Abstract
The pore filling process in the metal electrodeposition in the anodic aluminum oxide pores under the potentiostatic conditions is studied theoretically. The model takes into consideration the transfer of metal cations inside the pores and in the outer diffusion layer. The thickness of outer diffusion layer is determined by the hydrodynamic conditions. The kinetics of metal electrodeposition is described by the equation of mixed kinetics at large deviations from the equilibrium. In the quasi-steady-state approximation, the problem for the pores of different initial lengths, which are characterized by the normal distribution law, is solved analytically. The results are compared with the data obtained by the numerical method.
Similar content being viewed by others
References
Searson, P.C., Cammarata, R.C., and Chien, C.L., J. Electron. Mater., 1995, vol. 24, p. 955.
Nagaura, T., Takeuchi, F., Yamauchi, Y., Wada, K., and Inoue, S., Electrochem. Commun., 2008, vol. 10, p. 681.
Proenca, M.P., Sousa, C.T., Ventura, J., Vazquez, M., and Araujo, J.P., Electrochim. Acta, 2012, vol. 72, p. 215.
Xu, C.-L., Li, H., Zhao, G.-Y., and Li, H.-L., Appl. Surf. Sci., 2006, vol. 253, p. 1399.
Li, L., Zhang, Y., Li, G., Wang, X., and Zhang, L., Mater. Lett., 2005, vol. 59, p. 1223.
Xu, J., Huang, X., Xie, G., Fang, Y., and Liu, D., Mater. Lett., 2005, vol. 59, p. 981.
Yang, Y.-W., Chen, Y.-B., Liu, F., Chen, X.-Y., and Wu, Y.-C., Electrochim. Acta, 2001, vol. 56, p. 6420.
Liu, H., Lu, B., Wei, S., Bao, M., Wen, Y., and Wang, F., Solid State Sci., 2012, vol. 14, p. 789.
Napolskii, K.S., Roslyakov, I.V., Eliseev, A.A., Petukhov, D.I., Lukashin, A.V., Chen, S.-F., Liu, C.-P., and Tsirlina, G.A., Electrochim. Acta, 2011, vol. 56, p. 2378.
Borissov, D., Isik-Uppenkamp, S., and Rohwerder, M., J. Phys. Chem. C, 2009, vol. 113, p. 3133.
Choi, J., Sauer, G., Nielsch, K., Wehrspohn, R.B., and Gosele, U., Chem. Mater., 2003, vol. 15, p. 776.
Riveros, G., Gomez, H., Cortes, A., Marotti, R.E., and Dalchiele, E.A., Appl. Phys. A, 2005, vol. 81, p. 17.
Meng, G., Cao, A., Cheng, J.-Y., Vijayaraghavan, A., Jung, Y.J., Shima, M., and Ajayan, P.M., J. Appl. Phys., 2005, vol. 97, p. 064303.
Valizadeh, S., George, J.M., Leisner, P., and Hultman, L., Electrochim. Acta, 2001, vol. 47, p. 865.
Bograchev, D.A., Volgin, V.M., and Davydov, A.D., Electrochim. Acta, 2013, vol. 96, p. 1.
Bograchev, D.A., Volgin, V.M., and Davydov, A.D., Electrochim. Acta, 2013, vol. 112, p. 279.
Napolskii, K.S., Barczuk, P.J., Vassiliev, S.Yu., Veresov, A.G., Tsirlina, G.A., and Kulesza, P.J., Electrochim. Acta, 2007, vol. 52, p. 7910.
Bluhm, E.A., Bauer, E., Chamberlin, R.M., Abney, K.D., Young, J.S., and Jarvinen, C.D., Langmuir, 1999, vol. 15, p. 8668.
Bluhm, E.A., Bauer, E., Fife, J.N., Chamberlin, R.M., Abney, K.D., Young, J.S., and Jarvinen, C.D., Langmuir, 2000, vol. 16, p. 7056.
Fedoryuk, M.V., Asimptotika: Integraly i ryady (Asymptotics: Integrals and Series), Moscow: Nauka, 1987.
Feller, W., An Introduction to Probability: Theory and Its Applications. Wiley India, 2008.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © D.A. Bograchev, V.M. Volgin, A.D. Davydov, 2015, published in Elektrokhimiya, 2015, Vol. 51, No. 9, pp. 907–914.
Rights and permissions
About this article
Cite this article
Bograchev, D.A., Volgin, V.M. & Davydov, A.D. Modeling of metal electrodeposition in the pores of anodic aluminum oxide. Russ J Electrochem 51, 799–806 (2015). https://doi.org/10.1134/S1023193515090049
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193515090049