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A novel and low cost electrochemical sensor for ceftazidime and cefazoline as antibiotic drugs based on nickel/SDS-poly(o-aminophenol) modified electrode

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Abstract

Poly(o-aminophenol) (POAP) was formed by successive cyclic voltammetry in monomer solution in the presence of sodium dodecyl sulfate (SDS) on the surface of a carbon paste electrode (CPE). Ni(II) ions were incorporated into the electrode by immersion of the polymeric modified electrode having amine groups in 0.1 M Ni(II) ion solution. Electrochemical study of this modified electrode shows a good redox behavior of the Ni(III)/Ni(II) couple. The electrocatalytic oxidations of ceftazidim and cefazolin at the surface of the Ni/SDS-POAP/CPE were studied in a 0.1 M NaOH solution. Finally, using chronoamperometric method, the catalytic rate constants (k) for ceftazidim and cefazolin were calculated. Electrode was successfully applied for determination of ceftazidim and cefazolin in pharmaceutical preparations.

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Authors and Affiliations

  1. Chemistry Department, Islamic Azad University, Ayatollah Amoli Branch, Amol, Iran

    Shahla Fathi

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  1. Shahla Fathi
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Correspondence to Shahla Fathi.

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Published in Russian in Elektrokhimiya, 2014, Vol. 50, No. 5, pp. 523–531.

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Fathi, S. A novel and low cost electrochemical sensor for ceftazidime and cefazoline as antibiotic drugs based on nickel/SDS-poly(o-aminophenol) modified electrode. Russ J Electrochem 50, 468–475 (2014). https://doi.org/10.1134/S1023193513100078

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  • DOI: https://doi.org/10.1134/S1023193513100078

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