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Synthesis, structure, and physico-chemical properties of sulfide ceramics CaY2S4-Yb2S3

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Abstract

Solid solutions are synthesized in the system of CaY2S4-Yb2S3. Temperature and concentration dependences of electrolytic properties are studied, the sulfide ion-based conductivity is confirmed. It is shown that the high contribution of ion conductivity in the synthesized phases is due to formation of charged vacancies. Mechanisms of defect formation are suggested.

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Authors and Affiliations

  1. Vyatka State University, ul. Moskovskaya 36, Kirov, 610000, Russia

    E. V. Koshurnikova, L. A. Kalinina, Yu. N. Ushakova & M. V. P’yankova

  2. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198504, Russia

    I. V. Murin

Authors
  1. E. V. Koshurnikova
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  2. L. A. Kalinina
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  3. Yu. N. Ushakova
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  4. M. V. P’yankova
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  5. I. V. Murin
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Correspondence to E. V. Koshurnikova.

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Original Russian Text © E.V. Koshurnikova, L.A. Kalinina, Yu.N. Ushakova, M.V. P’yankova, I.V. Murin, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 8, pp. 858–864.

Published on the basis of the lecture in XI Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, 2012.

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Koshurnikova, E.V., Kalinina, L.A., Ushakova, Y.N. et al. Synthesis, structure, and physico-chemical properties of sulfide ceramics CaY2S4-Yb2S3 . Russ J Electrochem 49, 769–775 (2013). https://doi.org/10.1134/S1023193513080107

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  • DOI: https://doi.org/10.1134/S1023193513080107

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