Abstract
In energy-storage systems such as fuel cells and metal-air batteries, the main current-forming process is the reaction of oxygen electroreduction (OER). A simple method is proposed for synthesizing OER catalysts based on polymer complexes of transition metals (nickel, palladium) with Schiff bases prepared by electrochemical polymerization of starting monomers. The OER catalysts are prepared by thermolysis of polymers in inert atmosphere. Their properties are characterized by the methods of cyclic voltammetry with the use of a rotating disk electrode. The surface state (the catalyst film density, the size and composition of particles) is controlled by scanning electron microscopy with X-ray microanalysis. The electrode demonstrates the high catalytic activity in the oxygen electroreduction reaction in alkaline solutions (higher than 750 mA/mg of the initial polymer mass).
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Nie, Y., Li, L., and Wei, Z., Recent advancements in Pt and Pt-free catalysts for oxygen reduction reaction, Chem. Soc. Rev, 2015, vol. 44, p. 2168.
Bagotzky, V.S., Tarasevich, M.R., Radyuskina, K.A., Levina, O.A., and Andrusyova, S.I., Electrocatalysis of the oxygen reduction process on metal chelates in acid electrolyte, J. Power Sources, 1977/78, vol. 2, p. 233.
Gupta, S., Tryk, D., Bae, I., Aldred, W., and Yeager, E., Heat-treated polyacrylonitrile-based catalysts for oxygen electroreduction, J. Appl. Electrochem., 1989, vol. 19, p. 19.
Tarasevich, M.R., Beketaeva, L.A., Efremov, B.N., Zagudaeva, N.M., Kuznetsova, L.N., Rybalka, K.V., and Sosenkin, V.E., Electrochemical properties of carbon black AD-100 and AD-100 promoted with pyropolymer of cobalt tetra (p-methoxyphenyl) porphyrin, Russ. J. Electrochem., 2004, vol. 40, p. 542.
Nallathambi, V., Lee, J.-W., Kumaraguru, S.P., Wu, G., and Popov, B.N., Development of high performance carbon composite catalyst for oxygen reduction reaction in PEM Proton Exchange Membrane fuel cells, J. Power Sources, 2008, vol. 183, p. 34.
Lefèvre, M., Proietti, E., Jaouen, F., and Dodelet, J.-P., Iron-based catalysts with improved oxygen reduction activity in polymer electrolyte fuel cells, Science, 2009, vol. 324, p. 71.
Kramm, U.I., Lefèvre, M., Larouche, N., Schmeisser, D., and Dodelet, J.-P, Correlations between mass activity and physicochemical properties of Fe/N/C catalysts for the ORR in PEM fuel cell via 57Fe Mössbauer spectroscopy and other techniques, J. Am. Chem. Soc., 2014, vol. 136, no. 3, p. 978.
Du, J., Cheng, F.Y., Wang, S.W., Zhang, T.R., and Chen, J., M (Salen)-derived nitrogen-doped M/C (M = Fe, Co, Ni) porous nanocomposites for electrocatalytic oxygen reduction, Sci. Rep., 2014, vol. 4, p. 4386.
Rojas-Carbonell, S., Santaro, C., Serov, A., and Atanassov, P., Transition metal-nitrogen-carbon catalysts for oxygen reduction reaction in neutral electrolyte, Electrochem. Commun., 2017, vol. 75, p. 38.
Wu, G., Current challenge and perspective of PGMfree cathode catalysts for PEM fuel cells, Front. Energy, 2017, vol. 11, no. 3, p. 286.
Thippani, T., Mandal, S., Wang, G., Ramani, V.K., and Kothandaraman, R., Probing oxygen reduction and oxygen evolution reactions on bifunctional nonprecious metal catalysts for metal–air batteries, RSC Adv., 2016, vol. 6, no. 75, p. 71122.
Huang, Y., Cui, F., Zhao, Y., Bao, J., Lian, J., Xu, Y., Liu, T., and Li, H., Controllable synthesis of ultra-thin NiCo2O4 nanosheet incorporated composite nanotubes towards efficient oxygen reduction, Chem.–Asian J., 2017.
Wu, R., Wang, J., Chen, K., Chen, S., Li, J., Wang, Q., Nie, Y., Song, Y., Chen, H., and Wei, Z., Space-confined pyrolysis for the fabrication of Fe/N/C nanoparticles as a high performance oxygen reduction reaction electrocatalyst, Electrochim. Acta, 2017, vol. 244, p. 47.
Wu, G., More, K.L., Johnston, C.M., and Zelenay P., High-performance electrocatalysts for oxygen reduction derived from polyaniline, iron, and cobalt, Science, 2011, vol. 332, p. 443.
Zhang, P., Sun, F., Xiang, Z., Shen, Z., Yun, J., and Cao, D., ZIF-derived in situ nitrogen-doped porous carbons as efficient metal-free electrocatalysts for oxygen reduction reaction, Energy Environ. Sci., 2014, vol. 7, no. 1, p. 442.
Wu, Z.S., Chen, L., Liu, J., Parvez, K., Liang, H., Shu, J., Sachdev, H., Graf, R., Feng, X., and Mullen, K., High-performance electrocatalysts for oxygen reduction derived from cobalt porphyrin-based conjugated mesoporous polymers, Adv. Mater., 2013, vol. 26, p.1450.
Lee, J.S., Park, G.S., Kim, S.T., Liu, M., and Cho, J., A highly efficient electrocatalyst for the oxygen reduction reaction: N-doped ketjenblack incorporated into Fe/Fe3C-functionalized melamine foam, Angew. Chem., 2013, vol.125, no. 3, p. 1060.
Wu, G., Johnston, C.M., Mack, N.H., Artyushkova, K., Ferrandon, M., Nelson, M., Lezama-Pacheco, J.S., Conradson, S.D., More, K.L., Myers, D.J., and Zelenay, P., Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells, J. Mater. Chem., 2011, vol. 21, no. 30, p. 11392.
Ai, K., Liu, Y., Ruan, C., Lu, L., and Lu, G., Sp2 C-dominant N-doped carbon sub-micrometer spheres with a tunable size: A versatile platform for highly efficient oxygen-reduction catalysts, Adv. Mater., 2013, vol. 25, no. 7, p. 998.
Novozhilova, M.V., Smirnova, E.A., Karushev, M.P., Timonov, A.M., Malev, V.V., and Levin, O.V., Synthesis and study of catalysts of electrochemical oxygen reduction reaction based on polymer complexes of nickel and cobalt with Schiff bases, Russ. J. Electrochem., 2016, vol. 52, no. 12, p. 1183.
Popeko, I.E., Vasil’ev, V.V., Timonov, A.M., and Shagisultanova, G.A., Electrochemical behavior of palladium(II) complexes with Schiff-bases and synthesis of Pd(II)–Pd(IV) mixed-ligand complex, Zh. Neorg. Khim., 1990, vol. 35, no. 4, p. 933.
Erikson, H., Sarapuu, A., Solla-Gullón, J., and Tammeveski, K., Recent progress in oxygen reduction electrocatalysis on Pd-based catalysts, J. Electroanal. Chem., 2016, vol. 780, p. 327.
Vecchio, C., Alegre, C., Sebastián, D., Stassi, A., Aricò, S., and Baglio, V., Investigation of supported Pd-based electrocatalysts for the oxygen reduction reaction: performance, durability and methanol tolerance, Materials, 2015, no. 8, p. 7997.
Venarusso, L., Bettini, J., and Maia, G., Superior catalysts for oxygen reduction reaction based on porous nanostars of a Pt, Pd, or Pt–Pd alloy shell supported on a gold core, ChemElectroChem., 2016, vol. 3, no. 5, p. 749.
Krasikova, S.A., Besedina, M.A., Karushev, M.P., Dmitrieva, E.A., and Timonov, A.M., In situ electrochemical microbalance studies of polymerization and redox processes in polymeric complexes of transition metals with Schiff bases, Russ. J. Electrochem., 2010, vol. 46, no. 2, p. 218.
Koutecky, J. and Levich, V.G., The application of the rotating disc electrode to studies of kinetic and catalytic processes, Zh. Fiz. Khim., 1958, vol. 32, no. 7, p. 1565.
Cai, P., Ci, S., Zhang, E., Shao, P., Cao, C., and Wen, Z., FeCo alloy nanoparticles confined in carbon layers as high-activity and robust cathode catalyst for Zn–Air battery, Electrochim. Acta, 2016, vol. 220, p. 354.
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Original Russian Text © M.V. Novozhilova, Yu.S. Danilova, M.P. Karushev, A.M. Timonov, V.V. Malev, O.V. Levin, 2018, published in Elektrokhimiya, 2018, Vol. 54, No. 10, pp. 879–884.
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Novozhilova, M.V., Danilova, Y.S., Karushev, M.P. et al. Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases. Russ J Electrochem 54, 769–774 (2018). https://doi.org/10.1134/S102319351810004X
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DOI: https://doi.org/10.1134/S102319351810004X