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A study of cryostructuring of a polymer system. 39. Poly(vinyl alcohol) composite cryogels filled with chitosan microparticles

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Abstract

Composite macroporous poly(vinyl alcohol) (PVA) cryogels have been prepared by cryogenic treatment (freezing at −20°C for 12 h followed by defrosting at a rate of 0.03°C/min) of dispersions of chitosan particles swollen in an aqueous 120 g/L PVA solution. The elasticity moduli and fusion temperatures have been determined for corresponding samples, and their microstructure has been investigated by optical microscopic examination of their thin sections. The rigidity and heat endurance of the PVA-chitosan composite cryogels have been shown to increase with filler concentration. In addition, the rheological properties of initial dispersions have been studied and the appearance of adhesion contacts between discrete and continuous phases has been revealed already at the stage of dispersion preparation. The optical microscopic investigations of the morphological features of the initial dispersions and the microstructure of the composites have established a relatively uniform distribution of filler particles in the bulk of composite cryogels. It has been shown that chitosan particles incorporated into the matrix of the macroporous PVA cryogel are capable of sorbing heavy metal ions—in particular, bivalent copper ions—from aqueous solutions.

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References

  1. Lozinskii, V.I., Usp. Khim., 1998, vol. 67, p. 641.

    Google Scholar 

  2. Gutiérrez, M.C., Aranaz, I., Ferrer, M.L., and Del Monto, F., in Macroporous Polymers: Production, Properties and Biological/Biomedical Applications, Mattiasson, B., Kumar, A., and Galaev, I., Eds., Boca Raton: CRC, 2010, p. 83.

  3. Gun’ko, V.M., Savina, I.N., and Mikhalovsky, S.V., Adv. Colloid Interface Sci., 2013, vols. 187–188, p. 1.

    Article  Google Scholar 

  4. Lozinskii, V.I., Vakula, A.S., and Zubov, A.L., Biotekhnologiya, 1992, no. 4, p. 5.

    Google Scholar 

  5. Lazzeri, L., Trends Polym. Sci., 1996, vol. 4, p. 249.

    CAS  Google Scholar 

  6. Lozinsky, V.I. and Plieva, F.M., Enzyme Microb. Technol., 1998, vol. 23, p. 227.

    Article  CAS  Google Scholar 

  7. Altunina, L.K., Kuvshinov, V.A., and Dolgikh, S.N., in Advances in Geological Storage of Carbon Dioxide, Lombardi, S., Altunina, L.K., and Beaubien, S.E., Eds., NATO Sci. Ser. IV, Earth Environ. Sci., 2006, vol. 65, p. 103.

  8. Pan, Y., Xiong, D., and Gao, F., J. Mater. Sci., Mater. Med., 2008, vol. 19, p. 1963.

    Article  CAS  Google Scholar 

  9. Lozinskii, V.I., Izv. Ross. Akad. Nauk, Ser. Khim., 2008, p. 996.

    Google Scholar 

  10. Baker, M.I., Walsh, S.P., Schwartz, Z., and Boyan, B.D., J. Biomed. Mater. Res., Appl. Biomater., 2012, vol. 100, p. 1451.

    Article  Google Scholar 

  11. Wan, W., Bannerman, A.D., Yang, L., and Mak, H., Adv. Polym. Sci., 2014, vol. 263, p. 285.

    Google Scholar 

  12. Kumar, M.N.V.R., React. Funct. Polym., 2000, vol. 46, p. 1.

    Article  CAS  Google Scholar 

  13. Berger, J., Reist, M., Mayer, J.M., Felt, O., Peppas, N.A., and Gurny, R., Eur. J. Pharm. Biopharm., 2004, vol. 57, p. 19.

    Article  CAS  Google Scholar 

  14. Muzzarelli, R.A.A. and Muzzarelli, C., Adv. Polym. Sci., 2005, vol. 186, p. 151.

    Article  CAS  Google Scholar 

  15. Kurita, K., Marine Biotechnol., 2006, vol. 8, p. 203.

    Article  CAS  Google Scholar 

  16. Vrana, N.E., Liu, Y., McGuinness, G.B., and Cahill, P.A., Macromol. Symp., 2008, vol. 269, no. 1, p. 106.

    Article  CAS  Google Scholar 

  17. Mathews, D.T., Birney, Y.A., Cahill, P.A., and McGuinness, G.B., J. Biomed. Mater. Res., Appl. Biomater., 2008, vol. 84, p. 531.

    Article  CAS  Google Scholar 

  18. Addel-Mohsen, A.M., Aly, A.S., Hrdina, R., Montaser, A.S., and Hebeish, A., J. Polym. Environ., 2011, vol. 19, p. 1005.

    Article  Google Scholar 

  19. Lozinsky, V.I., Solodova, E.V., Zubov, A.L., and Simenel, I.A., J. Appl. Polym. Sci., 1995, vol. 58, p. 171.

    Article  CAS  Google Scholar 

  20. Lozinsky, V.I., Damshkaln, L.G., Kurochkin, I.N., and Kurochkin, I.I., Colloid J., 2007, vol. 69, p. 747.

    Article  CAS  Google Scholar 

  21. Podorozhko, E.A., D’yakonova, E.A., Kolosova, O.E., Klabukova, L.F., and Lozinsky, V.I., Colloid J., 2012, vol. 74, p. 708.

    Article  CAS  Google Scholar 

  22. Podorozhko, E.A., D’yakonova, E.A., and Lozinsky, V.I., Colloid J., 2015, vol. 77, p. 46.

    Article  CAS  Google Scholar 

  23. Lozinsky, V.I., Zubov, A.L., and Titova, E.F., Enzyme Microb. Technol., 1996, vol. 18, p. 561.

    Article  CAS  Google Scholar 

  24. Lozinsky, V.I., Zubov, A.L., Savina, I.N., and Plieva, F.M., J. Appl. Polym. Sci., 2000, vol. 77, p. 1822.

    Article  CAS  Google Scholar 

  25. Lozinskii, V.I. and Zubov, A.L., RF Patent no. 2036095, 1992; Byull. Izobret., 1995, no. 15.

  26. Lipatov, Yu.S., Fizicheskaya khimiya napolnennykh polimerov (Physical Chemistry of Filled Polymers), Moscow: Khimiya, 1977.

    Google Scholar 

  27. Lozinsky, V.I., Damshkaln, L.G., Kurochkin, I.N., and Kurochkin, I.I., Eur. Polym. J., 2014, vol. 53, p. 189.

    Article  CAS  Google Scholar 

  28. Mikhailov, N.V. and Rehbinder, P.A., Kolloidn. Zh., 1955, vol. 17, p. 107.

    CAS  Google Scholar 

  29. Matveenko, V.N. and Kirsanov, E.A., Vestn. Mosk. Univ., Ser. 2: Khim., 2011, vol. 2, p. 243.

    Google Scholar 

  30. Uriev, N.B., Usp. Khim., 2004, vol. 73, p. 39.

    Article  Google Scholar 

  31. Eldridge, J.E. and Ferry, J.D., J. Phys. Chem., 1954, vol. 58, p. 992.

    Article  CAS  Google Scholar 

  32. Hassan, C.M. and Peppas, N.A., Adv. Polym. Sci., 2000, vol. 153, p. 37.

    Article  CAS  Google Scholar 

  33. Lozinsky, V.I., Zubov, A.L., Kulakova, V.K., Titova, E.F., and Rogozhin, S.V., J. Appl. Polym. Sci., 1992, vol. 44, p. 1423.

    Article  Google Scholar 

  34. Lozinsky, V.I., Zubov, A.L., and Titova, E.I., Enzyme Microb. Technol., 1997, vol. 20, p. 182.

    Article  CAS  Google Scholar 

  35. Hatakeyama, T., Yamaguchi, A., and Hatakeyama, H., Eur. Polym. J., 1987, vol. 23, p. 361.

    Article  CAS  Google Scholar 

  36. Watase, M. and Nishinari, K., Makromol. Chem., 1988, vol. 189, p. 871.

    Article  CAS  Google Scholar 

  37. Lozinsky, V.I., Vainerman, E.S., Domotenko, L.V., Mamtsis, A.M., Titova, E.F., Belavtseva, E.M., and Rogozhin, S.V., Colloid Polym. Sci., 1986, vol. 264, p. 19.

    Article  CAS  Google Scholar 

  38. Podorozhko, E.A., Korlyukov, A.A., and Lozinsky, V.I., J. Appl. Polym. Sci., 2010, vol. 117, p. 1332.

    CAS  Google Scholar 

  39. Lozinskii, V.I., Izv. Akad. Nauk, Ser. Khim., 2008, p. 996.

    Google Scholar 

  40. Savina, I.N., Hanora, A., Plieva, F.M., Galaev, I.Yu., Mattiasson, B., and Lozinsky, V.I., J. Appl. Polym. Sci., 2005, vol. 95, p. 529.

    Article  CAS  Google Scholar 

  41. Salmon, S. and Hudson, S.M., J. Macromol. Sci. C, 1997, vol. 37, p. 199.

    Google Scholar 

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    E. A. Podorozhko, A. N. Ryabev & V. I. Lozinsky

  2. Moscow State University of Design and Technology, ul. Sadovnicheskaya 33/1, Moscow, 117997, Russia

    I. A. Lunev & N. R. Kil’deeva

Authors
  1. E. A. Podorozhko
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  2. I. A. Lunev
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  3. A. N. Ryabev
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  4. N. R. Kil’deeva
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  5. V. I. Lozinsky
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Correspondence to V. I. Lozinsky.

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Original Russian Text © E.A. Podorozhko, I.A. Lunev, A.N. Ryabev, N.R. Kil’deeva, V.I. Lozinsky, 2015, published in Kolloidnyi Zhurnal, 2015, Vol. 77, No. 2, pp. 197–206.

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Podorozhko, E.A., Lunev, I.A., Ryabev, A.N. et al. A study of cryostructuring of a polymer system. 39. Poly(vinyl alcohol) composite cryogels filled with chitosan microparticles. Colloid J 77, 186–195 (2015). https://doi.org/10.1134/S1061933X1502012X

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  • DOI: https://doi.org/10.1134/S1061933X1502012X

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