Skip to main content
SpringerLink
Log in

Comprehensive ion-exchange and adsorption study of the distribution of exchanging inorganic cations over the interlayer gaps of vermiculite

  • Published:
Colloid Journal Aims and scope Submit manuscript

Abstract

The exchange of Co2+ ions on Na-vermiculite has been comprehensively studied by the ionexchange, adsorption, and X-ray diffraction methods. It has been shown that vermiculite is distinguished by high selectivity to Co2+ cations and Kielland dependence log \(\tilde K_m (\theta )\) increasing with filling of ion-exchange sites with sorbed cations rather than a decreasing one that is observed for common systems. It has been established that the ion exchange is accompanied by segregation of Na+ and Co2+ cations in separate interlayer gaps of vermiculite with the final formation of a disordered layered “cake” composed of separate silicate layers and interlayer gaps enriched with Na+ and Co2+ ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Theng, B.K.G., Greenland, D.J., and Quirk, J.P., Clay Miner., 1967, vol. 7, p. 1.

    Article  CAS  Google Scholar 

  2. McBride, M.B. and Mortland, M.M., Clay Miner., 1975, vol. 10, p. 357.

    Article  CAS  Google Scholar 

  3. Maes, A., Peigner, P., and Cremers, A., Abstracts of Papers, Int. Clay Conf., Mexico, 1975; Illinois: Appl. Pull. Wilmette, 1975, p. 319.

    Google Scholar 

  4. Tarasevich, Yu.I., Stroenie i khimiya poverkhnosti sloistykh silikatov (Surface Structure and Chemistry of Layered Silicates), Kiev: Naukova Dumka, 1988.

    Google Scholar 

  5. Maes, A. and Cremers, A., J. Chem. Soc., Faraday Trans. 1, 1978, vol. 74, p. 1234.

    Article  CAS  Google Scholar 

  6. Polyakov, V.E. and Tarasevich, Yu.I., Khim. Tekhnol. Vody, 2012, vol. 34, p. 18.

    CAS  Google Scholar 

  7. Levy, R. and Shainberg, I., Clays Clay Miner., 1972, vol. 20, p. 37.

    Article  CAS  Google Scholar 

  8. The X-Ray Identification and Crystal Structures of Clay Minerals, Brown, G., Ed., London, 1961.

    Google Scholar 

  9. Saehr, D., Le Dreed, R., and Wey, R., Abstracts of Papers, Int. Clay Conf., Bologna and Pavia, Italy, 1981; Amsterdam: Elsevier, 1982, p. 133.

    Google Scholar 

  10. Glaeser, R. and Mering, J., Clay Miner. Bull., 1954, vol. 2, p. 188.

    Article  CAS  Google Scholar 

  11. Glaeser, R. and Mering, J., C.R. Acad. Sci., 1958, vol. 246, p. 1569.

    CAS  Google Scholar 

  12. McBride, M.B. and Mortland, M.M., Clays Clay Miner., 1973, vol. 21, p. 323.

    Article  CAS  Google Scholar 

  13. Sharkina, E.V., Stroenie i svoistva organomineral’nykh soedinenii (Structure and Properties of Organomineral Compounds), Kiev: Naukova Dumka, 1976.

    Google Scholar 

  14. Zhukova, A.I., Bondarenko, S.V., Sharkina, E.V., Rudenko, V.M., and Tarasevich, Yu.I., in Fizikokhimicheskaya mekhanika i liofil’nost’ dispersnykh sistem (Physicochemical Mechanics and Lyophilicity of Disperse Systems), Kiev: Naukova Dumka, 1977, no. 9, p. 9.

    Google Scholar 

  15. Barrer, R.M. and Falconer, J.D., Proc. R. Soc. London A, 1956, vol. 236, p. 227.

    Article  CAS  Google Scholar 

  16. Tarasevich, Yu.I., Khim. Tekhnol. Vody, 1982, vol. 4, p. 19.

    CAS  Google Scholar 

  17. Tarasevich, Yu.I., Poverkhnostnye yavleniya na dispersnykh materialakh (Surface Phenomena in Disperse Materials), Kiev: Naukova Dumka, 2011.

    Google Scholar 

  18. Khachaturyan, A.G., Teoriya fazovykh prevrashchenii i struktura tverdykh rastvorov (The Theory of Phase Transitions and Solid Solution Structure), Moscow: Nauka, 1974.

    Google Scholar 

  19. Laird, D.A. and Shang, C., Clays Clay Miner., 1997, vol. 45, p. 681.

    Article  CAS  Google Scholar 

  20. Tarasevich, Yu.I., Krysenko, D.A., Polyakov, V.E., and Aksenenko, E.V., Zh. Fiz. Khim., 2008, vol. 82, p. 1682.

    Google Scholar 

  21. Goronovskii, I.T., Nazarenko, Yu.P., and Nekryach, E.F., Kratkii spravochnik po khimii (An Abridged Handbook of Chemistry), Kiev: Naukova Dumka, 1987.

    Google Scholar 

  22. Tarasevich, Yu.I., Polyakov, V.E., and Krysenko, D.A., Zh. Fiz. Khim., 2010, vol. 84, p. 978.

    Google Scholar 

  23. Polyakov, V.E., Tarasevich, Yu.I., and Alekseev, O.L., Ukr. Khim. Zh., 1968, vol. 34, p. 526.

    CAS  Google Scholar 

  24. Amflett, Ch., Neorganicheskie ionity (Inorganic Ionites), Moscow: Mir, 1966.

    Google Scholar 

  25. Tarasevich, Yu.I., Krysenko, D.A., and Polyakov, V.E., Kolloidn. Zh., 2002, vol. 64, p. 836.

    Google Scholar 

  26. Simoncic, P. and Armbruster, T., Am. Mineral., 2004, vol. 89, p. 421.

    CAS  Google Scholar 

  27. Skipper, N.T., Soper, A.K., and McConnel, J.D.C., J. Chem. Phys., 1991, vol. 94, p. 5751.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Dumanskii Institute of Colloid and Water Chemistry, National Academy of Sciences of Ukraine, bul’v. Akademika Vernadskogo 42, Kyiv, 03680, Ukraine

    Yu. I. Tarasevich, D. A. Krysenko, Z. G. Ivanova & V. E. Polyakov

Authors
  1. Yu. I. Tarasevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. A. Krysenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Z. G. Ivanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. E. Polyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © Yu.I. Tarasevich, D.A. Krysenko, Z.G. Ivanova, V.E. Polyakov, 2013, published in Kolloidnyi Zhurnal, 2013, Vol. 75, No. 3, pp. 379–384.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tarasevich, Y.I., Krysenko, D.A., Ivanova, Z.G. et al. Comprehensive ion-exchange and adsorption study of the distribution of exchanging inorganic cations over the interlayer gaps of vermiculite. Colloid J 75, 345–350 (2013). https://doi.org/10.1134/S1061933X13030162

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X13030162

Keywords

Search

Navigation