Abstract
We consider some features of applying the method of acoustic emission (AE) for monitoring electrolysis. The dynamics of changes in AE at the nonequilibrium stage of electrodeposition of copper from a sulfate electrolyte is described. It is shown that the AE method allows one to evaluate the kinetics of electrolysis and recognize its nonequilibrium stage. The foundations of a method for determining the dynamics of electrolysis in real time based on the parameters of the concomitant emission of ultrasound are proposed.
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REFERENCES
Ivanov, V.I. and Barat V.A., Akustiko-emissionnaya diagnostika (Acoustic-Emission Diagnostics), Moscow: Spektr, 2017.
Builo, S.I., Fiziko-mekhanicheskie i statisticheskie aspekty povysheniya dostovernosti rezul’tatov akustiko-emissionnogo kontrolya i diagnostiki (Physico-Mechanical and Statistical Aspects of Increasing the Reliability of Results of Acoustic Emission Monitoring and Diagnostics), Rostov-on-Don: South. Fed. Univ., 2008.
Builo, S.I. and Kuznetsov, D.M., Acoustic-emission testing and diagnostics of the kinetics of physicochemical processes in liquid media, Russ. J. Nondestr. Test., 2010, vol. 46, no. 9, pp. 684–689.
Urbach, A., Banov, M., Harbuz Ye., Zujevs, V., and Khodos, N., Application of acoustic emission method for research of process of crystallic substance dilution, Sci. J. Riga Tech. Univ., 2010, vol. 34, pp. 48–53.
Titarenko, N.N., Dvornikov, P.A., Kovtun, S.N., and Polionov, V.P., Using generation of acoustic vibrations in chemical reaction and properties of the bubble medium in liquid to reveal through defects in claddings of slugs with sodium, Izv. Vyssh. Uchebn. Zaved. Yad. Energ., 2013, no. 1, pp. 35–42.
Builo, S.I., Kuznetsov, D.M., and Gaponov, V.L., Acoustic emission testing of capillary liquid flows in porous media, Russ. J. Nondestr. Test., 2014, vol. 50, no. 7, pp. 392–395.
Builo, S.I., Kuznetsov, D.M., and Gaponov, V.L., Acoustic emission diagnostics of the kinetics of physicochemical processes in liquid and solid media, in Advanced Materials. Studies and Applications, New York: Nova Science Publ., 2015, ch. 13, pp. 193–208.
Builo, S.I., Kuznetsov, D.M., Gaponov, V.L., and Balakai, V.I., The acoustic emission diagnostics of galvanic process kinetics, in Proc. Int. Conf. Phys. Mech. New Mater. Appl., New York: Nova Science Publ., 2017, ch. 63, pp. 457–462.
Builo, S.I., A method for identifying deformation and destruction stages by location of critical points of a reconstructed flow of acoustic-emission events, Russ. J. Nondestr. Test., 2008, vol. 44, no. 8, pp. 517–526.
Builo, S.I., Use of invariant combinations of parameters characterizing acoustic emission in diagnostics of prefracture states of solids, Russ. J. Nondestr. Test., 2002, vol. 38, no. 2, pp. 116–120.
Sadakov, G.A., Neravnovesnaya elektrokhimiya v gal’vanotekhnike (Nonequilibrium Electrochemistry in Electroplating), Moscow: Mashinostroenie, 2015.
Vetter, K.J., Electrochemical Kinetics, New York: Academic Press, 1967.
Builo, S.I., Relation between the amplitude of acoustic emission of an ensemble of microflaws and the deformation rate: Reconstruction of the number of AE events during a change in the dynamic range of detected signals, Russ. J. Nondestr. Test., 2007, vol. 43, no. 3, pp. 188–195.
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This work was supported by the RF Ministry of Education and Science, project no. 9.4726.2017/8.9.
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Translated by V. Potapchouck
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Builo, S.I., Kuznetsov, D.M. & Gaponov, V.L. Acoustic-Emission Monitoring of Nonequilibrium Stage of Electrolysis. Russ J Nondestruct Test 55, 803–807 (2019). https://doi.org/10.1134/S1061830919110032
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DOI: https://doi.org/10.1134/S1061830919110032