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Optimization of the Compositions of Solid Electrolytes Pb1 – xRxF2 + x with Fluorite-Type Structure in Conductivity and Thermal Stability

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Abstract

The compositions of nonstoichiometric phases Pb1 – xRxF2 + x (CaF2 type, R is a rare-earth element) have been optimized with respect to the ionic conductivity and thermal stability based on the temperature measurements of the electrical conductivity of single crystals and alloys, in dependence of their R3+ ionic radius and RF3 content, and on the analysis of the phase diagrams of the PbF2–RF3 systems. It is shown that Pb0.95Yb0.05F2.05 and Pb0.9Sc0.1F2.1 crystals have the highest conductivities among the Pb1 – xRxF2 + x phases (σ500 K = 9.3 × 10–3 and 2.0 × 10–2 S/cm and σ293 K = 1.4 × 10–6 and 1.5 × 10–4 S/cm, respectively). The conductivity σ293 K of the solid electrolyte Pb0.9Sc0.1F2.1 is sufficient for using it in room-temperature fluorine-ion sensors and current sources.

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REFERENCES

  1. B. P. Sobolev and N. I. Sorokin, Crystallogr. Rep. 59 (6), 807 (2014).

    Article  ADS  Google Scholar 

  2. N. I. Sorokin, A. M. Golubev, and B. P. Sobolev, Crystallogr. Rep. 59 (2), 248 (2014).

    Article  ADS  Google Scholar 

  3. N. I. Sorokin and B. P. Sobolev, Crystallogr. Rep. 64 (5), 621 (2019).

    Article  ADS  Google Scholar 

  4. A. K. Ivanov-Shits, N. I. Sorokin, P. P. Fedorov, and B. P. Sobolev, Solid State Ionics 31 (4), 253 (1989).

    Article  Google Scholar 

  5. A. K. Ivanov-Shits, N. I. Sorokin, P. P. Fedorov, and B. P. Sobolev, Solid State Ionics 31 (4), 269 (1989).

    Article  Google Scholar 

  6. A. K. Ivanov-Shits, N. I. Sorokin, P. P. Fedorov, and B. P. Sobolev, Solid State Ionics 37 (1–2), 125 (1990).

    Article  Google Scholar 

  7. N. I. Sorokin, Elektrokhimiya 42 (7), 828 (2006).

    Google Scholar 

  8. B. P. Sobolev, N. I. Sorokin, and N. B. Bolotina, Photonic and Electronic Properties of Fluoride Materials, Vol. 1: Int. Collection “Progress in Fluorine Science,” Ed. by A. Tressaud and K. Poeppelmeier (Elsevier, Amsterdam, 2016), p. 465.

  9. N. I. Sorokin, P. P. Fedorov, A. K. Ivanov-Shits, and B. P. Sobolev, Fiz. Tverd. Tela 30 (5), 1537 (1988).

    Google Scholar 

  10. N. I. Sorokin, E. A. Sul’yanova, I. I. Buchinskaya, and B. P. Sobolev, Crystallogr. Rep. 50 (4), 695 (2005).

    Article  ADS  Google Scholar 

  11. N. I. Sorokin, B. P. Sobolev, and M. Breiter, Phys. Solid State 44 (8), 1579 (2002).

    Article  ADS  Google Scholar 

  12. J. W. Fergus, Sens. Actuators B 42, 119 (1997).

    Article  Google Scholar 

  13. N. I. Sorokin and B. P. Sobolev, Crystallogr. Rep. 52 (5), 842 (2007).

    Article  ADS  Google Scholar 

  14. A. V. Chadwick, Solid State Ionics 8, 209 (1983).

    Article  Google Scholar 

  15. N. I. Sorokin, Russ. J. Phys. Chem. 76 (3), 319 (2002).

    Google Scholar 

  16. B. P. Sobolev, The Rare Earth Trifluorides, Part 1: The High Temperature Chemistry of the Rare Earth Trifluorides (Institute of Crystallography, Moscow, 2000; Institut d’Estudis Catalans, Barcelona, 2000).

  17. I. I. Buchinskaya and P. P. Fedorov, Usp. Khim. 73 (4), 404 (2004).

    Article  Google Scholar 

  18. C. C. Liang and A. V. Joshi, J. Electrochem. Soc. 122, 466 (1975).

    Article  Google Scholar 

  19. I. V. Murin, Izv. SO Akad. Nauk SSSR, Ser. Khim. Nauk, No. 2, Iss. 1, 53 (1984).

    Google Scholar 

  20. J. M. Reau, P. P. Fedorov, L. Rabardel, et al., Mater. Res. Bull. 18, 1235 (1983).

    Article  Google Scholar 

  21. A. Rhandour, J. M. Reau, S. F. Matar, and P. Hagenmuller, J. Phys. Chem. Solids 47 (6), 587 (1986).

    Article  ADS  Google Scholar 

  22. J. ten Eicken, W. Gunsser, S. V. Chernov, et al., Solid State Ionics 53–56, 843 (1992).

    Article  Google Scholar 

  23. S. J. Patwe, P. Balaya, P. S. Goyal, and A. K. Tyagi, Mater. Res. Bull. 36, 1743 (2001).

    Article  Google Scholar 

  24. N. I. Sorokin and B. P. Sobolev, Crystallogr. Rep. 61 (3), 469 (2016).

    Article  ADS  Google Scholar 

  25. D. S. Stockbarger, J. Opt. Soc. Am. 39 (9), 31 (1949).

    Article  Google Scholar 

  26. V. A. Arkhangel’skaya, V. N. Baklanova, I. A. Ivanova, et al., Trudy GOI (Gos. Opt. Inst.) 54 (188), 129 (1983).

    Google Scholar 

  27. Y. Ito and K. Koto, Solid State Ionics 18–19, 1202 (1986).

    Article  Google Scholar 

  28. B. P. Sobolev, The Rare Earth Trifluorides, Part 2: Introduction to Materials Science of Multicomponent Metal Fluoride Crystals (Institute of Crystallography, Moscow, 2001; Institut d’Estudis Catalans, Barcelona, 2001).

  29. N. I. Sorokin, P. P. Fedorov, and B. P. Sobolev, Inorg. Mater. 33 (1), 1 (1997).

    Google Scholar 

  30. N. I. Sorokin, G. A. Shchavlinskaya, I. I. Buchinskaya, and B. P. Sobolev, Elektrokhimiya 34 (9), 1031 (1998).

    Google Scholar 

  31. C. E. Derrington, A. Navrotsky, and M. O’Keeffe, Solid State Commun. 18, 47 (1976).

    Article  ADS  Google Scholar 

  32. J. P. Goff, W. Hayes, S. Hull, and M. T. Hutchings, J. Phys.: Condens. Matter 3, 3677 (1991).

    ADS  Google Scholar 

  33. I. Kosacki, A. P. Litvinchuk, J. J. Tarasov, and M. Ya. Valakh, J. Phys.: Condens. Matter 1, 929 (1989).

    ADS  Google Scholar 

  34. L. M. Volodkovich, G. S. Petrov, R. A. Vecher, and A. A. Vecher, Termochim. Acta 88, 497 (1985).

    Article  Google Scholar 

  35. H. W. den Hartog and. J. van der Veen, Phys. Rev. B 37 (4), 1807 (1988).

  36. P. P. Fedorov, I. P. Zibrov, B. P. Sobolev, and I. V. Shishkin, Zh. Neorg. Khim. 32 (7), 1794 (1987).

    Google Scholar 

  37. P. P. Fedorov, I. P. Zibrov, E. V. Tarasova, et al., Zh. Neorg. Khim. 33 (12), 3222 (1988).

    Google Scholar 

  38. P. P. Fedorov, V. Trnovcova, V. A. Meleshina, et al., Neorg. Mater. 30 (3), 406 (1994).

    Google Scholar 

  39. W. Hume-Rothery and G. V. Raynor, The Structure of Metals and Alloys (The Institute of Metals, London, 1956).

    MATH  Google Scholar 

  40. J. ten Eicken, W. Gunsser, M. Karus, et al., Solid State Ionics 72, 7 (1994).

    Article  Google Scholar 

  41. R. W. Bonne and J. Schoonman, J. Electrochem. Soc. 124, 28 (1977).

    Article  Google Scholar 

  42. I. V. Murin, A. V. Glumov, and O. V. Glumov, Elektrokhimiya 15 (8), 1119 (1979).

    Google Scholar 

  43. W. Bollmann and R. Reimann, Phys. Status Solidi A 16, 187 (1973).

    Article  ADS  Google Scholar 

  44. J. Schoonman and H. W. den Hartog, Solid State Ionics 7, 9 (1982).

    Article  Google Scholar 

  45. D. R. Figueroa, A. V. Chadwick, and J. H. Strange, J. Phys. C 11, 55 (1978).

    ADS  Google Scholar 

  46. A. N. Aleinikov, N. N. Aleinikov, and N. N. Vershinin, Proc. IX All-Union Symp. on Chemistry of Inorganic Fluorides, Cherepovets, July 3–6,1990, p. 31.

  47. J. H. Kennedy and J. C. Hunter, J. Electrochem. Soc. 123 (1), 10 (1976).

    Article  Google Scholar 

  48. P. Hagenmuller, J. M. Reau, C. Lucat, et al., Solid State Ionics 3–4, 341 (1981).

    Article  Google Scholar 

  49. I. Kosacki, Appl. Phys. A 49, 413 (1989).

    Article  ADS  Google Scholar 

  50. R. N. Zakirov and A. S. Marinin, Proc. IX All-Union Symp. on Chemistry of Inorganic Fluorides, Cherepovets, July 3–6,1990, p. 136.

  51. A. A. Potanin, Zh. Vseross. Khim. O-va im. D. I. Mendeleeva. 45 (5–6), 58 (2001).

    Google Scholar 

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Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation within the State assignment for the Federal Scientific Research Centre “Crystallography and Photonics” of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Federal Scientific Research Centre “Crystallography and Photonics,” Russian Academy of Sciences, 119333, Moscow, Russia

    N. I. Sorokin & B. P. Sobolev

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  1. N. I. Sorokin
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  2. B. P. Sobolev
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Correspondence to N. I. Sorokin.

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Translated by Yu. Sin’kov

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Sorokin, N.I., Sobolev, B.P. Optimization of the Compositions of Solid Electrolytes Pb1 – xRxF2 + x with Fluorite-Type Structure in Conductivity and Thermal Stability. Crystallogr. Rep. 65, 98–105 (2020). https://doi.org/10.1134/S1063774520010241

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  • DOI: https://doi.org/10.1134/S1063774520010241

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