Abstract
A novel V2AlC electrode material for supercapacitors was investigated in this study. The structure and surface morphology were examined using X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM). The formation of irregularly shaped V2AlC with different particle size distribution was confirmed by XRD and FESEM. The electrochemical measurements were performed by cyclic voltammetry (CV), galvanostatic charge discharge and electrochemical impedance spectroscopy (EIS). V2AlC electrode exhibited 27.6 F g–1 of specific capacitance at the current density of 0.5 A g–1. The specific capacitance of V2AlC electrode remained 93.8% of the first cycle after 2000 cycles. V2AlC has great potential for application in supercapacitors.
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Wang, G.P., Zhang, L., and Zhang, J.J. A review of electrode materials for electrochemical supercapacitors, Chem. Soc. Rev., 2012, vol. 41, p.797.
Ji, C.C., Bao, S.J., and Lu, Z.J., 3D interpenetrating macroporous graphene aerogels with MnO2 coating for supercapacitors, Russ. J. Electrochem., 2015, vol. 51, p.782.
Wang, S.Y., Zhao, J.C., and Wang, L.L., High performance Na3V2(PO4)3/C composite electrode for sodium-ion capacitors, Ionics, 2015, vol. 21, p. 2633.
Chang, S.K., Zainal, Z., and Tan, K.B. Synthesis and electrochemical properties of nanostructured nickel–cobalt oxides as supercapacitor electrodes in aqueous media, Int. J. Energ. Res., 2015, vol. 39, p. 1366.
Casado, N., Hernández, G., and Sardon, H., Current trends in redox polymers for energy and medicine, Prog. Polym. Sci., 2016, vol. 52, p.107.
Ferris, A., Garbarino, S., and Guay, D., 3D RuO2 Microsupercapacitors with remarkable areal energy, Adv. Mater., 2015, vol. 27, p. 6625.
Cao, F., Pan, G.X., and Xiam, X.H., Synthesis of hierarchical porous NiO nanotube arrays for supercapacitor application, J. Power Sources, 2014, vol. 264, p.161.
Pan, X.X., Chen, X.M., and Li, Y., Facile synthesis of Co3O4 nanosheets electrode with ultrahigh specific capacitance for electrochemical supercapacitors, Electrochim. Acta, 2015, vol. 182, p. 1101.
Poonguzhali, R., Shanmugam, N., and Gobi, R., Effect of Fe doping on the electrochemical capacitor behavior of MnO2 nanocrystals, J. Power Sources, 2015, vol. 293, p.790.
Naguib, M., Halim, J., and Lum, J., New two-dimensional niobium and vanadium carbides as promising materials for Li-ion batteries, J. Am. Chem. Soc., 2013, vol. 135, p. 15966.
Agnese, Y.D., Taberna, P.-L., and Gogotsi, Y., Twodimensional vanadium carbide (MXene) as positive electrode for sodium-ion capacitors, J. Phys. Chem. Lett., 2015, vol. 6, p. 2305.
Ji, X., Xu, K., and Chen, C., Different charge-storage mechanisms in disulfide vanadium and vanadium carbide monolayer, J. Mater. Chem. A, 2015, vol. 3, p. 9909.
Lukatskaya, M.R., Halim, J., and Dyatkin, B., Roomtemperature carbide-derived carbon synthesis by electrochemical etching of MAX phases, Angew. Chem. Int. Ed., 2014, vol. 53, p. 4877.
Zhao, M.Q., Sedran, M., and Ling, Z., Synthesis of carbon/ sulfur nanolaminates by electrochemical extraction of titanium from Ti2SC, Angew. Chem. Int. Ed., 2015, vol. 54, p. 4810.
Liu, J., Zhang, Y., and Li, Y., In situ chemical synthesis of sandwich-structured MnO2/graphene nanoflowers and their supercapacitive behavior, Electrochim. Acta, 2015, vol. 173, p.148.
Su, X.H, Yu, L., and Cheng, G., High-performance α-MnO2 nanowire electrode for supercapacitors, Appl. Energ., 2015, vol. 153, p. 94.
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Published in Russian in Elektrokhimiya, 2018, Vol. 54, No. 1, pp. 107–110.
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Xia, N., Zhao, J.C., Sun, J. et al. A Novel V2AlC Electrode Material for Supercapacitors. Russ J Electrochem 54, 92–95 (2018). https://doi.org/10.1134/S1023193517120114
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DOI: https://doi.org/10.1134/S1023193517120114