Abstract
The use of a solution-phase redox mediator presents an opportunity to perform the slow oxygen reduction reaction in the bulk solution rather than on the surface of a precious metal electrocatalyst. Specific details of several potential mediator chemistries (Br2/2Br−, V(V)/V(VI) etc.), the current status of the development, and the potential for future applications of such a technology are discussed.
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Published in Russian in Elektrokhimiya, 2014, Vol. 50, No. 5, pp. 451–461.
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Tolmachev, Y.V., Vorotyntsev, M.A. Fuel cells with chemically regenerative redox cathodes (review). Russ J Electrochem 50, 403–411 (2014). https://doi.org/10.1134/S1023193514020050
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DOI: https://doi.org/10.1134/S1023193514020050