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Preconcentration and electroanalysis of silver at pt electrode modified with poly(2-aminothiazole)

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Abstract

Conducting poly(2-aminothiazole) (PAT) films were electrodeposited on a platinum disc electrode surface by constant potential electrolysis of 2-aminothiazole (AT) for the stripping voltammetric determination of Ag(I). Ag(I) was preconcentrated on the polymer matrix by dipping the modified Pt electrode (PAT-Pt electrode) into Ag(I)(aq) solution. Effects of the film thickness, reduction potential, pH, preconcentration time, Ag(I) concentration and the interference of some other metal ions on the oxidation peak current of silver were studied. Cu(II) interference observed to be significant for the stripping voltammetric determination of Ag(I). The detection limit was calculated on the basis of signal to noise ratio of 3 as 2 × 10−7 mol L−1.

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Authors and Affiliations

  1. Kırıkkale Vocational High School, Department of Chemistry and Chemical Processing Technologies, Kırıkkale University, 71450, Yahşihan, Kırıkkale, Turkey

    Hakan Çiftçi

  2. Department of Chemistry, Faculty of Arts and Sciences, Kırıkkale University, 71450, Yahsihan, Kırıkkale, Turkey

    Hasan Nur Testereci & Zeki Öktem

Authors
  1. Hakan Çiftçi
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  2. Hasan Nur Testereci
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  3. Zeki Öktem
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Correspondence to Zeki Öktem.

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Published in Rusian in Elektrokhimiya, 2013, Vol. 49, No. 12, pp. 1292–1297.

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Çiftçi, H., Testereci, H.N. & Öktem, Z. Preconcentration and electroanalysis of silver at pt electrode modified with poly(2-aminothiazole). Russ J Electrochem 49, 1160–1164 (2013). https://doi.org/10.1134/S1023193513010151

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  • DOI: https://doi.org/10.1134/S1023193513010151

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