Skip to main content
SpringerLink
Log in

Diagnostics of the Phase Composition of Lead-Zirconate-Titanate Films according to Raman Spectra: Phase Identification

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

The problem concerning the diagnostics of the phase composition of lead-zirconate-titanate (PZT) films under conditions of overlapping Raman spectra is solved via applied mathematical statistics. The proposed phase-identification method based on reference spectra is implemented using different Raman-spectrum regions measured on the surface of multiphase PZT films. It is demonstrated that the identification of phases, as well as determination of their concentration, must be performed using the spectral range in which the calculated first principal components of the set of Raman spectra differ to the greatest extent from each other.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. G. Beshenkov, A. F. Vyatkin, A. G. Znamenskii, and V. A. Marchenko, J. Surf. Invest.: X-ray, Synchrotron Neutron Tech. 2 (1), 25 (2008).

    Google Scholar 

  2. G. Burns and B. A. Scott, Phys. Rev. Lett. 25, 1191 (1970). doi 10.1103/PhysRevLett.25.1191

    Article  Google Scholar 

  3. G. Burns and B. A. Scott, Phys. Rev. B 7, 3088 (1973). doi 10.1103/PhysRevB.7.3088

    Article  Google Scholar 

  4. I. Taguchi, A. Pignolet, L. Wang, et al., J. Appl. Phys. 74, 6625 (1993). doi 10.1063/1.355103

    Article  Google Scholar 

  5. F. A. G. Souza, K. C. V. Lima, A. P. Ayala, et al., Phys. Rev. B 66, 132107 (2002). doi 10.1103/Phys-RevB.66.132107

    Article  Google Scholar 

  6. J. Lappalainen, J. Frantti, J. Hiltunen, et al., Ferroelectrics 335, 149 (2006). doi 10.1080/00150190600689720

    Article  Google Scholar 

  7. R. Merlin, J. A. Sanjurjo, and A. Pinczuk, Solid State Commun. 16, 931 (1975). doi 10.1016/0038-1098(75)90897-2

    Article  Google Scholar 

  8. V. N. Detsik, E. Yu. Kaptelov, S. A. Kukushkin, et al., Fiz. Tverd. Tela 39 (1), 121 (1997).

    Google Scholar 

  9. I. P. Pronin, E. Yu. Kaptelov, S. V. Senkevich, et al., Phys. Solid State 52 (1), 132 (2010).

    Article  Google Scholar 

  10. E. R. Malinowski and D. G. Howery, Factor Analysis in Chemistry (John Wiley and Sons, New York, 1980).

    Google Scholar 

  11. V. G. Beshenkov, A. G. Znamenskii, A. V. Irzhak and V. A. Marchenko, J. Surf. Invest.: X-ray, Synchrotron Neutron Tech. 12 (1), 159 (2018). doi 10.1134/S1027451018010238

    Article  Google Scholar 

  12. V. G. Beshenkov, A. A. Burlakov, A. G. Znamenskii, and V. A. Marchenko, Tech. Phys. Lett. 40 (8), 644 (2014).

    Article  Google Scholar 

  13. S. A. Aivazyan, V. M. Bukhshtaber, I. S. Enyukov, and L. D. Meshalkin, Applied Statistics: Classification and Dimensionality Reduce (Finansy i Statistika, Moscow, 1989) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. G. Beshenkov, A. G. Znamenskii, A. V. Irzhak & V. A. Marchenko

Authors
  1. V. G. Beshenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. G. Znamenskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Irzhak
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. A. Marchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. G. Beshenkov.

Additional information

Original Russian Text © V.G. Beshenkov, A.G. Znamenskii, A.V. Irzhak, V.A. Marchenko, 2018, published in Poverkhnost’, 2018, No. 9, pp. 31–35.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Beshenkov, V.G., Znamenskii, A.G., Irzhak, A.V. et al. Diagnostics of the Phase Composition of Lead-Zirconate-Titanate Films according to Raman Spectra: Phase Identification. J. Surf. Investig. 12, 861–865 (2018). https://doi.org/10.1134/S102745101805004X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S102745101805004X

Keywords

Search

Navigation