Skip to main content
SpringerLink
Log in

Study of cryostructurization of polymer systems VII. Structure formation under freezing of poly(vinyl alcohol) aqueous solutions

  • Polymer Science
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

Rheological properties of the cryogels produced by freezing of concentrated aqueous solutions of poly(vinyl alcohol) have been studied. These properties were shown to depend on the polymer concentration in the initial solution, on PVA molecular weight, cryostructurization duration and temperature. Electron microscopy demonstrates the heterogeneous porous structure of these cryogels and the dependence of the observed pattern on the conditions of formation of the studied objects.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Labudzińska A, Ziabicki A (1971) Kolloid Z und Z Polymere 243:21

    Google Scholar 

  2. Kukharchik MM, Baramboim NK (1972) Vysokomolekul soed 12B:843

    Google Scholar 

  3. Gul' VE, Bulatnikova LI, Belyatskaya ON, Ermakova EV, Bykova LV (1976) Vysokomolekul soed 18A:118

    Google Scholar 

  4. Watase M (1983) Nippon Kagaku Kaisi, in Japan No 7:973

    Google Scholar 

  5. Watase M (1983) Nippon Kagaku Kaisi, in Japan No 9:1254

    Google Scholar 

  6. Watase M, Nishinari K, Nambu M (1983) Polymer Communications 24:53

    Google Scholar 

  7. Watase M, Nishinari K (1983) Polymer Communications 24:270

    Google Scholar 

  8. Rogozhin SV, Lozinsky VI, Vainerman ES, Domotenko LV, Mamtsis AM, Ivanova SA, Shtil'man MI, Korshak W (1984) Dokl Akad nauk SSSR 278:129

    Google Scholar 

  9. Beresniewicz A (1959) J Polym Sci 35:321

    Google Scholar 

  10. Toroptseva AM, Belogorodskaya KV, Bondarenko VM (1972) Laboratory Manual in Chemistry and Technology of High Molecular Weight Compounds, Leningrad, „Khimia“, p 138, in russ.

    Google Scholar 

  11. Kargin VA, Sogolova TI (1949) Zhurn phys khim 23:540

    Google Scholar 

  12. Hrouz J, Ilavsky M, Havliček J, Dušek K (1978) Collection of Czechoslovak Chem Comm 43:1999

    Google Scholar 

  13. Lee EH, Radok JR (1960) J Appl Mech 27:438

    Google Scholar 

  14. Belavtseva EM, Titova EF, Lozinsky VI, Vainerman ES, Rogozhin SV (1984) Coll & Polym Sci 262:775

    Google Scholar 

  15. Lozinsky VI, Vainerman ES, Rogozhin SV (1982) Inventor's Certificate of the USSR No 1008214

  16. Rogozhin SV, Vainerman ES, Lozinsky VI (1982) Dokl Akad nauk SSSR 263:115

    Google Scholar 

  17. Obolonkova ES, Rogovina LZ, Dmitrieva NA, Belavtseva EM, Slonimsky GL (1974) Kolloidn zhurn 36:284

    Google Scholar 

Download references

Author information

Author notes

  1. V. I. Lozinsky

    Present address: A. N. Nesmeyanov Institute of Organoelement Compounds USSR Academy of Sciences, Moscow, U.S.S.R.

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds USSR Academy of Sciences, Moscow, U.S.S.R.

    E. S. Vainerman, L. V. Domotenko, A. M. Mamtsis, E. F. Titova, E. M. Belavtseva & S. V. Rogozhin

Authors
  1. V. I. Lozinsky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. S. Vainerman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Domotenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Mamtsis
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. F. Titova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. E. M. Belavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. V. Rogozhin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lozinsky, V.I., Vainerman, E.S., Domotenko, L.V. et al. Study of cryostructurization of polymer systems VII. Structure formation under freezing of poly(vinyl alcohol) aqueous solutions. Colloid & Polymer Sci 264, 19–24 (1986). https://doi.org/10.1007/BF01410304

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01410304

Key words

Search

Navigation