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Influence of the Sulfur Concentration in a Fe–S Melt on Diamond Preservation under P–T Conditions of the Earth’s Mantle

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Abstract

The results of experiments on dissolution of diamond in a Fe melt with variable concentrations of S at high P–T parameters are presented. It is established that the maximal degree of diamond dissolution occurs at a sulfur concentration of 15 wt %. With decreasing or increasing S content, dissolution of diamond slows down and almost does not occur during the period of the experiment (60 min), when the “eutectic” composition is gained. In contrast to a pure Fe melt, the presence of S decreases the carbon solubility and, therefore, reduces the aggressiveness of metal melt in relation to diamonds, thus, stimulating their preservation in the Earth’s mantle, especially if the concentration of S exceeds that in the “eutectic” composition.

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Correspondence to V. M. Sonin.

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Original Russian Text © V.M. Sonin, E.I. Zhimulev, A.A. Chepurov, A.I. Chepurov, N.P. Pokhilenko, 2018, published in Doklady Akademii Nauk, 2018, Vol. 481, No. 2.

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Sonin, V.M., Zhimulev, E.I., Chepurov, A.A. et al. Influence of the Sulfur Concentration in a Fe–S Melt on Diamond Preservation under P–T Conditions of the Earth’s Mantle. Dokl. Earth Sc. 481, 922–924 (2018). https://doi.org/10.1134/S1028334X1807019X

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  • DOI: https://doi.org/10.1134/S1028334X1807019X

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