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Codeposition of Zinc with Manganese from Different Gluconate Baths

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Abstract

Codeposition of zinc and manganese from slightly acidic gluconate solutions with various anions (chloride and/or sulfate) showed that independently on the bath speciation manganese ions were a key factor inhibiting electroreduction of zinc ions. It resulted in two potential ranges of the electrodeposition behavior. Morphology and composition of the electrodeposits was not affected by the type of anions in the electrolyte, but was seriously dependent on a deposition potential. Nucleation mode, surface wettability and corrosion properties of the deposits were also discussed.

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Funding

This work was financially supported by the National Science Centre of Poland under a project no. 2018/31/N/ST8/00908.

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  1. AGH University of Science and Technology, Faculty of Non-Ferrous Metals, 30-059, Cracow, Poland

    Karolina Chat-Wilk, Ewa Rudnik, Grzegorz Włoch & Piotr Osuch

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  1. Karolina Chat-Wilk
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  2. Ewa Rudnik
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  3. Grzegorz Włoch
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  4. Piotr Osuch
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Contributions

K. Chat-Wilk performed experimental work and participated in the results analysis E. Rudnik proposed an idea of the work, analysed the results, calculated the equilibrium diagrams and prepared the manuscript; G. Włoch carried out SEM and EDS analyses; while P. Osuch performed the WCA measurements.

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Correspondence to Karolina Chat-Wilk or Ewa Rudnik.

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Karolina Chat-Wilk, Rudnik, E., Włoch, G. et al. Codeposition of Zinc with Manganese from Different Gluconate Baths. Russ J Electrochem 58, 168–183 (2022). https://doi.org/10.1134/S1023193522030053

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