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Ceramics of the Cs2O–Al2O3 System Prepared by Solid-Phase Technology and the Glycine–Nitrate Combustion Process

  • INORGANIC MATERIALS AND NANOMATERIALS
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Abstract

Cs2O–Al2O3 ceramic samples containing 20 and 33 mol % cesium oxide were prepared by сeramic technique and by the glycine–nitrate combustion process. The prepared samples were identified and characterized by X-ray powder diffraction and X-ray fluorescence analyses, scanning electron microscopy, and differential thermal analysis. X-ray powder diffraction and scanning electron microscopy showed that the phase composition and surface of the samples change significantly and nonmonotonically depending on the synthetic method used and the heat treatment parameters of the batch. Optimal synthetic conditions and heat treatment parameters for preparing Cs2O–Al2O3 samples were elucidated.

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ACKNOWLEDGMENTS

The authors express their gratitude to the staff of the resource centers “X-ray Diffraction Methods of Investigation”, “Interdisciplinary Resource Centre for Nanotechnology”, “Innovative Technologies of Composite Nanomaterials”, and “Geomodel” of the science park of St. Petersburg State University.

Funding

This work was supported by Ministry of Education and Science of the Russian Federation (project No. 075-15-2021-1383).

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Authors and Affiliations

  1. St. Petersburg State University, 199034, St. Petersburg, Russia

    A. V. Fedorova, V. A. Stolyarov, M. E. Pavelina, P. D. Kolonitskii, S. O. Kirichenko & V. L. Stolyarova

  2. St. Petersburg State Electrotechnical University “LETI” named after V.I. Ul’yanov (Lenin), 197022, St. Petersburg, Russia

    A. V. Timchuk

Authors
  1. A. V. Fedorova
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  2. V. A. Stolyarov
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  3. M. E. Pavelina
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  4. P. D. Kolonitskii
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  5. S. O. Kirichenko
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  6. A. V. Timchuk
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  7. V. L. Stolyarova
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Correspondence to A. V. Fedorova.

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The authors declare that they have no conflicts of interest to disclose here.

Additional information

In commemoration of the 300th anniversary of St. Petersburg State University’s founding

Translated by O. Fedorova

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Fedorova, A.V., Stolyarov, V.A., Pavelina, M.E. et al. Ceramics of the Cs2O–Al2O3 System Prepared by Solid-Phase Technology and the Glycine–Nitrate Combustion Process. Russ. J. Inorg. Chem. 68, 911–922 (2023). https://doi.org/10.1134/S0036023623600909

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