Skip to main content
SpringerLink
Log in

Synthesis, microstructure, and electric properties of CaZr0.9Y0.1O3 – δ films obtained on porous SrTi0.8Fe0.2O3 – δ supports

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Compact CaZr0.9Y0.1O3–δ (CZY) film on a porous SrTi0.8Fe0.2O3–δ (STF) support is obtained using the technique of deposition from solutions of inorganic salts in ethanol. According to the data of scanning electron microscopy (SEM), the film has a nanoporous granular structure with the grain size of 0.2 to 1 μm. The thickness of the CZY film on the STF support is about 3 μm after 15-fold solution application. The results of studying the elemental composition showed that elements of the support diffuse into the film in the course of synthesis. Analysis of the data of impedance spectroscopy shows that conductivity of the CZY film is limited the grain bulk. It is assumed that the comparatively low conductivity activation energy of the film (50.3 kJ/mol) is due to diffusion of elements of the STF support that results in variation of the film composition and properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hwang, S. and Choi, G., Solid State Ionics, 2006, vol. 177, p. 3099.

    Article  CAS  Google Scholar 

  2. Gorelov, V.P., Balakireva, V.B., Kuz’min, A.V., and Plaksin, S.V., Inorg. Mater., 2014, vol. 50, p. 495.

    Article  CAS  Google Scholar 

  3. Bao, J., Ohno, H., Kurita, N., Okuyama, Y., and Fukatsu, N., Electrochim. Acta, 2011, vol. 56, p. 1062.

    Article  CAS  Google Scholar 

  4. Xia, C., Zha, S., Yang, W., Peng, R., Peng, D., and Meng, G., Solid State Ionics, 2000, vol. 133, p. 287.

    Article  CAS  Google Scholar 

  5. Hidalgo, H., Reguzina, E., Millon, E., Thomann, A.-L., Mathias, J., Boulmer-Leborgne, C., Sauvage, T., and Brault, P., Surf. Coat. Technol., 2011, vol. 205, p. 4495.

    Article  CAS  Google Scholar 

  6. Beckers, L., Sanchez, F., Schubert, J., Zander, W., and Buchal, C., J. Appl. Phys., 1996, vol. 79, p. 3337.

    Article  CAS  Google Scholar 

  7. Galicka-Fau, K., Legros, C., Andrieux, M., Herbst-Ghysel, M., Gallet, I., Condat, M., Durand, O., and Servet, B., Solid Films, 2008, vol. 516, p. 7967.

    Article  CAS  Google Scholar 

  8. Dunyushkina, L.A., Plaksin, S.V., Pankratov, A.A., Kuzmina, L.A., Kuimov, V.M., and Gorelov, V.P., Russ. J. Electrochem., 2011, vol. 47, p. 1274.

    Article  CAS  Google Scholar 

  9. Dunyushkina, L.A., Smirnova, E.O., Smirnov, S.V., Kuimov, V.M., and Plaksin, S.V., Ionics, 2013, vol. 19, p. 511.

    Article  CAS  Google Scholar 

  10. Dunyshkina, L.A., Smirnov, S.V., Plaksin, S.V., Kuimov, V.M., and Gorelov, V.P., Ionics, 2013, vol. 19, p. 1715.

    Article  Google Scholar 

  11. Dunyushkina, L.A., Smirnov, S.V., Kuimov, V.M., and Gorelov, V.P., Int. J. Hydrogen Energy, 2014, vol. 39, p. 18385.

    Article  CAS  Google Scholar 

  12. Uchiyama, K., Isse, Y., Hori, Y., Nishida, T., Uraoka, Y., Kariya, T., and Yanagimoto, K., Proceedings of 6th Thin Film Materials & Devices Meeting, November, 2009, p. 100228102-1.

    Google Scholar 

  13. Kharton, V., Kovalevsky, A., and Tsipis, E., J. Solid State Electrochem., 2002, vol. 7, p. 30.

    Article  CAS  Google Scholar 

  14. Guo, X. and Waser, R., Prog. Mater. Sci., 2006, vol. 51, p. 151.

    Article  CAS  Google Scholar 

  15. Jurado, J., Colomer, M., and Frade, J., Solid State Ionics, 2001, vol. 143, p. 251.

    Article  CAS  Google Scholar 

  16. Boukamp, B., Solid State Ionics, 1986, vol. 20, p. 31.

    Article  CAS  Google Scholar 

  17. Dudek, M. and Bućko, M.M., J. Solid State Electrochem., 2010, vol. 14, p. 565.

    Article  CAS  Google Scholar 

  18. Bao, J., Okuyama, Y., Shi, Z., Fukatsu, N., and Kurita, N., Mater. Trans., 2012, vol. 53, p. 973.

    Article  CAS  Google Scholar 

  19. Iwahara, H., Yajima, T., Hibino, T., Ozaki, K., and Suzuki, H., Solid State Ionics, 1993, vol. 61, p. 65.

    Article  CAS  Google Scholar 

  20. Savaniu, C.D., Canales-Vazquez, J., and Irvine, J.T.S., J. Mater. Chem., 2005, vol. 15, p. 598.

    Article  CAS  Google Scholar 

  21. Kreuer, K.D., Adams, S., Munch, W., Fuchs, A., Klock, U., and Maier, J., Solid State Ionics, 2001, vol. 145, p. 295.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    L. A. Dunyushkina, V. M. Kuimov, A. A. Pankratov, O. G. Reznitskikh & A. Sh. Khaliullina

Authors
  1. L. A. Dunyushkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. M. Kuimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Pankratov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. G. Reznitskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. Sh. Khaliullina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. M. Kuimov.

Additional information

Original Russian Text © L.A. Dunyushkina, V.M. Kuimov, A.A. Pankratov, O.G. Reznitskikh, A.Sh. Khaliullina, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 11, pp. 1186–1192.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dunyushkina, L.A., Kuimov, V.M., Pankratov, A.A. et al. Synthesis, microstructure, and electric properties of CaZr0.9Y0.1O3 – δ films obtained on porous SrTi0.8Fe0.2O3 – δ supports. Russ J Electrochem 52, 1057–1063 (2016). https://doi.org/10.1134/S1023193516110033

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193516110033

Keywords

Search

Navigation