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Electrochemical doping of polyaniline with the tetracyanoquinodimethane anion

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Abstract

A new complex of aniline (An) with tetracyanoquinodimethane (TCQM) An(TCQM)4 has been obtained and studied. The redox cycling of polyaniline (PAni-sulfo) in a neutral electrolyte containing Cl– and ClO −4 anions led to a replacement of the sulfate anion by the Cl– and ClO −4 anions. The TCQM anion can also replace the sulfate anions in polyaniline (PAni) during the cycling of the latter in a neutral electrolyte containing TCQM anions. The introduction of TCQM in PAni creates conditions for generating nanocrystalline regions inside the polymer.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Abalyaeva & N. N. Dremova

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  1. V. V. Abalyaeva
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  2. N. N. Dremova
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Correspondence to V. V. Abalyaeva.

Additional information

Original Russian Text © V.V. Abalyaeva, N.N. Dremova, 2016, published in Elektrokhimiya, 2016, Vol. 52, No. 8, pp. 834–842.

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Abalyaeva, V.V., Dremova, N.N. Electrochemical doping of polyaniline with the tetracyanoquinodimethane anion. Russ J Electrochem 52, 746–753 (2016). https://doi.org/10.1134/S1023193516080024

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