Skip to main content
SpringerLink
Log in

Electrochemical performance of LiNi0.5Mn1.5O4 doped with la and its compatiblity with new electrolyte system

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Cathode materials LiNi0.5Mn1.5O4 and LiNi0.5 − x/2La x Mn1.5 − x/2O4 (x = 0.04, 0.1, 0.14) were successfully prepared by the sol-gel self-combustion reaction (SCR) method. The X-ray diffraction (XRD) patterns indicated that, a few of doping La ions did not change the structure of LiNi0.5Mn1.5O4 material. The scanning electronic microscopy (SEM) showed that the sample heated at 800°C for 12 h and then annealed at 600°C for 10 h exhibited excellent geometry appearance. A novel electrolyte system, 0.7 mol L−1 lithium bis(oxalate)borate (LiBOB)-propylene carbonate (PC)/dimethyl carbonate (DMC) (1: 1, v/v), was used in the cycle performance test of the cell. The results showed that the cell with this novel electrolyte system performed better than the one with traditional electrolyte system, 1.0 mol L−1 LiPF6-ethylene carbonate (EC)/DMC (1: 1, v/v). And the electrochemical properties tests showed that LiNi0.45La0.1Mn1.45O4/Li cell performed better than LiNi0.5Mn1.5O4/Li cell at cycle performance, median voltage, and efficiency.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Wronski, Z.S., Int. Mater. Rev., 2001, vol. 46, p. 1.

    Article  CAS  Google Scholar 

  2. Shi, Z.C. and Yang, Y., Progress Chem., 2005, vol. 17, p. 604.

    CAS  Google Scholar 

  3. Armstrong, A.R. and Bruce, P.G., Electrochem. Solid State Lett., 2004, vol. 7, p. 1.

    Article  Google Scholar 

  4. Li, S., Cheng, J.F., and Ji, S.J., Rare. Metal. Mat. Eng., 2003, vol. 32, p. 468.

    CAS  Google Scholar 

  5. Lee, Y.S. and Yoshio, M., Electrochem. Solid State Lett., 2001, vol. 4, p. 166.

    Article  Google Scholar 

  6. Van, D.V.A., Marianetti, C., and Morgan, C., Solid State Ion., 2000, vol. 135, p. 21.

    Article  Google Scholar 

  7. Idemoto, Y., Narai, H., and Koura, N., J. Power Sources, 2003, vol. 119–121, p. 125.

    Article  Google Scholar 

  8. Kim, J.H., Myung, S.T., and Sun, Y.K., Electrochim. Acta, 2004, vol. 49, p. 219.

    Article  CAS  Google Scholar 

  9. Wu, X. and Kim, S.B., J. Power Sources, 2002, vol. 109, p. 53.

    Article  CAS  Google Scholar 

  10. Ooms, F.G.B., Kelder, E.M., and Schoonman, J., Solid State Ion., 2002, vols. 152–153, p. 143.

    Article  Google Scholar 

  11. Rojas, R.M., Amarilla, J.M., Pascual, L., and Rojo, J.M., J. Power Sources, 2006, vol. 160, p. 529.

    Article  CAS  Google Scholar 

  12. KiJoo, H. and Yang, K.S., J. Power Sources, 2002, vol. 109, p. 427.

    Article  Google Scholar 

  13. Alcantara, R., Jaraba, M., and Lavela, P., Electrochim. Acta, 2002, vol. 47, p. 1829.

    Article  CAS  Google Scholar 

  14. Sung, B.P., Won, S.E., and Ho, J., J. Power Sources, 2006, vol. 159, p. 679.

    Article  Google Scholar 

  15. Yang, L., Furczon, M.M., and Xiao, A., J. Power Sources, 2010, vol. 195, p. 1698.

    Article  CAS  Google Scholar 

  16. Xu, K., Zhang, S.S., and Jow, T.R., Electrochem. Solid State Lett., 2002, vol. 5, p. 26.

    Article  Google Scholar 

  17. Panitz, J.C., Wietelmann, U., and Wachtler, M., J. Power Sources, 2006, vol. 153, p. 396.

    Article  CAS  Google Scholar 

  18. Jiang, J. and Dahn, J.R., Electrochem Solid State Lett., 2003, vol. 6, p. 180.

    Article  Google Scholar 

  19. Fan, W.F., Qu, M.Z., and Peng, G., Chinese J. lnorg. Chem., 2009, vol. 25, p. 124.

    CAS  Google Scholar 

  20. Fang, X., Lu, Y., and Ding, N., Electrochim. Acta, 2010, vol. 55, p. 832.

    Article  CAS  Google Scholar 

  21. Zhong, Q.M., Bonakdarpour, A., and Zhang, M.J., Electrochem. Soc., 1997, vol. 144, p. 205.

    Article  CAS  Google Scholar 

  22. Xi, X.R., Wang, S.C., and Zhan, Z.K., Min. Metall. Eng., 2009, vol. 29, p. 85.

    CAS  Google Scholar 

  23. Yan, Q.X., Wang, Z.X., and Wu, J., J. Funct. Mater., 2009, vol. 40, p. 933.

    CAS  Google Scholar 

  24. Nakai, I., Shiraishi, Y., and Nishikawa, F., Spectrochim. Acta, Part B, 1999, vol. 54, p. 143.

    Article  Google Scholar 

  25. Meng, M.W., Liao, Q.H., and Huang, Y., Heat Treat. Met., 2009, vol. 34, no. 3, p. 10.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Petrochemical Technology, Lanzhou University of Technology, Lanzhou, 730050, China

    Xiaoling Cui, Xinming Shi, Guixian Li, Shiyou Li, Xiaoli Xu, Yongli Li & Liping Mao

  2. Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining, 810008, China

    Xiushen Ye

Authors
  1. Xiaoling Cui
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Xinming Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Guixian Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Shiyou Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xiaoli Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yongli Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Liping Mao
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Xiushen Ye
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guixian Li.

Additional information

Published in Russian in Elektrokhimiya, 2014, Vol. 50, No. 4, pp. 407–414.

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cui, X., Shi, X., Li, G. et al. Electrochemical performance of LiNi0.5Mn1.5O4 doped with la and its compatiblity with new electrolyte system. Russ J Electrochem 50, 363–369 (2014). https://doi.org/10.1134/S102319351310011X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S102319351310011X

Keywords

Search

Navigation