Abstract
A novel mixed composite system, [Ag2HgI4:0.2AgI]: x KI, (x = 0.2, 0.4, 0.6 mol %), was prepared and [Ag2HgI4:0.2AgI] composite system was used as the host. Electrical conductivity was measured to study the transition behavior at frequencies of 100, 120 Hz, 1, and 10 kHz in the temperature range of 90–170°C. Conductivity increased sharply during the α-β phase transition. Upon increasing the dopant-to-host ratio, the conductivity of the superionic system exhibited Arrhenius (thermally activated)-type behavior. X-ray powder diffraction, DTA, DTG and TGA were performed to confirm the doping effect and transition in the host. The phase transition temperature decreased with an increase in the dopant concentration. Activation energies in eV for pre- and post-transition phase behavior are also reported.
Similar content being viewed by others
References
Maier, J., Prog. J. Solid State Chem., 1995, vol. 23, p. 171.
Liang, C.C., J. Electrochem. Soc., 1973, vol. 120, p. 1289.
Wieczorek, W., Solid State Ionics, 1992, vols. 53–56, p. 1064.
Wagner, J.B., Jr., Mater. Res. Bull., 1980, vol. 15, p. 1691.
Noorussaba and Ahmad, A., Analytical and Bioanalytical Electrochemistry, 2011 (in press).
Noorussaba and Ahmad, A., Bull. Mater. Sci., 2010, vol. 33, p. 419.
Noorussaba, Ahmad, A., and Ozcelik, B., Abstract of Papers, Workshop on Nanoscience and Nanotechnology “Aligarh Nano”, Aligarh: NNAN, 2011, p. 53.
Noorussaba and Ahmad, A., Central Europ. J. Chem., 2010, vol. 8, p. 1227.
Noorussaba, Ahmad, A., and Ozcelik, B., Phase Transitions, 2011 (in press).
Noorussaba, Ahmad, A., and Ozcelik, B., Abstract of Papers, Conference of Young Scientists on “Chemistry: Frontiers and Challenges”, Aligarh: ICCFC, 2011, p. 231.
Noorussaba and Ahmad, A., Abstract of Papers, Conference of Young Scientists on the Emerging Areas in Chemistry, Mysore: NACEAC, 2009, p. 119.
Ingram, M.D., Phys. Chem. Glasses, 1987, vol. 28, p. 215.
Agrawal, R.C., Vermab, M.L., and Gupta, R.K., Solid State Ionics, 2004, vol. 171, p. 199.
Secco, E.A. and Usha, M.G., Solid State Ionics, 1994, vol. 68, p. 213.
Wagner, C., Z. Phys. Chem., Ser. B, 1936, vol. 34, p. 309.
Koch, E. and Wagner, C., Z. Phys. Chem., Ser. B, 1936, vol. 34, p. 317.
Friesel, M., Lunden, A., and Baranowski, B., Phys. Rev., Ser. B, 1985, vol. 32, no. 4, p. 2506.
Varshney, P., Sarita, Ahmad, A., and Beg, S., J. Phys. Chem. Solids, 2006, vol. 67, p. 2305.
Magistris, A., Chiodelli, G., and Camari, G.V., Z. Naturforsch, 1976, vol. 31, p. 974.
Agrawal, R.C. and Kumar, R., J. Phys., Ser. D, 1996, vol. 29, p. 156.
Lauer, U. and Maier, J., Solid State Ionics, 1992, vol. 51, p. 209.
Viswanathan, A. and Suthanthiraraj, S.A., Solid State Ionics, 1993, vol. 62, p. 79.
Kumari, M.S. and Secco, E.A., Canad. J. Chem., 1985, vol. 63, p. 324.
Fernandez, V., Jaque, F., and Calleja, J.M., Solid State Commun., 1986, vol. 59, p. 803.
Shannon, R.D., Acta Crystallogr. Sect., Ser. A, 1976, vol. 32, p. 751.
Secco, E.A. and Usha, M.G., Solid State Ionics, 1994, vol. 68, p. 213.
Yanjiu, L., Secco, E.A., and Usha, M.G., J. Phys. Chem. Solids, 1993, vol. 54, p. 821.
Mac, R., Murrary, L., and Secco, E.A., Canad. J. Chem., 1978, vol. 56, p. 2616.
Nair, S.M., Yahya, A.I., Rafiuddin, and Ahmad, A., Solid State Ionics, 1996, vols. 86–88, p. 137.
Wang, Y. and Rubner, M.F., Synthetic Metals, 1990, vol. 39, p. 153.
Wang, Y. and Rubner, M.F., Synthetic Metals, 1992, vol. 47, p. 255.
Hull, S. and Keen, D.A., J. Phys., 2000, vol. 12, p. 3751.
Boyce, J.B. and Huberman, B.A., Phys. Rep., 1979, vol. 51, p. 189.
Browall, K.W., Kasper, J.S., and Wiedemeier, H., J. Solid State Chem., 1974, vol. 10, p. 20.
Burley, G., National Bureau of Standards, Washington DC, 1962.
Seitz, Modern Theory of Solids, 1940, p. 49.
Istomin, S.Ya., Chernov, S.V., Antipov, E.V., and Dobrovolsky, A.Yu., J. Solid State Chem., 2007, vol. 180, p. 1882.
Adamski, A., Sojka, Z., Dyrek, K., and Che, M., Solid State Ionics, 1999, vol. 117, p. 113.
Agrawal, R.C., Gupta, R.K., Kumar, R., and Kumar, A., J. Mater. Sci., 1994, vol. 29, p. 3673.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Elektrokhimiya, 2013, Vol. 49, No. 11, pp. 1188–1195.
The article is published in the original.
Rights and permissions
About this article
Cite this article
Noorussaba, Ahmad, A. Phase transition in a [Ag2HgI4:0.2AgI] mixed composite system doped with KI. Russ J Electrochem 49, 1065–1072 (2013). https://doi.org/10.1134/S1023193512080125
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1023193512080125