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Nickel-selective coated disk electrode based on carbon nanotube composite modified with a new Schiff base

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Abstract

A coated disk polyvinyl chloride (PVC) matrix membrane ion-selective electrode for detection of nickel ion was fabricated based on multiwalled carbon nanotube composite modified with bis(2-hydroxyacetophenone)-1,2-propandiimine (BHAPN) as ionophore. The electrode showed a Nernstian slope of 29.7 ± 0.45 mV decade−1 over a wide concentration range of 9.1 × 10−7 to 2.0 × 10−2 mol L−1 of Ni(NO3)2 with detection limit of 3.2 × 10−7 mol L−1. This electrode was applicable in the pH range of 3.0–7.9 and had a short response time of approximately 6.0 s. The electrode exhibited good selectivity for Ni(II) relative to other metal ions. The use of multiwalled carbon nanotube (MWCNTs) in a polymer matrix improves the linear range and sensitivity of the electrode. The practical analytical utility of the electrode was demonstrated by the using it as an indicator electrode for potentiometric titration of Ni(II) ions with EDTA solution.

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Authors and Affiliations

  1. Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454, Iran

    J. Tashkhourian & S. M. Ghaderizadeh

  2. Department of Chemistry, Faculty of Science, Yasouj University, Yasouj, Iran

    M. Montazerozohori

Authors
  1. J. Tashkhourian
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  2. S. M. Ghaderizadeh
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  3. M. Montazerozohori
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Correspondence to J. Tashkhourian.

Additional information

Published in Russian in Elektrokhimiya, 2015, Vol. 51, No. 3, pp. 248–257.

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Tashkhourian, J., Ghaderizadeh, S.M. & Montazerozohori, M. Nickel-selective coated disk electrode based on carbon nanotube composite modified with a new Schiff base. Russ J Electrochem 51, 209–217 (2015). https://doi.org/10.1134/S1023193515030106

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  • DOI: https://doi.org/10.1134/S1023193515030106

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