Abstract
A model approach is developed, which enables one, using the concentration dependences of the diffusion permeability for individual layers, to estimate the density of a diffusion flux through a bilayer membrane, determine the concentration of a virtual solution at the interface between the membrane layers, and find the thickness of each layer that has constant diffusion characteristics. The approach is verified by the example of a perfluorinated MF-4SC membrane, with its surface being modified with polyaniline under different conditions. The adequacy of the approach is confirmed by a satisfactory coincidence of the modified layer thicknesses calculated in terms of the model and found by the optical examination of membrane sections.
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REFERENCES
Loza, S.A., Zabolotsky, V.I., Loza, N.V., and Fomenko, M.A., Pet. Chem., 2016, vol. 56, p. 1027.
Melnikov, S.S., Sheldeshov, N.V., and Zabolotskii, V.I., Desalin. Water Treat., 2018, vol. 123, p. 1.
Zabolotskii, V., Sheldeshov, N., and Melnikov, S., J. Appl. Electrochem., 2013, vol. 43, p. 1117.
Zhao, Y., Tang, K., Liu, H., Van der Bruggen, B., Sotto Díaz, A., Shen, J., and Gao, C., J. Membr. Sci., 2016, vol. 520, p. 262.
Berezina, N.P., Kononenko, N.A., Filippov, A.N., Shkirskaya, S.A., Falina, I.V., and Sycheva, A.A.-R., Russ. J. Electrochem., 2010, vol. 46, p. 485.
Kononenko, N.A., Loza, N.V., Shkirskaya, S.A., Falina, I.V., and Khanukaeva, D.Yu., J. Solid State Electrochem., 2015, vol. 19, p. 2623.
Protasov, K.V., Shkirskaya, S.A., Berezina, N.P., and Zabolotskii, V.I., Russ. J. Electrochem., 2010, vol. 46, p. 1131.
Moshtarikhah, S., Oppers, N.A.W., De Groot, M.T., Keurentjes, J.T.F., Schouten, J.C., and Van der Schaaf, J., J. Appl. Electrochem., 2017, vol. 47, p. 213.
Lebedev, K., Ramırez, P., Mafe, S., and Pellicer, J., Langmuir, 2000, vol. 16, p. 9941.
Nikonenko, V.V., Zabolotskii, V.I., and Lebedev, K.A., Elektrokhimiya, 1996, vol. 32, p. 234.
Filippov, A.N., Starov, V.M., Kononenko, N.A., and Berezina, N.P., Adv. Colloid Interface Sci., 2008, vol. 139, p. 29.
Kononenko, N.A., Gnusin, N.P., Berezina, N.P., and Parshikov, S.B., Russ. J. Electrochem., 2002, vol. 38, p. 828.
Gnusin, N.P., Berezina, N.P., Shudrenko, A.A., and Ivina, O.P., Zh. Fiz. Khim., 1994, vol. 68, p. 565.
Demina, O.A., Kononenko, N.A., Falina, I.V., and Demin, A.V., Colloid J., 2017, vol. 79, p. 317.
Filippov, A.N., Kononenko, N.A., and Demina, O.A., Colloid J., 2017, vol. 79, p. 556.
Shkirskaya, S.A., Sycheva, A.A., Berezina, N.P., Timofeev, C.B., and Krishtopa, M.V., RF Patent No. 2411070 (2009).
Berezina, N.P., Shkirskaya, S.A., Kolechko, M.V., Popova, O.V., Senchikhin, I.N., and Roldughin, V.I., Russ. J. Electrochem., 2011, vol. 47, p. 995.
Shkirskaya, S.A., Extended Abstract of Cand. Sci. (Chem.) Dissertation, Krasnodar: Kuban State Univ., 2008.
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This work was supported by the Russian Foundation for Basic Research, project no. 18-38-20069.
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Translated by E. Khozina
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Falina, I.V., Demina, O.A., Kononenko, N.A. et al. A Model Description of Diffusion Permeability of Bilayer Ion-Exchange Membranes. Colloid J 82, 200–207 (2020). https://doi.org/10.1134/S1061933X20010044
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DOI: https://doi.org/10.1134/S1061933X20010044