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Determination of thermodynamic properties of triple phases formed in different regions of phase diagram of the Ag-Bi-S system using EMF measurements

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Abstract

The technique of measurement of electromotive force (EMF technique) in reversible cells of solid-state galvanic cells with RbAg4I5 as solid electrolyte was used to determine standard thermodynamic properties of triple phases in the system of Ag-Bi-S in equilibrium with metallic bismuth. The results are compared to the available literature data obtained in equilibrium with crystalline sulfur.

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Authors and Affiliations

  1. Institute of Experimental Mineralogy, Russian Academy of Sciences, Chernogolovka, Russia

    M. V. Voronin & E. G. Osadchii

Authors
  1. M. V. Voronin
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  2. E. G. Osadchii
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Correspondence to E. G. Osadchii.

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Original Russian Text © M.V. Voronin, E.G. Osadchii, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 8, pp. 828–833.

Published on the basis of the lecture in XI Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, 2012.

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Voronin, M.V., Osadchii, E.G. Determination of thermodynamic properties of triple phases formed in different regions of phase diagram of the Ag-Bi-S system using EMF measurements. Russ J Electrochem 49, 741–746 (2013). https://doi.org/10.1134/S1023193513080211

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  • DOI: https://doi.org/10.1134/S1023193513080211

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