Abstract
The effect of the reference electrode (Ag, AgCl∣KF + KCl or Sn, SnF2) on the kinetics of new phase growth at interfaces formed by LaF3:Eu2+ or CeF3:Sr2+ single crystal solid electrolytes with metal electrodes of Ag and Bi is studied by chronoamperometry and linear scan voltammetry. It is shown that when a solid-phase reference electrode is used, the current transients reflect hindrances associated with instantaneous two- or three-dimensional nucleation as well as limitations for fluoride ion diffusion in the solid electrolyte.
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Original Russian Text © M.S. Turaeva, I.V. Tarasenkova, O.V. Glumov, I.V. Murin, 2013, published in Elektrokhimiya, 2013, Vol. 49, No. 7, pp. 794–800.
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Turaeva, M.S., Tarasenkova, I.V., Glumov, O.V. et al. Kinetics of intermediate phase growth at the interface of fluoride-conducting solid electrolytes with metal electrodes. Russ J Electrochem 49, 712–717 (2013). https://doi.org/10.1134/S1023193513070185
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DOI: https://doi.org/10.1134/S1023193513070185