 

  2. Melnikov, S.S., Sheldeshov, N.V., and Zabolotskii, V.I., Desalin. Water Treat., 2018, vol. 123, p. 1.

    Article  CAS  Google Scholar 

  3. Zabolotskii, V., Sheldeshov, N., and Melnikov, S., J. Appl. Electrochem., 2013, vol. 43, p. 1117.

    Article  CAS  Google Scholar 

  4. Zhao, Y., Tang, K., Liu, H., Van der Bruggen, B., Sotto Díaz, A., Shen, J., and Gao, C., J. Membr. Sci., 2016, vol. 520, p. 262.

    Article  CAS  Google Scholar 

  5. Berezina, N.P., Kononenko, N.A., Filippov, A.N., Shkirskaya, S.A., Falina, I.V., and Sycheva, A.A.-R., Russ. J. Electrochem., 2010, vol. 46, p. 485.

    Article  CAS  Google Scholar 

  6. Kononenko, N.A., Loza, N.V., Shkirskaya, S.A., Falina, I.V., and Khanukaeva, D.Yu., J. Solid State Electrochem., 2015, vol. 19, p. 2623.

    Article  CAS  Google Scholar 

  7. Protasov, K.V., Shkirskaya, S.A., Berezina, N.P., and Zabolotskii, V.I., Russ. J. Electrochem., 2010, vol. 46, p. 1131.

    Article  CAS  Google Scholar 

  8. Moshtarikhah, S., Oppers, N.A.W., De Groot, M.T., Keurentjes, J.T.F., Schouten, J.C., and Van der Schaaf, J., J. Appl. Electrochem., 2017, vol. 47, p. 213.

    Article  CAS  Google Scholar 

  9. Lebedev, K., Ramırez, P., Mafe, S., and Pellicer, J., Langmuir, 2000, vol. 16, p. 9941.

    Article  CAS  Google Scholar 

  10. Nikonenko, V.V., Zabolotskii, V.I., and Lebedev, K.A., Elektrokhimiya, 1996, vol. 32, p. 234.

    CAS  Google Scholar 

  11. Filippov, A.N., Starov, V.M., Kononenko, N.A., and Berezina, N.P., Adv. Colloid Interface Sci., 2008, vol. 139, p. 29.

    Article  CAS  Google Scholar 

  12. Kononenko, N.A., Gnusin, N.P., Berezina, N.P., and Parshikov, S.B., Russ. J. Electrochem., 2002, vol. 38, p. 828.

    Article  CAS  Google Scholar 

  13. Gnusin, N.P., Berezina, N.P., Shudrenko, A.A., and Ivina, O.P., Zh. Fiz. Khim., 1994, vol. 68, p. 565.

    CAS  Google Scholar 

  14. Demina, O.A., Kononenko, N.A., Falina, I.V., and Demin, A.V., Colloid J., 2017, vol. 79, p. 317.

    Article  CAS  Google Scholar 

  15. Filippov, A.N., Kononenko, N.A., and Demina, O.A., Colloid J., 2017, vol. 79, p. 556.

    Article  CAS  Google Scholar 

  16. Shkirskaya, S.A., Sycheva, A.A., Berezina, N.P., Timofeev, C.B., and Krishtopa, M.V., RF Patent No. 2411070 (2009).

  17. Berezina, N.P., Shkirskaya, S.A., Kolechko, M.V., Popova, O.V., Senchikhin, I.N., and Roldughin, V.I., Russ. J. Electrochem., 2011, vol. 47, p. 995.

    Article  CAS  Google Scholar 

  18. Shkirskaya, S.A., Extended Abstract of Cand. Sci. (Chem.) Dissertation, Krasnodar: Kuban State Univ., 2008.

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Funding

This work was supported by the Russian Foundation for Basic Research, project no. 18-38-20069.

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Correspondence to I. V. Falina.

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Translated by E. Khozina

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Falina, I.V., Demina, O.A., Kononenko, N.A. et al. A Model Description of Diffusion Permeability of Bilayer Ion-Exchange Membranes. Colloid J 82, 200–207 (2020). https://doi.org/10.1134/S1061933X20010044

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  • DOI: https://doi.org/10.1134/S1061933X20010044

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