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Peculiarities of the electrochemical behavior of polyaniline synthesized in the presence of Ce3+ cations

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Abstract

Polyaniline (PANI) is synthesized in the potentiostatic pulse mode from an electrolyte containing Ce3+ sulfate. The electrochemical behavior of PANI and PANI-Ce is studied in electrolytes with and without cerium cations. The data on the relaxation and the effect of electrochemical cycling on the magnitude and behavior of the electrochemical capacitance are shown. After the cathodic reduction in the presence of Ce3+ rare-earth cations, the PANI relaxation proceeds faster and the specific electrochemical capacitance is almost completely retained at long-term electrochemical cycling.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast’, 142432, Russia

    V. V. Abalyaeva

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  1. V. V. Abalyaeva
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Correspondence to V. V. Abalyaeva.

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Original Russian Text © V.V. Abalyaeva, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 9, pp. 974–981.

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Abalyaeva, V.V. Peculiarities of the electrochemical behavior of polyaniline synthesized in the presence of Ce3+ cations. Russ J Electrochem 49, 870–877 (2013). https://doi.org/10.1134/S1023193513090036

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  • DOI: https://doi.org/10.1134/S1023193513090036

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