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The Use of Galvanic Displacement for Synthesizing Pt/Carbide (Mo2C, ZrC, NbC) Catalysts Highly Active in the Hydrogen Evolution Reaction

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Abstract

The composite materials involving platinum nanoparticles on the surface of carbides of Mo, Zr, and Nb are synthesized by the currentless redox reaction between potassium tetrachloroplatinate(II) and the corresponding carbide (supporting electrolyte—0.5 М H2SO4). The greatest amount of platinum is deposited in the reduction of tetrachloroplatinate(II) by molybdenum carbide Mo2C, and the smallest amount is deposited in the reduction by ZrC. The synthesized materials are characterized by the methods of scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and cyclic voltammetry. The specific surface area of platinum deposited from solutions containing 0.05 M platinum salt during the deposition time of 20 min is found to be 28 m2/g for Pt/Mo2C, 26 m2/g for Pt/ZrC, and 10 m2/g for Pt/NbC. These materials exhibit the high catalytic activity in the reaction of electrochemical hydrogen evolution in acidic solutions.

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Notes

  1. The electrode potentials of half-reactions (4) and (5) were calculated based on the standard Gibbs energies of formation of substances shown in [39].

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology, Moscow, Russia

    V. V. Kuznetsov & K. V. Frolov

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

    V. V. Kuznetsov & M. A. Volkov

  3. Moscow State University, Moscow, Russia

    B. I. Podlovchenko

  4. National Research Nuclear University (MEPhI), Moscow, Russia

    V. V. Kuznetsov & D. A. Khanin

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  1. V. V. Kuznetsov
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  2. B. I. Podlovchenko
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  4. M. A. Volkov
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Correspondence to V. V. Kuznetsov.

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Translated by T. Safonova

A tribute to outstanding electrochemist Oleg Aleksandrovich Petrii (1937–2021).

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Kuznetsov, V.V., Podlovchenko, B.I., Frolov, K.V. et al. The Use of Galvanic Displacement for Synthesizing Pt/Carbide (Mo2C, ZrC, NbC) Catalysts Highly Active in the Hydrogen Evolution Reaction. Russ J Electrochem 58, 896–906 (2022). https://doi.org/10.1134/S1023193522100093

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