Abstract
Computer analysis of the mathematical model of discharge of sintered-type nickel oxide electrodes of compacted and ceramic metal types and also of the most promising at present electrodes on porous polymer metalized supports is presented. The model allows estimating the dependence of polarization of the electrode on the concentration of electrolyte, discharge current density, electrode thickness and porosity, effect of proton diffusion and solid phase conductivity on the performance of an individual grain of the active substance. The calculations take into account occurrence of the electrochemical process via the solid-phase mechanism and diffusion and migration of components of electrolyte. Analysis of data according to the suggested model shows its applicability for studying the capacity of nickel oxide electrodes of sintered-type design under different conditions of operation of alkaline power sources.
Similar content being viewed by others
References
Korovin, N.V. and Skundin, A.M., Khimicheskie istochniki toka. Spravochnik (Chemical Power Sources: Reference Book), Moscow: Izd-vo MEI, 2003.
Volynskii, V.V., Stepanov, A.B., Radkevich, Yu.B., and Popova, S.S., Tezisy dokladov Mezhdunarodnoi nauchno–tekhnicheskoi konferentsii “100 let Rossiiskomu avtomobilyu” (Abstracts of International Scientific and Technical Conference “Centenary of Russian Automobile”), Moscow: Promyshlennost’ i vysshaya shkola, 1996, p. 114.
Grishin, S.,V., Yakubovskaya, E.V., Volynskii, V.V., and Kazarinov, I.A., Elektrokhim. Energ., 2010, vol. 10, p. 96.
Kuchinskii, E.M. and Ershler, B.V., Zh. Fiz. Khim., 1946, vol. 20, p. 539.
Lukovtsev, P.D. and Temerin, S.A., Trudy soveshchaniya po elektrokhimii (Transactions of Conference in Electrochemistry), Moscow: 1953, p. 494.
Ufland, N.Yu. and Rozentsveig, S.A., Sbornik rabot po khimicheskim istochnikam toka (Collection of Works on Chemical Power Sources), Leningrad: Energiya, 1968, no. 3, p. 180.
Winsel, A., Z. Elektrochem., 1962, vol 66, p. 287.
Matekin, S.S., Extended Abstract of Cand. Sci. (Tech.) Dissertation, Novocherkassk, 2007.
Smetankin, G.P., Karavaeva, V.M., Matekin, S.S., Burdyugov, A.S., and Plokhova, T.V., Izv. Vyssh. Uchebn. Zaved., Sev.-Kavk. Reg., Tekh. Nauki, 2006, no. 10, p. 6.
Galushkina, I.A., Extended Abstract of Cand. Sci. (Tech.) Dissertation, Novocherkassk, 2011.
Galushkin, D.N., Galushkina, N.N., and Galushkina, I.A., Materialy XVI Vserossiiskoi nauchno–tekhnicheskoi konferentsii “Informatsionnye tekhnologii v nauke, proektirovanii i proizvodstve” (Materials of XVI All-Russia Scientific and Technical Conference “Information Technologies in Science, Engineering, and Production), Nizhny Novgorod: Izd-vo Nizhegor. nauch. i inform. metod. tsentra "Dialog”, December 2005, p. 27.
Sagoyan, L.N., D. Sci. (Chem.) Dissertation, Dnepropetrovsk, 1974.
Barsukov, V.Z., Extended Abstract of D. Sci. (Chem.) Dissertation, Dnepropetrovsk, 1985.
Deyuan, F. and Ralgh, E., J. Electrochem. Soc., 1991, vol. 138, p. 17.
Deyuan, F. and Ralgh, E., J. Electrochem. Soc., 1991, vol. 138, p. 2952.
Kozina, O.L., Extended Abstract of Cand. Sci. (Tech.) Dissertation, Nizhny Novgorod, 1998.
Gun’ko, Yu.L., Kozina, O.L., and Mikhalenko, M.G., Tezisy dokladov Vserossiskoi nauchno–metodicheskoi konferentsii (Abstracts of All-Russia Scientific Methodological Conference), Nizhny Novgorod, 1996, p. 71.
Wu, B. and White, R.E., J. Electrochem. Soc., 2001, vol. 148, p. 595.
Motupally, S., Streinz, C.C., and Weidner, J.W., J. Electrochem. Soc., 1995, vol. 142, p. 1401.
Motupally, S., Streinz, C.C., and Weidner, J.W., J. Electrochem. Soc., 1998, vol. 145, p. 29.
Gomadam, P.M., Weidner, J.W., Dougal, R.A., and White, R.E., J. Power Sources, 2002, vol. 110, p. 267.
Srinivasan, V., Weidner, J.W., and White, R.E., J. Solid State Electrochem., 2000, vol. 4, p. 367.
RatnaKumar, B.V., Timmerman, P., Sanchez, C., Stefano, S.D., and Halpert, G., J. Electrochem. Soc., 1996, vol. 143, p. 803.
De Vidts, P., J. Electrochem. Soc., 1995, vol. 142, p. 1509.
De Vidts, P., Delgado, J., and White, R.E., J. Electrochem. Soc., 1996, vol. 143, p. 3223.
De Vidts, P., Delgado, J., Wu, B., See, D., Kosanovich, K., and White, R.E., J. Electrochem. Soc., 1998, vol. 145, p. 3874.
Mao, Z., De Vidts, P., White, R.E., and Newman, J., J. Electrochem. Soc., 1994, vol. 141, p. 54.
Paxton, B. and Newman, J., J. Electrochem. Soc., 1997, vol. 144, p. 3818.
Briggs, G.W.D. and Snodin, Pr.., Electrochim. Acta, 1982, vol. 27, p. 553.
Sukhotin, A.M., Spravochnik po elektrokhimii (Reference Book in Electrochemistry), Leningrad: Khimiya, 1981.
Dibrov, I.A. and Grigor’eva, T.V., Elektrokhimiya, 1979, vol. 15, p. 281.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © Yu.L. Gun’ko, O.L. Kozina, M.G. Mikhalenko, A.B. Loskutov, A.A. Myunts, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 10, pp. 1060–1070.
Rights and permissions
About this article
Cite this article
Gun’ko, Y.L., Kozina, O.L., Mikhalenko, M.G. et al. Mathematical simulation of discharge of sintered-type nickel oxide electrode of nickel–cadmium battery. Russ J Electrochem 51, 935–944 (2015). https://doi.org/10.1134/S1023193515100055
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193515100055